Lyocell fibre and a process for its manufacture

• US 6,042,769 A
• Filed: 12/04/1996
• Issued: 03/28/2000
• Est. Priority Date: 06/22/1994
• Status: Expired due to Term

• Current Assignee: Lenzing AG (B & C Privatstiftung)
• Original Assignee: Acordis Fibres (Holdings Limited
• Inventors: Graveson, Ian, Gannon, James Martin, Woodings, Calvin Roger, Johnson, Pamela Ann
• Primary Examiner(s): Wortman, Donna C.
• Application Number:
  US08/750,304
• Time in Patent Office: 1,210 Days
• Field of Search: 264/129, 264/143, 264/187, 264/203, 264/211.14, 264/210.8, 264/210.7, 264/233, 264/211.15, 106/125, 106/168, 106/176, 106/126, 106/186, 106/198, 106/162, 106/163, 106/200.3
• US Class Current: 264/203
• CPC Class Codes: D01F 2/00 Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
• CPC Class Codes: D04H 1/42 characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
• CPC Class Codes: D04H 1/4266 Natural fibres not provided for in group D04H1/425
• CPC Class Codes: D04H 1/492 by fluid jet D04H1/49 takes precedence
• CPC Class Codes: D21H 13/08 from regenerated cellulose

Abstract

The fibrillation tendency of solvent-spun fiber can be increased by subjecting the fiber to a treatment which reduces its degree of polymerisation by about 200 units or more. Suitable methods of treatment include severe bleaching, for example application of an aqueous liquor containing 0.1 to 10 percent by weight sodium hypochlorite (as available chlorine) to the fiber followed by steaming. Fiber may be treated in never-dried or previously-dried form. Fiber treated by the process of the invention is useful for example in the manufacture of paper and hydroentangled fabrics. Fiber of increased tendency to fibrillation can be beaten to a Canadian Standard Freeness 400 in the Disintegration Test by 30,000-150,000 disintegrator revolutions and to a Canadian Standard Freeness 200 in the same Test by 50,000-200,000 disintegrator revolutions.

Claims

1. A process for the manufacture of lyocell fibre comprising the steps of:

(1) dissolving cellulose in a solvent to form a solution,

(2) extruding the solution through a die to form a plurality of filaments,

(3) washing the filaments to remove the solvent, thereby forming lyocell fibre, the cellulose in the lyocell fibre having a first Degree of Polymerisation, and

(4) reducing the Degree of Polymerisation of the cellulose in the lyocell fibre to a second Degree of Polymerisation, said second Degree of Polymerisation being at least 200 units less than said first Degree of Polymerisation, whereby the resulting fibre displays an increased tendency to fibrillation as compared to the lyocell fibre of step (3).

2. A process according to claim 1, wherein the solvent comprises a tertiary amine N-oxide.

3. A process according to claim 2, wherein the tertiary amine N-oxide is N-methlymorpholine N-oxide.

4. A process according to claim 1, wherein the Degree of Polymerisation of the cellulose is reduced in step (4) by at least 300 units.

5. A process according to claim 1, wherein the Degree of Polymerisation of the cellulose after step (4) is below 250 units.

6. A process according to claim 1, wherein the Degree of Polymerisation is reduced in step (4) by a bleaching treatment.

7. A process according to claim 6, wherein the bleaching treatment comprises applying to the fibre a bleaching liquor which is an aqueous solution comprising sodium hypochlorite.

8. A process according to claim 7, wherein the concentration of sodium hypochlorite in the bleaching liquor expressed as available chlorine is in the range 0.5 to 2.0 percent by weight.

9. A process according to claim 6, wherein the bleaching treatment comprises applying to the fibre a bleaching liquor which is an aqueous solution comprising hydrogen peroxide.

10. A process according to claim 1, wherein step (4) is performed on never-dried lyocell fibre.

11. A process according to claim 1, wherein step (4) is performed on previously-dried lyocell fibre.