Separation of carbon dioxide and hydrocarbons

• US 6,024,781 A
• Filed: 04/17/1998
• Issued: 02/15/2000
• Est. Priority Date: 04/17/1998
• Status: Expired due to Fees

• Current Assignee: BOC Group Pty Limited (Linde Plc)
• Original Assignee: BOC Group Pty Limited (Linde Plc)
• Inventors: Brooks, Jonathan Paul, La Cava, Alberto I., Shen, Dongmin, Guo, Chang Jie, Fitch, Frank R., Shirley, Arthur I., Bulow, Martin, Dougill, Silvia Beatriz
• Primary Examiner(s): Spitzer, Robert H.
• Application Number:
  US09/062,338
• Time in Patent Office: 669 Days
• Field of Search: 95/96-106, 95/114, 95/115, 95/139, 95/902, 95/903
• US Class Current: 95/101
• CPC Class Codes: B01D 2253/108 Zeolites
• CPC Class Codes: B01D 2256/24 Hydrocarbons
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2259/40086 by using a purge gas B01D2259/4009 takes precedence
• CPC Class Codes: B01D 53/04 with stationary adsorbents B01D53/025 takes precedence
• CPC Class Codes: B01D 53/0462 Temperature swing adsorption
• CPC Class Codes: B01D 53/047 Pressure swing adsorption
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y10S 95/902 Molecular sieve

Abstract

Carbon dioxide is separated from gaseous hydrocarbons by a cyclic adsorption process using at a temperature in the range of about -50 to about 200° C., wherein the adsorption step of the process is conducted by passing the gas mixture through an adsorption zone containing carbon molecular sieve or type A zeolite whose exchangeable cations are made up of about 50 to about 90% sodium ions and about 10 to about 50 percent potassium ions.

Claims

1. A method of separating carbon dioxide from a gas mixture by a cyclic adsorption process comprising the steps:

(a) passing said gas mixture through at least one adsorption zone containing an adsorbent selected from the group consisting of type A zeolite having as its exchangeable cations, about 40 to about 90% sodium ions, about 10 to about 50% potassium ions and about 0 to about 10% other ions selected from the group consisting of Group IA ions, Group IB ions, Group IIA ions, Group IIIA ions, Group IIIB ions, lanthanide series ions and mixtures of these;

thereby adsorbing at least part of the carbon dioxide from said gas mixture and producing a carbon dioxide-depleted gas; and

(b) regenerating said adsorbent, thereby producing a carbon dioxide-enriched gas.

2. The method of claim 1, wherein said cyclic adsorption process is selected from pressure swing adsorption, temperature swing adsorption and a combination of these.

3. The method of claim 2, wherein step (a) is carried out at a temperature in the range of about -50 to about 200°

C.

4. The method of claim 3, wherein step (a) is carried out at a pressure in the range of about 1 to about 120 bara.

5. The method of claim 4, wherein said gas mixture comprises carbon dioxide and at least one gaseous hydrocarbon.

6. The method of claim 5, wherein said hydrocarbon contains 1 to 6 carbon atoms.

7. The method of claim 6, wherein said hydrocarbon comprises alkanes, alkenes, alkynes and mixtures of these.

8. The method of claim 7, wherein said hydrocarbon contains 2 to 4 carbon atoms.

9. The method of claim 8, wherein said hydrocarbon is ethane, propane, ethene, propene, acetylene or mixtures of these.

10. The method of claim 8, wherein said hydrocarbon is an alkyne.

11. The method of claim 10, wherein the adsorbent is type A zeolite and, of the exchangeable cation sites associated with said zeolite, about 55 to about 65% are sodium ions and about 35 to about 45% are potassium ions.

12. The method of claim 11, wherein step (a) is carried out at a temperature in the range of about 0 to about 60°

C.

13. The method of claim 12, wherein said alkyne is ethyne or propyne.

14. The method of claim 13, wherein step (a) is carried out at a temperature in the range of about 20 to about 60°

C.

15. The method of claim 8, wherein said hydrocarbon is an alkane, an alkene or mixtures of these.

16. The method of claim 15, wherein said adsorbent is type A zeolite having as its exchangeable cations, about 50 to about 85% sodium ions, about 15 to about 45% potassium ions and about 0 to about 5% ions selected from said other ions.

17. The method of claim 16, wherein step (a) is carried out at a temperature in the range of about 70 to about 160°

C.

18. The method of claim 17, wherein said adsorbent is type A zeolite having as its exchangeable cations, about 60 to about 80% sodium ions and about 20 to about 40% potassium ions.

19. The method of claim 8, wherein said cyclic adsorption process is pressure swing adsorption and step (a) is carried out at a pressure in the range of about 1 to about 25 bara and step (b) is carried out at a pressure in the range of about 0.2 to about 2 bara.

20. The method of claim 19, wherein step (b) is at least partly carried out by purging said adsorption zone with carbon dioxide-depleted gas.

21. The method of claim 19, further comprising purging said adsorption zone with carbon dioxide-enriched gas prior to step (b).

22. The method of claim 6, wherein said adsorbent is type A zeolite, and substantially all exchangeable cations associated with said type A zeolite are sodium and potassium ions.

23. The method of claim 4, wherein said cyclic adsorption process is pressure swing adsorption and step (b) is carried out at a pressure in the range of about 0.15 to about 5 bara.

24. The method of claim 23, wherein step (b) is at least partly carried out by depressurizing said adsorption zone.

25. The method of claim 23, further comprising at least partly repressurizing said adsorption zone with carbon dioxide-depleted gas after step (b).

26. The method of claim 4, wherein said cyclic adsorption process is temperature swing adsorption and step (b) is carried out at a temperature in the range of about 100 to about 300°

C.

27. The method of claim 1, wherein step (b) is at least partly carried out by purging said adsorption zone with carbon dioxide-depleted gas.

28. The method of claim 1, further comprising purging said adsorption zone with carbon dioxide-enriched gas prior to step (b).