Vapor coating method

• US 6,045,864 A
• Filed: 12/01/1997
• Issued: 04/04/2000
• Est. Priority Date: 12/01/1997
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Blette, Russell E., Fleming, Robert J., Lyons, Christopher S., Wright, Robin E., Tokie, Jeffrey H., Ruta, Constantin I.
• Primary Examiner(s): King, Roy V.
• Application Number:
  US08/980,947
• Time in Patent Office: 855 Days
• Field of Search: 427/248.1, 427/255.23, 427/565, 427/509, 427/255.6, 427/255.28
• US Class Current: 427/255.23
• CPC Class Codes: B05B 7/0861 with one single jet constituted by a liquid or a mixture containing a liquid and several gas jets B05B7/0815 takes precedence
• CPC Class Codes: B05D 1/60 Deposition of organic layers from vapour phase vapour phase deposition in general C23C14/00, C23C16/00

Abstract

Coating system and method that allows coatings to be formed from a wide variety of coatable compositions that are entirely free of any solvents or, alternatively, have relatively little solvent in minor amounts effective to help dissolve one or more components of such compositions. A fluid composition is atomized and contacted with a carrier gas. The contacting occurs under conditions such that vaporization of substantially all of the atomized fluid composition occurs so as to form a vapor having a condensation temperature. The vapor is caused to flow to the surface of the substrate. The surface is at a temperature below the condensation temperature of the vapor. Consequently, the vapor condenses onto the surface to form the coating.

Claims

1. A method of forming a coating on at least a portion of a surface of a substrate, comprising the steps of:

(a) causing a stream of a carrier gas to collide with a stream of a fluid composition said colliding occurring at a carrier gas velocity substantially higher than the fluid stream velocity, the ratio of carrier gas velocity to fluid stream velocity being sufficient to cause vaporization of substantially all of the fluid composition to form a vapor having a condensation temperature;

(b) causing the vapor to flow to the surface of the substrate, said surface being at a temperature below the condensation temperature of the vapor; and

(c) condensing the vapor as a liquid on the surface to form the coating.

2. The method of claim 1, wherein the fluid composition is substantially nonreactive with respect to the carrier gas.

3. The method of claim 1, wherein said vapor is a first vapor and the method further comprises the steps of:

(1) causing a stream of a second carrier gas to collide with a second stream of a second fluid composition, said colliding occurring under conditions such that vaporization of substantially all of the second fluid composition occurs to form a second vapor having a second condensation temperature;

(2) causing the vapor to flow to the surface of the substrate, which surface is at a temperature below the condensation temperature of the vapor; and

(3) condensing the second vapor on the surface to form a part of the coating.

4. The method of claim 3, wherein said first and second vapors are blended prior to step (c).

5. The method of claim 3, wherein said first and second vapors are sequentially condensed on the surface of the substrate.

6. The method of claim 1, wherein the fluid composition comprises at least one fluid component having radiation crosslinkable functionality.

7. The method of claim 1, wherein the fluid composition comprises at least first and second components capable of reacting with each other such that the coating formed on the substrate comprises a reaction product derived from said first and second components.

8. The method of claim 1, wherein the carrier gas is at an elevated temperature that is below the boiling point of at least one component of the fluid composition.

9. The method of claim 1, wherein the vapor in step (b) is formed in a chamber having an entrance end at which said colliding occurs, and said substrate is supported within the chamber, said chamber being maintained at a temperature above the condensation temperature of the vapor.

10. The method of claim 1, wherein the vapor in step (b) flows through a chamber having an entrance end at which said colliding occurs and a discharge end having an orifice through which the vapor is directed onto the surface of the substrate, said chamber being maintained at a temperature above the condensation temperature of the vapor.

11. The method of claim 1, wherein step (a) comprises ejecting the streams of carrier gas and fluid composition through at least first and second orifices, respectively, of a nozzle such that said streams collide.

12. The method of claim 11, wherein:

(a) the first orifice is annularly shaped and is adapted to eject a hollow, substantially conically-shaped stream of carrier gas that tapers inward towards an apex as the carrier gas stream travels away from said first orifice, said stream of carrier gas having an interior region, and

(b) the second orifice is adapted to eject the stream of fluid composition through the interior region of the carrier gas stream to a collision with the carrier gas stream substantially at the apex.

13. The method of claim 1 in which the fluid composition is selected from the group consisting of fluoropolyether monomers, oligomers, and polymers and organofunctional silanes.

14. The method of claim 1 in which steps (a)-(c) take place at a pressure which is not a vacuum.

15. A method of forming a coating on at least a portion of a surface of a substrate, comprising the steps of:

(a) atomizing a fluid composition;

(b) colliding the atomized fluid composition with a carrier gas, said colliding occurring at a carrier gas velocity substantially higher than the velocity of the atomized fluid, the ratio of carrier gas velocity to atomized fluid velocity being sufficient to cause vaporization of substantially all of the atomized fluid composition to form a vapor having a condensation temperature,

(c) causing the vapor to flow to the surface of the substrate, said surface being at a temperature below the condensation temperature of the vapor; and

(d) condensing the vapor as a liquid onto the surface to form the coating.

