UV radiation and vapor-phase hydrogen peroxide sterilization packaging

• US 6,039,922 A
• Filed: 08/15/1997
• Issued: 03/21/2000
• Est. Priority Date: 08/15/1997
• Status: Expired due to Term

• Current Assignee: Tetra Laval Holdings & Finance SA (Tetra Laval Holdings BV)
• Original Assignee: Tetra Laval Holdings & Finance SA (Tetra Laval Holdings BV)
• Inventors: Palaniappan, Sevugan, Swank, Ronald
• Primary Examiner(s): MCKANE, ELIZABETH L
• Application Number:
  US08/911,967
• Time in Patent Office: 949 Days
• Field of Search: 422/24, 422/28, 422/292, 422/302, 422/304, 53/425
• US Class Current: 422/24
• CPC Class Codes: B65B 55/04 Sterilising wrappers or receptacles prior to, or during, packaging sterilising bottles B67C7/00
• CPC Class Codes: B65B 55/08 by irradiation
• CPC Class Codes: B65B 55/10 by liquids or gases
• CPC Class Codes: B65B 61/186 by applying or incorporating rigid fittings, e.g. discharge spouts

Abstract

The present invention discloses a method and apparatus for sterilizing packaging with vapor-phase hydrogen peroxide and ultraviolet radiation on a packaging machine. A partially formed packaging material is sprayed with gaseous hydrogen peroxide thereby allowing the gas to condense on the packaging material. The packaging material is then conveyed to a UV radiation source for irradiation of the packaging material. The packaging material is then dried with heated air to flush/remove any residual hydrogen peroxide. The present invention sterilizes the packaging material allowing for filling of the packaging material with a desired product such as milk, juice or water. The packaging material may be any number of possibilities such as gable top cartons, parallelepiped containers, flexible pouches, and the like. The invention allows for the efficacious use of hydrogen peroxide having a concentration of up to 53% while providing a packaging material having less than 0.5 ppm hydrogen peroxide.

Claims

1. A method for sterilizing a series of cartons being processed on a multiple station form, fill and seal packaging machine, each of the cartons erected and having sidewalls defining a hollow interior, the method comprising:

forming the bottom of each of the erected cartons on a mandrel to create a series of partially formed cartons;

placing each of the partially formed cartons on a conveyor assembly;

moving each of the partially formed cartons along the conveyor assembly at a predetermined interval to a vapor nozzle disposed above a partially formed carton on the conveyor assembly;

transforming a 35% concentration of hydrogen peroxide into a vapor phase hydrogen peroxide at a vaporizer, the vaporizer disposed above and in flow communication with the vapor nozzle;

applying a predetermined quantity of vapor-phase hydrogen peroxide for the predetermined interval to the interior and the exposed exterior of each of the partially formed cartons positioned at the vapor nozzle, the vapor-phase hydrogen peroxide applied through the vapor nozzle disposed approximately above the center of each of the partially formed cartons;

condensing the vapor-phase hydrogen peroxide onto each of the partially-formed cartons;

flowing hot air into each of the partially-formed cartons for the predetermined interval to remove hydrogen peroxide at a first hot air distribution station;

irradiating each of the partially formed cartons with ultraviolet radiation from a ultraviolet radiation source for a multiple of the predetermined interval, the ultraviolet radiation source disposed above the conveyor assembly and having a reflector to widely disperse the ultraviolet radiation to provide irradiation of the interior and the exposed exterior of each of the partially formed cartons; and

flowing hot air into each of the partially formed cartons for the predetermined interval at a second hot air distribution station to remove substantially all of the hydrogen peroxide;

whereby each of the partially formed cartons are sterilized and have a residue less than 0.5 parts per million of hydrogen peroxide while having a 4.5 log reduction of microogranisms.

2. The method according to claim 1 further comprising the step of filling each of the partially formed cartons.

3. The method according to claim 1 wherein each of the partially formed cartons has a fitment disposed thereon whereby the exposed portions of the fitment are sterilized with the sterilization of each of the partially formed cartons.

4. The method according to claim 1 wherein the vapor-phase hydrogen peroxide has a concentration lower than 53%.

5. The method according to claim 1 wherein the vapor-phase hydrogen peroxide has a concentration of 35%.

6. The method according to claim 1 wherein the ultraviolet radiation is provided by an excimer ultraviolet lamp have a substantially monochromatic wavelength.

7. The method according to claim 1 further comprising the step of transforming to the vapor phase a solution of hydrogen peroxide having a concentration less than 53% prior to the step of subjecting each of the partially formed cartons to a predetermined quantity of vapor-phase hydrogen peroxide.

8. The method according to claim 1 wherein the method for sterilizing occurs within a station substantially enclosed within the packaging machine.

9. A packaging machine for processing a series of cartons, each of the cartons erected and having sidewalls defining a hollow interior, the packaging machine comprising:

a bottom forming station for forming the bottom of each of the erected cartons to create the partially formed cartons;

a conveyor assembly for moving each of the partially formed cartons from the bottom forming station at a predetermined interval;

a vapor nozzle for applying a predetermined quantity of vapor-phase hydrogen peroxide to the interior and the exposed exterior of each of the partially formed cartons, the vapor nozzle disposed downline from the bottom forming station and above the conveyor assembly a distance greater than the height of a partially formed carton;

a vaporizer for transforming a solution of hydrogen peroxide and water into a vapor phase hydrogen peroxide, the vaporizer disposed above and in flow communication with the vapor nozzle;

a first hot air distributor capable of flowing hot air into each of the partially formed cartons, the hot air distributor disposed subsequent to the vaporizer;

an ultraviolet radiation chamber for irradiating each of the partially formed cartons with ultraviolet radiation, the ultraviolet radiation chamber having an ingress and an egress and disposed adjacent the vapor nozzle at the ingress, the ultraviolet radiation chamber having an ultraviolet radiation source disposed above the conveyor assembly and a reflector to widely disperse the ultraviolet radiation to provide irradiation of the interior and the exposed exterior of each of the partially formed cartons; and

a second hot air distributor capable of flowing hot air into each of the partially formed cartons, the hot air distributor disposed adjacent the egress of the ultraviolet radiation chamber;

whereby each of the partially formed cartons are sterilized by the vapor-phase hydrogen perxoide and the ultraviolet radiation, flushed of any residual hydrogen peroxide by the hot air, and have a residue less than 0.5 parts per million of hydrogen peroxide while having a 4.5 log reduction of microogranisms.

10. The apparatus according to claim 9 wherein each of the partially formed cartons has a fitment attached thereon whereby the exposed portions of the fitment are sterilized with the sterilization of each of the partially formed cartons.

11. The apparatus according to claim 9 wherein the vapor-phase hydrogen peroxide has a concentration lower than 53%.

12. The apparatus according to claim 9 wherein the vapor-phase hydrogen peroxide has a concentration of 35%.

13. The apparatus according to claim 9 wherein the ultraviolet radiation source is an excimer ultraviolet lamp having a substantially monochromatic wavelength.

14. The apparatus according to claim 9 wherein the vapor-phase hydrogen peroxide is applied at a temperature in excess of 175°

C.