Method and system for bisphenol a production using water

• US 6,033,635 A
• Filed: 11/04/1998
• Issued: 03/07/2000
• Est. Priority Date: 04/12/1996
• Status: Expired due to Fees

• Current Assignee: Ben Gammill
• Original Assignee: Ben Gammill
• Inventors: Gammill, Ben
• Primary Examiner(s): POWELL, WILLIAM A
• Application Number:
  US09/185,947
• Time in Patent Office: 489 Days
• Field of Search: 422/245.1, 422/250.1, 422/254, 422/261, 568/24, 568/716, 568/724, 568/727, 568/728
• US Class Current: 422/245.1
• CPC Class Codes: C07C 37/685 Processes comprising at least two steps in series
• CPC Class Codes: C07C 37/70 by physical treatment
• CPC Class Codes: C07C 37/74 by distillation
• CPC Class Codes: C07C 39/16 Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes

Abstract

Methods/systems for making a relatively high-purity bisphenol A product from phenol and acetone. Controlled turbulence is used to form bisphenol A adduct solids having improved physical properties. Phenol is separated from the bisphenol A product while inhibiting decomposition of bisphenol A.

Claims

1. A system for preparing a relatively high-purity bisphenol A product from an adduct solid while inhibiting decomposition of bisphenol A, the adduct solid comprising at least about 25 weight percent phenol, the system comprising:

a) a first solidification system producing a bisphenol A adduct solid from a first mixture of bisphenol A and phenol during use, the adduct solid comprising at least about 25 weight percent phenol, and the first solidification system operating at a temperature below 150°

C.;

b) a first recovery system separating at least a portion of the adduct solid from the first mixture during use, the first recovery system operating at a temperature below 150°

C.;

c) a mixing system heating water to a temperature less than about 150°

C. during use, and mixing the adduct solid with the heated water during use to form a first solution comprising bisphenol A, water, and phenol;

d) a separation column adapted to reduce the concentration of phenol in the first solution and produce a second solution comprising bisphenol A and less than about 1 weight percent phenol during use, the column comprising an overhead outlet near the top of the column, a bottoms outlet near the bottom of the column, and a feed inlet between the overhead outlet and the bottoms outlet, and the column operating at a temperature below about 150°

C. during use;

e) a second solidification system adapted to produce a bisphenol A product from the second solution during use, the second solidification system operating at a temperature below about 150°

C. during use; and

f) a second recovery system adapted to separate at least a portion of the bisphenol A product from the second solution during use, the separated portion comprising at least about 99 weight percent bisphenol A, the second recovery system operating at a temperature below about 150°

C. during use.

2. The system of claim 1, further comprising a distribution tray located within the column and a feed distributor located within the column, and wherein a recycle conduit is connected to the column to recycle at least a portion of a bottoms stream from the bottoms outlet into the column at a point between the distribution tray and the feed distributor.

3. The system of claim 1, further comprising a reactor producing the first mixture from the reaction of phenol and acetone during use.

4. The system of claim 1, further comprising a heated water injection system injecting heated water into the column during use.

5. The system of claim 1, further comprising a heated water injection system injecting heated water into the column during use, and wherein the heated water is in the form of steam.

6. The system of claim 1, further comprising a steam injection system adapted to inject steam into the column during use, and wherein the steam injection system comprises a steam injection port located near the bottom of the column.

7. The system of claim 1, further comprising a tray located in the column below a feed distributor in the column, the tray adapted to screen solids and inhibit at least a portion of solids from entering a bottoms stream during use.

8. The system of claim 1, further comprising a feed distributor within the column, and wherein the column comprises packing between the feed distributor and the bottoms outlet.

9. The system of claim 1, further comprising a steam system injecting steam into a column feed stream at a location upstream of the column during use.

10. The system of claim 1, further comprising a heating system heating at least a portion of the column wall during use.

11. The system of claim 1, further comprising a distributor located within the column and adapted to distribute a column feed stream substantially parallel to the column wall during use.

12. The system of claim 1 wherein the mixing system comprises a vessel with an agitator.

13. The system of claim 1 wherein the first recovery system comprises at least one screen bowl centrifuge and a phenol wash system to wash solids during use.

14. The system of claim 1 wherein the second solidification system comprises a draft-tube crystallizer.

15. The system of claim 1 wherein the second solidification system comprises a draft-tube crystallizer, and further comprising a vacuum system adapted to maintain the draft-tube crystallizer at an absolute pressure between about 500 torr and about 700 torr during use.

16. The system of claim 1 wherein the second solidification system comprises a draft-tube crystallizer, and further comprising a cooler adapted to maintain the temperature within the draft-tube crystallizer between about 90°

C. and about 100°

C. during use.

17. The system of claim 1, wherein the second recovery unit comprises at least one pusher centrifuge and a water wash system to wash solids during use.

18. The system of claim 1, wherein the second recovery unit comprises at least one contact dryer and a steam system heating the heat transfer surface of the dryer during use.

