Hot melt phase change ink containing Diels-Alder polymerization precursor

• US 6,042,227 A
• Filed: 05/19/1998
• Issued: 03/28/2000
• Est. Priority Date: 05/19/1998
• Status: Expired due to Term

• Current Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Original Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Inventors: Meinhardt, Michael B., King, Clifford R.
• Primary Examiner(s): MOSES, RICHARD L
• Application Number:
  US09/081,919
• Time in Patent Office: 679 Days
• Field of Search: 347/99, 347/95, 347/100, 347/88, 106/31.27, 106/31.29, 106/31.6, 106/31.61
• US Class Current: 347/99
• CPC Class Codes: B41M 5/52 Macromolecular coatings
• CPC Class Codes: B41M 5/5227 characterised by organic non-macromolecular additives, e.g. UV-absorbers, plasticisers, surfactants
• CPC Class Codes: B41M 5/5254 characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
• CPC Class Codes: B41M 5/529 characterised by the use of fluorine- or silicon-containing organic compounds
• CPC Class Codes: B41M 7/009 using thermal means, e.g. infrared radiation, heat
• CPC Class Codes: C09D 11/02 Printing inks C09D11/30 takes precedence

Abstract

A phase change ink carrier composition is disclosed which includes a Diels-Alder polymerization precursor wherein the composition forms a low viscosity liquid at temperatures in the range from about 90° C. to at least about 160° C., and forms a malleable material at temperatures from about 40° C. to about 80° C., and a solid at temperatures less than about 30° C.

Claims

1. A phase change ink carrier composition that includes a component that is a Diels-Alder polymerization precursor.

2. The phase change ink carrier composition of claim 1 wherein the Diels-Alder polymerization precursor is a bis-diene.

3. The phase change ink carrier composition of claim 2 wherein the Diels-Alder polymerization precursor is the difurfuryl ester of a dimer acid.

4. The phase change ink carrier composition of claim 1 wherein the Diels-Alder polymerization precursor is a bis-dienophile.

5. The phase change ink carrier composition of claim 4 wherein the Diels-Alder polymerization precursor is an alkoxylated bisphenol A glycidyl diacrylate.

6. The phase change ink carrier composition of claim 1 wherein the Diels-Alder polymerization precursor is contacted with a bis-diene or a bis-dienophile Diels-Alder polymerization precursor to form an imaging composition wherein the composition forms a low viscosity liquid at temperatures in the range from about 90°

C. to at least about 160°

C., and forms a high viscosity, malleable material at temperatures from about 80°

C. to about 40°

C. and a solid at temperatures less than about 30°

C.

7. A phase change ink composition comprising the phase change ink carrier composition of claim 1 and at least one compatible colorant.

8. A phase change ink composition comprising the phase change ink carrier composition of claim 2 and at least one compatible colorant.

9. The phase change ink composition comprising the phase change ink carrier composition of claim 4 and at least one compatible colorant.

10. The phase change ink carrier composition of claim 1 further including at least one amide compound.

11. The phase change ink carrier composition of claim 1 further including at least one component selected from the group consisting of a urethane resin, a urea resin, a mixed urethane/urea resin and mixtures thereof.

12. The phase change ink carrier composition of claim 1 further including a wax selected from the group consisting of an ester, an amide, a natural wax, a synthetic wax and mixtures thereof.

13. The phase change ink carrier composition of claim 12 further including the wax being a polyethylene wax.

14. The phase change ink carrier composition of claim 1 further including a polycarbonate.

15. A method of printing comprising the steps of:

a. forming an ink from a compatible colorant and an ink carrier composition including a Diels-Alder polymerization precursor, the ink being a low viscosity liquid from about 90°

C. to about 160°

C., a malleable material from about 80°

C. to about 40°

C., and a solid below about 30°

C.;

b. applying a liquid layer to a support surface, the liquid layer containing one selected from the group consisting of a silicon-containing compound including a dienophile, a natural or synthetic oil containing a dienophile, a silicon-containing compound including a diene and a compatibilizing additive, a natural or synthetic oil containing a compatible diene and a wax containing a compatible diene; and

c. applying the ink in image-wise fashion to the liquid layer to cause the ink to react with the liquid layer in a Diels-Alder polymerization reaction to form an image.

16. The method according to claim 15 further comprising the Diels-Alder polymerization reaction precursor being a bis-diene that reacts with the dienophile in the liquid layer.

17. The method according to claim 16 further comprising the silicon-containing compound containing a divinyl silyl compound as the dienophile.

18. The method according to claim 17 further comprising the divinyl silyl compound being 1,3-divinyl-1,3-diphenyl-1,3-dimethyldisiloxane or 1,5-divinyl-3-phenylpentamethyltrisiloxane.

19. The method according to claim 16 further comprising the natural or synthetic oil containing cyclohexanedimethanol divinyl ether as the dienophile.

20. The method according to claim 15 further comprising the Diels-Alder polymerization precursor being a bis-dienophile that reacts with the diene in the liquid layer.

21. The method according to claim 15 further comprising the support surface being a final receiving substrate so that the ink is applied directly to the final receiving substrate.

22. The method according to claim 15 further comprising transferring the image from the support surface to a final receiving substrate.