Hydrophilic article and method for producing same

• US 6,045,903 A
• Filed: 06/08/1998
• Issued: 04/04/2000
• Est. Priority Date: 06/09/1997
• Status: Expired due to Fees

• Current Assignee: Nissan Motor Co., Ltd.
• Original Assignee: Nissan Motor Co., Ltd.
• Inventors: Sugawara, Satoko, Seino, Takashi, Kai, Yasuaki
• Primary Examiner(s): Jones, Deborah
• Assistant Examiner(s): STEIN, STEPHEN J
• Application Number:
  US09/092,857
• Time in Patent Office: 666 Days
• Field of Search: 428/428, 428/432, 428/450, 428/472, 428/331, 106/13, 106/286.4, 106/287.19, 106/287.34, 427/165, 427/397.7
• US Class Current: 428/331
• CPC Class Codes: C03C 17/007 containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
• CPC Class Codes: C03C 17/25 by deposition from the liquid phase
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 2217/23 Mixtures
• CPC Class Codes: C03C 2217/45 Inorganic continuous phases
• CPC Class Codes: C03C 2217/478 Silica
• CPC Class Codes: C03C 2218/113 by sol-gel processes
• CPC Class Codes: Y10T 428/259 Silicic material

Abstract

The invention relates to a hydrophilic article having (a) a substrate; and (b) a hydrophilic film formed on the substrate. This film has a hydrophilic outermost layer containing (1) a titania; (2) an amorphous oxide in an amount of from 5 to 25 wt % based on the total weight of the outermost layer; and (3) silica particles having a particle diameter of from 3 to 20 nm. A combination of the titania and the amorphous oxide constitutes the hydrophilic outermost layer'"'"'s matrix phase (continuous phase), and the silica particles constitute the disperse phase distributed over the matrix phase. The hydrophilic outermost layer is superior in abrasion resistance and duration of hydrophilicity. The hydrophilic article is produced by a method including sequential steps of (a) providing a sol mixture comprising a first sol containing a precursor of the titania, a second sol containing a precursor of the amorphous oxide, and a silica colloidal solution containing the silica particles; (b) applying the sol mixture to the substrate, thereby to form thereon a precursory film; and (c) baking the precursory film into the outermost layer.

Claims

1. A hydrophilic article comprising:

(a) a substrate; and

(b) a hydrophilic film formed on said substrate, said film having a hydrophilic outermost layer, said outermost layer comprising;

(1) a titania;

(2) an amorphous oxide in an amount of from 5 to 25 wt % based on a total weight of said outermost layer; and

(3) silica particles having a particle diameter of from 3 to 20 nm.

2. A hydrophilic article according to claim 1, wherein said outermost layer is prepared by a method comprising sequential steps of:

(a) providing a sol mixture comprising a first sol containing a precursor of said titania, a second sol containing a precursor of said amorphous oxide, and a silica colloidal solution containing said silica particles;

(b) applying said sol mixture to said substrate, thereby to form thereon a precursory film; and

(c) baking said precursory film into said outermost layer.

3. A hydrophilic article according to claim 1, wherein said amorphous oxide is a silica.

4. A hydrophilic article according to claim 1, wherein a weight ratio of said amorphous oxide to said titania is from 6:

94 to 13;

84.

5. A hydrophilic article according to claim 1, wherein said silica particles are in an amount of from 10 to 50 wt % based on the total weight of said outermost layer.

6. A hydrophilic article according to claim 1, wherein said silica particles have a particle diameter of from 3 to 15 nm.

7. A hydrophilic article according to claim 6, wherein said silica particles have a particle diameter of from 5 to 10 nm.

8. A hydrophilic article according to claim 1, wherein said outermost layer has a thickness of from 50 to 110 nm.

9. A hydrophilic article according to claim 1, wherein said substrate is made of a soda-lime glass.

10. A hydrophilic article according to claim 9, wherein said hydrophilic film further comprises an interlayer interposed between said substrate and said outermost layer, such that there is prevented a migration of a sodium ion from said substrate to said outermost layer.

11. A hydrophilic article according to claim 10, wherein said interlayer is prepared by a method comprising sequential steps of:

(a) applying a sol containing a silica precursor to said substrate, thereby to form thereon a precursory film; and

(b) baking said precursory film into said interlayer made of a silica.

12. A hydrophilic article according to claim 10, wherein said interlayer has a thickness of from 50 to 110 nm.

13. A hydrophilic article according to claim 1, wherein said titania comprises an anatase-type titania.

14. A hydrophilic article according to claim 1, wherein said hydrophilic article is an automotive window glass pane.

15. A hydrophilic article according to claim 1, wherein said hydrophilic article is an automotive outside mirror.

16. A hydrophilic article according to claim 1, wherein said hydrophilic outermost layer comprises a matrix phase and a disperse phase distributed over said matrix phase, said matrix phase comprising a combination of said titania and said amorphous oxide, said disperse phase comprising said silica particles.

17. A hydrophilic article according to claim 1, wherein said amorphous oxide has a particle diameter that is substantially smaller than that of said silica particles.

18. A method for producing a hydrophilic article having a substrate coated with a hydrophilic film, said hydrophilic film having a hydrophilic outermost layer comprising a titania, an amorphous oxide, and silica particles, said method comprising sequential steps of:

(a) providing a sol mixture comprising a first sol containing a precursor of said titania, a second sol containing a precursor of said amorphous oxide, and a silica colloidal solution containing said silica particles;

(b) applying said sol mixture to said substrate, thereby to form thereon a precursory film; and

(c) baking said precursory film into said outermost layer.

19. A method according to claim 18, wherein the step (c) is conducted at a temperature of from 400 to 850°

C.

20. A method for producing a hydrophilic article, said hydrophilic article having a substrate, a hydrophilic outermost layer formed on said substrate, and an interlayer interposed between said substrate and said hydrophilic outermost layer, said hydrophilic outermost layer comprising a titania, an amorphous oxide, and silica particles, said method comprising steps of:

(a) applying a sol containing a silica precursor to said substrate, thereby to form thereon a first precursory film;

(b) drying said first precursory film into said interlayer made of a silica;

(c) providing a sol mixture comprising a first sol containing a precursor of said titania, a second sol containing a precursor of said amorphous oxide, and a silica colloidal solution containing said silica particles;

(d) applying said sol mixture to said interlayer, thereby to produce a first precursor of said hydrophilic article;

(e) preliminarily baking said first precursor at a first temperature into a second precursor of said hydrophilic article; and

(f) bending said second precursor into said hydrophilic article, while said second precursor is baked at a second temperature that enables said bending of said second precursor.

21. A method according to claim 20, wherein the step (b) is conducted at a temperature of from 150 to 450°

C., and said first and second temperatures of the steps (e) and (f) are from 500 to 600°

C. and from 600 to 750°

C., respectively.