16. The method of claim 15, wherein the fluid composition contains substantially no solvent.

17. The method of claim 15, wherein said vapor is a first vapor and the method further comprises the steps of:

(1) atomizing a second fluid composition;

(2) contacting the atomized second fluid composition with a second carrier gas, said contacting occurring under conditions such that vaporization of substantially all of the atomized second fluid composition occurs to form a second vapor having a second condensation temperature;

(3) causing the second vapor to flow to the surface of the substrate, said surface being at a temperature below the condensation temperature of the second vapor; and

(4) condensing the second vapor onto the surface to form a part of the coating.

18. The method of claim 17, wherein said first and second vapors are blended prior to step (d).

19. The method of claim 17, wherein said first and second vapors are sequentially condensed on the surface of the substrate.

20. The method of claim 15, wherein the fluid composition is substantially nonreactive with respect to the carrier gas.

21. The method of claim 15, wherein the fluid composition comprises at least first and second components capable of reacting with each other such that the coating formed on the substrate comprises a reaction product derived from said first and second components.

22. The method of claim 15, wherein the carrier gas is at an elevated temperature that is below the boiling point of at least one component of the fluid composition.

23. The method of claim 15, wherein the vapor in step (b) is formed in a chamber having an entrance end at which said contacting occurs, and said substrate is supported within the chamber, said chamber being maintained at a temperature above the condensation temperature of the vapor.

24. The method of claim 15, wherein the vapor in step (b) flows through a chamber having an entrance end at which said contacting occurs and a discharge end having an orifice through which the vapor is directed onto the surface of the substrate, said chamber being maintained at a temperature above the condensation temperature of the vapor.

25. The method of claim 15 in which the fluid composition is selected from the group consisting of fluoropolyether monomers and oligomers, and organofunctional silanes.

26. The method of claim 15 in which steps (a)-(d) occur at a pressure which is not a vacuum.

27. A method of forming a polymeric coating on at least a portion of a surface of a substrate, comprising the steps of:

(a) atomizing a fluid composition comprising one or more polymeric precursor components;

(b) colliding the fluid composition with a carrier gas, said colliding occurring under conditions such that vaporization of substantially all of the atomized fluid composition occurs;

(c) causing the vapor to flow to the surface of the substrate, which surface is at a temperature below the condensation temperature of the vapor; and

(d) condensing the vapor as a liquid on the surface to form the coating.

28. The method of claim 27, wherein the fluid composition contains substantially no solvent.

29. The method of claim 27, wherein said vapor is a first vapor and the method further comprises the steps of:

(1) atomizing a second fluid composition;

(2) contacting the atomized second fluid composition comprising one or more polymer precursors with a second carrier gas, said contacting occurring under conditions such that vaporization of substantially all of the atomized second fluid composition occurs to form a second vapor having a second condensation temperature; and

(3) causing the second vapor to flow to the surface of the substrate, said surface being at a temperature below the condensation temperature of the second vapor.

30. The method of claim 29, wherein said first and second vapors are blended prior to step (d).

31. The method of claim 27, wherein the fluid composition comprises at least one radiation curable component, and wherein the method further comprises the step of irradiating the condensed vapor with a dosage of radiant curing energy effective to solidify the coating.

32. The method of claim 27, wherein the fluid composition comprises a curable polymeric coating precursor, and a quantity of a curing agent effective to facilitate curing of the polymeric coating precursor.

33. The method of claim 27, wherein the fluid composition is substantially nonreactive with respect to the carrier gas.

34. The method of claim 27, wherein the fluid composition comprises at least first and second components capable of reacting with each other such that the polymeric coating formed on the substrate comprises a polymeric reaction product derived from said first and second components.

35. The method of claim 27, wherein the carrier gas is at an elevated temperature that is below the boiling point of at least one component of the fluid composition.

36. The method of claim 27, wherein the vapor in step (b) is formed in a chamber having an entrance end at which said colliding occurs, and said substrate is supported within the chamber, said chamber being maintained at a temperature above the condensation temperature of the vapor.

37. The method of claim 27, wherein the vapor in step (b) flows through a chamber having an entrance end at which said colliding occurs and a discharge end having an orifice through which the vapor is directed onto the surface of the substrate, said chamber being maintained at a temperature above the condensation temperature of the vapor.

38. The method of claim 27, wherein step (b) comprises ejecting the carrier gas through a first orifice of a nozzle and ejecting the fluid composition through a second orifice of the same nozzle, of which:

(a) the first orifice is annularly shaped and is adapted to eject a hollow, substantially conically-shaped stream of carrier gas that tapers inward towards an apex as the carrier gas stream travels away from said first orifice, said stream of carrier gas having an interior region, and

(b) the second orifice is adapted to eject the stream of fluid composition through the interior region of the carrier gas stream to a collision with the carrier gas stream substantially at the apex.

39. The method of claim 27 in which at least one of the polymeric precursor components is selected from the group consisting of fluoropolyether monomers and oligomers, and organofunctional silanes.

40. The method of claim 27 in which steps (a)-(d) occur at a pressure which is not a vacuum.