Multilayer recording element suitable for the production of flexographic printing plates by digital information transfer

• US 6,037,102 A
• Filed: 09/26/1996
• Issued: 03/14/2000
• Est. Priority Date: 10/02/1995
• Status: Expired due to Term

• Current Assignee: XSYS Print Solutions Deutschland GmbH
• Original Assignee: BASF AG (BASF SE)
• Inventors: Leinenbach, Alfred, Nisslmuller, Hans-Jurgen, Sandig, Hartmut, Goffing, Friedrich, Loerzer, Thomas
• Primary Examiner(s): Hamilton, Cynthia
• Application Number:
  US08/721,545
• Time in Patent Office: 1,265 Days
• Field of Search: 430/306, 430/273.1, 430/944
• US Class Current: 430/306
• CPC Class Codes: B41C 1/05 Heat-generating engraving heads, e.g. laser beam, electron beam
• CPC Class Codes: G03F 7/202 Masking pattern being obtained by thermal means, e.g. laser ablation
• CPC Class Codes: G03F 7/30 Imagewise removal using liquid means
• CPC Class Codes: Y10S 430/145 Infrared
• CPC Class Codes: Y10S 430/146 Laser beam

Abstract

A multilayer recording element is suitable for the production of flexographic printing plates by digital information transfer and has, arranged one on top of the other on a dimensionally stable substrate, a layer (A) crosslinkable by actinic radiation, a layer (B) sensitive to IR radiation and, if required, a peelable cover sheet, the layer (A) crosslinkable by actinic radiation being capable of being washed out by means of a developer after imagewise exposure and consisting essentially of a mixture of at least one elastomeric binder, ethylenically unsaturated copolymerizable organic compounds, a photoinitiator and, if required, further assistants, and the layer (B) sensitive to IR radiation being a layer which is soluble or dispersible in the developer and contains, in a film-forming binder having elastomeric character, at least one finely divided substance which has a high absorbance in the wavelength range from 750 to 20,000 nm.

Claims

1. A process for the production of flexographic printing plates using a multilayer recording element consisting essentially of arranged one on top of the other on a dimensionally stable substrate,

(1) optionally, an adhesion promoting layer,

(2) a layer (A) which is crosslinkable by actinic radiation,

(3) a layer (B) which is sensitive to IR, and

(4) optionally, a peelable cover sheet,

wherein the layer (a) can be washed out by means of a developer after imagewise exposure and essentially consists of a mixture of

(A1) at least one elastomeric binder,

(A2) ethylenically unsaturated copolymerizable organic compounds,

(A3) a photoinitiator or photoinitiator system, and

(A4) optionally further assistants,

and wherein the layer (B) is soluble or dispersible in the developer or in a different predeveloper and contains an elastomeric film-forming binder, at least one finely divided substance which has a high absorbance in the wavelength range from 750 to 20000 nm, the layer (b) has all optical density of ≧

w, 5 in the actinic range, and

wherein the recording element contains no oxygen-impermeable barrier layer between layers (A) and (B), performing the following steps;

(i) optionally, removing a cover sheet,

(ii) structuring imagewise layer (B) by means of an IR-laser from a digital data set, thus producing a mask by IR-ablation on the layer (A) underneath,

(iii) exposing the recording element to actinic radiation, in the presence of atmospheric oxygen, thus crosslinking layer (A) in those parts which are not covered by the mask,

(iv) removing layer (B) with water or an alcohol/water mixture,

(v) removing the uncrosslinked parts of layer (A) with an organic solvent or organic solvent mixture.