Multilayer films having pressure sensitive adhesive layers

• US 6,045,895 A
• Filed: 12/01/1997
• Issued: 04/04/2000
• Est. Priority Date: 12/01/1997
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Gadbois, Gregory B., Devens, Douglas A. Jr., Hyde, Patrick D., Krueger, Dennis L., Kollaja, Richard A.
• Primary Examiner(s): Krynski, William
• Assistant Examiner(s): SHEWAREGED, BETELHEM
• Application Number:
  US08/980,920
• Time in Patent Office: 855 Days
• Field of Search: 428/213, 428/214, 428/215, 428/216, 428/354, 428/480, 428/40.1, 428/910, 428/77, 428/136
• US Class Current: 428/213
• CPC Class Codes: B32B 7/027 Thermal properties
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: Y10S 428/91 Product with molecular orientation
• CPC Class Codes: Y10S 428/921 Fire or flameproofing
• CPC Class Codes: Y10T 428/14 Layer or component removable to expose adhesive
• CPC Class Codes: Y10T 428/2495 Thickness [relative or absolute]
• CPC Class Codes: Y10T 428/24959 of adhesive layers
• CPC Class Codes: Y10T 428/24967 Absolute thicknesses specified
• CPC Class Codes: Y10T 428/24975 No layer or component greater than 5 mils thick
• CPC Class Codes: Y10T 428/28 Web or sheet containing structurally defined element or component and having an adhesive outermost layer
• CPC Class Codes: Y10T 428/2848 Three or more layers
• CPC Class Codes: Y10T 428/31504 Composite [nonstructural laminate]
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• CPC Class Codes: Y10T 428/31786 Of polyester [e.g., alkyd, etc.]
• CPC Class Codes: Y10T 428/31855 Of addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31931 Polyene monomer-containing
• CPC Class Codes: Y10T 428/31938 Polymer of monoethylenically unsaturated hydrocarbon

Abstract

The present invention provides unified multilayer films having at least one internal layer that includes a pressure sensitive adhesive material. Preferably, multilayer films of the present invention are no greater than about 250 micrometers (μm) thick. In particularly preferred embodiments of the present invention, multilayer films include layers that include a pressure sensitive adhesive material alternating with layers that include a material that is not a pressure sensitive adhesive. In other preferred embodiments, multilayer films include alternating layers of different pressure sensitive adhesive materials.

Claims

1. A multilayer film having a unified construction of at least 10 substantially contiguous layers of organic polymeric material, wherein at least one internal layer comprises a pressure sensitive adhesive material.

2. The multilayer film of claim 1 having a total thickness of no greater than about 250 micrometers.

3. The multilayer film of claim 1 having at least three layers comprising the same pressure sensitive adhesive material.

4. The multilayer film of claim 1 wherein the unified construction comprises layers comprising a pressure sensitive adhesive material alternating with layers comprising a material that is not a pressure sensitive adhesive.

5. The multilayer film of claim 4 wherein the construction comprises at least 13 such alternating layers.

11. The multilayer film of claim 4 comprising at least three layers comprising the same material that is not a pressure sensitive adhesive.

12. The multilayer film of claim 4 wherein all the layers comprising a pressure sensitive adhesive comprise the same pressure sensitive adhesive material.

14. The multilayer film of claim 4 having two outermost layers comprising a material that is not a pressure sensitive adhesive.

22. The multilayer film of claim 1 wherein at least one layer comprises a flame retardant.

23. The multilayer film of claim 1 wherein the unified construction comprises layers comprising a first pressure sensitive adhesive material alternating with layers comprising a second pressure sensitive adhesive which is a different material from the first pressure sensitive adhesive material.

30. The multilayer film of claim 1 wherein the unified construction comprises layers comprising a pressure sensitive adhesive material selected from the group consisting of tackified natural rubbers, tackified synthetic rubbers, tackified styrene block copolymers, self-tacky acrylate copolymers, tackified acrylate copolymers, tackified methacrylate copolymers, self-tacky poly-α

-olefins, tackified poly-or-olefins, and tackified silicones.

