Monopropellant and propellant compositions including mono and polyaminoguanidine dinitrate

• US 6,045,638 A
• Filed: 10/09/1998
• Issued: 04/04/2000
• Est. Priority Date: 10/09/1998
• Status: Expired due to Term

• Current Assignee: Arc Automotive Incorporated (The Jordan Co. LP)
• Original Assignee: Atlantic Research Corporation (L3Harris Technologies, Inc.)
• Inventors: Lundstrom, Norman H.
• Primary Examiner(s): Jordan, Charles T.
• Assistant Examiner(s): FELTON, AILEEN BAKER
• Application Number:
  US09/168,568
• Time in Patent Office: 543 Days
• Field of Search: 149/46, 149/61, 149/62, 149/76, 149/36, 149/47, 149/78
• US Class Current: 149/36
• CPC Class Codes: C06B 25/34 the compound being a nitrated acyclic, alicyclic or heterocyclic amine
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

A pyrotechnic gas generant composition including a high oxygen balance fuel that is the resulting reaction product of an aminoguanidine or polyaminoguanidine salt and nitric acid, namely, aminoguanidine dinitrate, diaminoguanidine dinitrate, and triaminoguanidine dinitrate. Specifically, aminoguanidine dinitrate, diaminoguanidine dinitrate, and triaminoguanidine dinitrate can be used as monopropellants or in combination with oxidizers and additives as a solid bipropellant composition. In each instance, the high oxygen balance fuel(s) of the present invention provide(s) both high gas output and low production of solid combustion products. Specifically, the high oxygen balance fuel(s) may be incorporated into gas generators, gun propellants, inflation and expulsion devices, flotation devices, pyrotechnics, fire suppression devices and smokeless, reduced smoke and metallized rocket propellants.

Claims

1. A solid pyrotechnic gas generant composition comprising aminoquanidine dinitrate as a high oxygen balance fuel which is combustible to achieve a total gas output of 100.0 wt. %.

2. A pyrotechnic gas generant composition of claim 2, comprising 2-100% by weight of said high oxygen balance fuel.

3. A pyrotechnic gas generant composition of claim 2, comprising 50-100% by weight of said high oxygen balance fuel.

4. A pyrotechnic gas generant composition of claim 2, further comprising an oxidizer, said gas generant comprising from 0-50% by weight of oxidizer.

5. A pyrotechnic gas generant composition of claim 3, comprising from 0-60% by weight of said oxidizer.

6. A pyrotechnic gas generant composition of claim 4, further including at least one additive selected from the group consisting of a scavenger, ignition aid, ignition initiator, gas conversion catalyst, ballistic modifier, slag formers, binders, energetic binders, plasticizers, energetic plasticizers, fuels, stabilizers, curing agents, cure catalysts, cross linkers, coolants, and compounding aids and mixtures thereof.

7. A pyrotechnic gas generant composition of claim 6, wherein said oxidizer is selected from the group consisting of non-metallic, alkali metal, alkaline earth metal, transition metal and transition metal complex nitrates, nitrites, chlorates, chlorites, perchlorates, chromates, or mixtures thereof.

8. A pyrotechnic gas generant composition of claim 7, wherein said oxidizer comprises sodium nitrate and ammonium perchlorate.

9. A pyrotechnic gas generant composition of claim 7, said oxidizer comprising ammonium nitrate.

10. A pyrotechnic gas generant composition of claim 7, wherein said oxidizer comprises ammonium perchlorate, said composition further comprising an additive selected from at least one of the group consisting of ammonium perchlorate, phase stabilized ammonium nitrate, potassium perchlorate, strontium nitrate, potassium nitrate, lithium nitrate, and lithium carbonate and mixtures thereof.

11. A method for inflating an article capable of retaining gas, comprising the steps of:

(a) reacting a solid gas generant composition comprising aminoguanidine dinitrate as a high oxygen balance fuel which is combustible to achieve a total gas output of 100.0 wt. %;

(b) generating gas as a reaction product of said reaction of said high oxygen balance fuel; and

(c) passing the gas into the article, thereby inflating the article.

12. The method of claim 11, wherein step (a) is practiced by reacting said high oxygen balance fuel as a monopropellant in the absence of oxidizers.

13. The method of claim 11, wherein step (a) is practiced by reacting said high oxygen balance fuel in the presence of an oxidizer.

14. The method of claim 13, wherein the reaction product of said high oxygen balance fuel and oxidizer generates gas and a solid material as reaction products.

15. The method of claim 14, further comprising passing said generated gas and solid material through a filter to thereby retain a portion of the solid material thereon, and then subsequently passing the filter gas on to the article.

16. A solid pyrotechnic gas generant composition comprising 100 wt. % of a high oxygen balance fuel as a monopropellant in the absence of an oxidizer, said high oxygen balance fuel being selected from the group consisting of aminoguanidine dinitrate, diaminoguanidine dinitrate, triaminoguanidine dinitrate, and mixtures thereof.