Process and apparatus for the production of an aqueous solution of hydrogen peroxide

• US 6,045,684 A
• Filed: 04/16/1998
• Issued: 04/04/2000
• Est. Priority Date: 04/16/1997
• Status: Expired due to Fees

• Current Assignee: Katayama Chemical Inc., Permelec Electrode, Ltd.
• Original Assignee: Katayama Chemical Inc., Permelec Electrode, Ltd.
• Inventors: Nishiki, Yoshinori, Nishimura, Kunio, Uno, Masaharu, Shimamune, Takayuki, Wakita, Shuhei
• Primary Examiner(s): Phasge, Arun S.
• Application Number:
  US09/060,814
• Time in Patent Office: 719 Days
• Field of Search: 205/466, 205/510, 204/522, 204/529, 204/531, 204/277, 204/265
• US Class Current: 205/466
• CPC Class Codes: B01D 61/44 Ion-selective electrodialysis

Abstract

An on-site process and apparatus for producing hydrogen peroxide at a high efficiency substantially from brine and oxygen-containing gas alone as raw materials while removing alkaline earth metals. Sea water concentrated by an electrodialytic apparatus 2 or the like as a raw material is supplied to an impurity removing apparatus 10 where caustic soda produced in an acid-alkali producing apparatus 11 at a subsequent stage and/or carbon dioxide gas is added to remove alkaline earth metals contained in sea water in the form of a hydroxide or carbonate precipitate. Separately, the acid-alkali producing apparatus 11 performs a salt separating operation to produce caustic soda which is then supplied to a hydrogen peroxide generator 28 to produce an alkaline aqueous solution of hydrogen peroxide.

Claims

1. A process for producing an aqueous solution of hydrogen peroxide from sea water containing an alkaline earth metal ion, which comprises removing alkaline earth metal ion from the sea water, separating the sea water into an alkaline aqueous solution and an acidic aqueous solution, and then electrolyzing the alkaline aqueous solution while adding thereto an oxygen-containing gas to produce an aqueous solution of hydrogen peroxide, wherein said removing step comprises adding a part of the alkaline aqueous solution produced in the separating step to the brine prior to electrolysis.

2. The process of claim 1, further comprising the step of concentrating the sea water prior to said separating step.

3. The process of claim 2, wherein said concentrating step comprises subjecting the sea water to electrodialysis.

4. The process of claim 1, wherein said separating step comprises subjecting the sea water to salt separation.

5. The process of claim 1, wherein said removing step comprises removing alkaline earth metal ion from the sea water in the form of a hydroxide precipitate.

6. A process for producing an aqueous solution of hydrogen peroxide from sea water containing an alkaline earth metal ion, which comprises removing alkaline earth metal ion from the sea water, separating the sea water into an alkaline aqueous solution and an acidic aqueous solution, and then electrolyzing the alkaline aqueous solution while adding thereto an oxygen-containing gas to produce an aqueous solution of hydrogen peroxide, wherein said removing step comprises adding a part of the alkaline aqueous solution produced in the separating step to the sea water prior to electrolysis to remove part of the alkaline earth metal ion in the form of a hydroxide precipitate and adding a carbon dioxide-containing gas to the sea water prior to electrolysis to remove part of the alkaline earth metal ion in the form of a carbonate precipitate.

7. The process of claim 6, further comprising the step of concentrating the sea water prior to said separating step.

8. The process of claim 7, wherein said concentrating step comprises subjecting the sea water to electrodialysis.

9. A process for producing an aqueous solution of hydrogen peroxide from sea water containing an alkaline earth metal ion, which comprises removing alkaline earth metal ion from the sea water, separating the sea water into an alkaline aqueous solution and an acidic aqueous solution, and then electrolyzing the alkaline aqueous solution while adding thereto an oxygen-containing gas to produce an aqueous solution of hydrogen peroxide, wherein said removing step comprises subjecting the sea water containing an alkaline earth metal ion to electrodialysis prior to electrolysis using a membrane having selective permeability to monovalent ions.

10. The process of claim 9, wherein said separating step comprises subjecting the sea water to salt separation.

11. An apparatus for producing an aqueous solution of hydrogen peroxide from sea water containing alkaline earth metal ion, which comprises means for removing alkaline earth metal ion from the sea water, means for separating the sea water into an alkaline aqueous solution and an acidic aqueous solution, and means for electrolyzing the alkaline aqueous solution while adding thereto an oxygen-containing gas to produce an aqueous solution of hydrogen peroxide, wherein said removing means comprises one or more of (i) recycling means for adding a part of the alkaline aqueous solution produced by said separating means to the sea water prior to electrolysis;

(ii) means for adding a carbon dioxide-containing gas to the sea water prior to electrolysis; and

(iii) electrodialytic means comprising a membrane having selective permeability to monovalent ions.

12. The apparatus of claim 11, comprising means for concentrating the sea water prior to electrolysis.

13. The apparatus of claim 12, wherein said concentrating means comprises electrodialytic means.

14. The apparatus of claim 11, wherein said removing means comprises recycling means for adding a part of the alkaline aqueous solution produced by said separating means to the sea water prior to electrolysis.

15. The apparatus of claim 11, wherein said removing means comprises recycling means for adding a part of the alkaline aqueous solution produced by said separating means to the sea water prior to electrolysis and means for adding a carbon dioxide-containing gas to the sea water prior to electrolysis.