6. A multilayer film having a unified construction of at least 10 substantially contiguous layers comprising layers which comprise a pressure sensitive adhesive alternating with layers comprising a nontacky thermoplastic material.

7. The multilayer film of claim 6 wherein the nontacky thermoplastic material is elastomeric.

9. The multilayer film of claim 6 wherein each layer comprising a pressure sensitive adhesive material comprises a mixture of two or more different pressure sensitive adhesive materials.

10. The multilayer film of claim 6 wherein each layer comprising a pressure sensitive adhesive material comprises a mixture of at least one pressure sensitive adhesive material and at least one material that is not a pressure sensitive adhesive.

8. A multilayer film having a unified construction of at least 10 substantially contiguous layers comprising layers which comprise a pressure sensitive adhesive alternating with layers comprising an elastomer that is not a pressure sensitive adhesive.

13. A multilayer film having a unified construction of at least 10 substantially contiguous layers of organic polymeric material, in which layers comprising pressure sensitive adhesive alternate with layers that are not pressure sensitive adhesives, having two outermost layers comprising a pressure sensitive adhesive material.

15. A multilayer film having a unified construction of at least 10 substantially contiguous layers of organic polymeric material, in which layers comprising pressure sensitive adhesive alternate with layers that are not pressure sensitive adhesives, wherein the two outermost layers comprise different materials.

16. A multilayer film having a unified construction of at least 10 substantially contiguous layers of organic polymeric material, in which layers comprising pressure sensitive adhesive alternate with layers that are not pressure sensitive adhesives, having only one outermost layer comprising a pressure sensitive adhesive material.

17. A multilayer film having a unified construction of at least 10 substantially contiguous layers of organic polymeric material, in which layers comprising pressure sensitive adhesive alternate with layers that are not pressure sensitive adhesives having internal layers of no greater than about 5 micrometers thick.

18. A multilayer film having a unified construction of at least 10 substantially contiguous layers of organic polymeric material, in which layers comprising pressure sensitive adhesive alternate with layers that are not pressure sensitive adhesives, having two outermost layers, each being no greater than about 150 micrometers thick.

19. A multilayer film having a unified construction of at least 10 substantially contiguous layers of organic polymeric material, wherein at least one internal layer comprises a pressure sensitive adhesive, which multilayer film is oriented.

20. The multilayer film of claim 19 which is oriented in one direction.

21. A multilayer film having a unified construction of at least 10 substantially contiguous layers of organic polymeric material, wherein at least one internal layer comprises a pressure sensitive adhesive which is further characterized by having a layer comprising a pressure sensitive adhesive material, a layer comprising a material that is not a pressure sensitive adhesive, and a tie layer therebetween.

24. A multilayer film having a unified construction and a total thickness of no greater than about 250 micrometers;

wherein the construction comprises at least 5 substantially contiguous layers of organic polymeric material;

the construction comprising layers comprising a pressure sensitive adhesive material alternating with layers comprising a material that is not a pressure sensitive adhesive.

25. The multilayer film of claim 24 wherein the construction comprises at least 10 layers.

26. The multilayer film of claim 24 wherein at least one layer comprises a flame retardant.

31. The multilayer film of claim 24 wherein the unified construction comprises layers comprising a pressure sensitive adhesive material selected from the group consisting of tackified natural rubbers, tackified synthetic rubbers, tackified styrene block copolymers, self-tacky acrylate copolymers, tackified acrylate copolymers, tackified methacrylate copolymers, self-tacky poly-α

-olefins, tackified poly-α

-olefins, and tackified silicones.

27. A multilayer film having a unified construction comprising at least 5 substantially contiguous and alternating layers of different pressure sensitive adhesive materials.

28. The multilayer film of claim 27 wherein the unified construction has a total thickness of no greater than about 250 micrometers.

29. The multilayer film of claim 27 wherein the construction comprises at least 10 layers.

32. A multilayer film having a unified construction of at least 10 substantially contiguous layers comprising layers which comprise crosslinked pressure sensitive adhesive alternating with layers comprising a material that is not a pressure sensitive adhesive.