19. The system of claim 1, wherein the mixing system is adapted to heat the water to a temperature greater than about 60°

C. and less than about 90°

C. during use.

20. The system of claim 1, wherein the first solidification system comprises a crystallizer adapted to maintain a stream at a temperature greater than about 40°

C. and less than about 60°

C. during use.

21. The system of claim 1, wherein the first solidification system comprises a crystallizer and wherein the crystallizer comprises a conduit loop, the conduit loop comprising a solidification zone that communicates with a heat exchanger.

22. The system of claim 1, further comprising a steam injection system adapted to inject steam into the column during use, and wherein the steam injection system comprises a steam injection port located near the bottom of the column, and further comprising a control system adapted to monitor the phenol concentration in a bottoms stream and adjust the amount of steam injected into the column as a function of the phenol concentration in the bottoms stream during use.

23. The system of claim 1, further comprising a steam system adapted, during use, to inject steam into a column feed stream at a location upstream of the column, and wherein the steam injection system is adapted to inject steam having a pressure greater than about 50 psia and less than about 155 psia during use.

24. The system of claim 1, further comprising a heating system adapted to heat at least a portion of the column wall to a temperature of greater than about 110°

C. and less than about 150°

C. during use.

25. The system of claim 1, further comprising a heating system adapted to heat the adduct solution to a temperature of less than about 150°

C. during use, prior to the introduction of the adduct solution into the column.

26. The system of claim 1 wherein the mixing system further comprises a vessel, and wherein the heating system comprises a shell and tube heat exchanger located downstream of the vessel.

27. The system of claim 1 wherein the mixing system further comprises coils, the coils being adapted to heat the adduct solids within the vessel to a temperature of less than about 150°

C. during use.

28. The system of claim 1 wherein the second solidification system comprises a draft-tube crystallizer, and further comprising a water system adapted to add water to the draft-tube crystallizer at a selected temperature during use to maintain the temperature of a stream within the crystallizer at a selected temperature during use.

29. The system of claim 1 wherein the second solidification system comprises a draft-tube crystallizer, and further comprising a water system adapted to add water to the draft-tube crystallizer to maintain the composition of a stream within the crystallizer at 40-60 weight percent water and 40-60 weight percent bisphenol A.

31. The system of claim 1, further comprising a control system controlling the amount of heated water mixed with the adduct solution during use as a function of the rate of a stream comprising phenol and bisphenol A entering the first recovery system.

32. The system of claim 1, further comprising a control system controlling the amount of heated water mixed with the adduct solution during use as a function of the rate that the adduct solution exits the mixing system.

33. The system of claim 1 further comprising a control system controlling the amount of water during use that is added to a bottoms recycle stream comprising bisphenol A and water, the amount of water added being controlled as a function of properties of a column bottoms stream.

30. A system for separating phenol from a bisphenol A adduct solid while inhibiting decomposition of bisphenol A, the adduct solid comprising at least about 25 weight percent phenol, the system comprising:

a) a mixing system adapted to heat water to a temperature less than about 150°

C. and mix the adduct solid with the heated water to form a first solution comprising bisphenol A, water, and phenol;

b) a conduit connected to allow the first solution to flow to a separation column, the separation column being adapted to receive the first solution from the mixer and adapted to reduce the concentration of phenol in the first solution to produce a second solution comprising bisphenol A and less than about 1 weight percent phenol, the column comprising an overhead outlet near the top of the column, a bottoms outlet near the bottom of the column, and a feed inlet between the overhead outlet and the bottoms outlet.

34. A system for preparing a relatively high-purity bisphenol A product from an adduct solid while inhibiting decomposition of bisphenol A, the adduct solid comprising at least about 25 weight percent phenol, the system comprising:

a) a first solidification system producing a bisphenol A adduct solid from a first mixture of bisphenol A and phenol during use, the adduct solid comprising at least about 25 weight percent phenol, and the first solidification system operating at a temperature below 150°

C.;

b) a first recovery system separating at least a portion of the adduct solid from the first mixture during use, the first recovery system operating at a temperature below 150°

C.;

c) a mixing system adapted to melt the adduct solid and add water at a temperature less than about 150°

C. to the melted adduct solid during use to form a first solution comprising bisphenol A, water, and phenol;

d) a separation column adapted to reduce the concentration of phenol in the adduct solution and produce a second solution comprising bisphenol A and less than about 1 weight percent phenol during use, the column comprising an overhead outlet near the top of the column, a bottoms outlet near the bottom of the column, and a feed inlet between the overhead outlet and the bottoms outlet, and the column operating at a temperature below about 150°

C. during use;

e) a second solidification system adapted to produce a bisphenol A product from the second solution during use, the second solidification system operating at a temperature below about 150°

C. during use; and

f) a second recovery system adapted to separate at least a portion of the bisphenol A product from the second solution during use, the separated portion comprising at least about 99 weight percent bisphenol A, the second recovery system operating at a temperature below about 150°

C. during use.