Method to determine the state of charge and remaining life of lithium batteries used in oilfield services applications

• US 6,045,941 A
• Filed: 07/08/1997
• Issued: 04/04/2000
• Est. Priority Date: 07/08/1997
• Status: Expired due to Fees

• Current Assignee: Schlumberger Technology Corporation (Schlumberger NV)
• Original Assignee: Schlumberger Technology Corporation (Schlumberger NV)
• Inventors: Milewits, Marvin
• Primary Examiner(s): Nuzzolillo, Maria
• Assistant Examiner(s): CHANEY, CAROL DIANE
• Application Number:
  US08/889,775
• Time in Patent Office: 1,001 Days
• Field of Search: 429/101, 429/90, 429/91, 429/92, 320/132
• US Class Current: 429/91
• CPC Class Codes: H01M 2200/00 Safety devices for primary or secondary batteries
• CPC Class Codes: H01M 6/14 Cells with non-aqueous electrolyte
• CPC Class Codes: H01M 6/50 Methods or arrangements for servicing or maintenance, e.g. for maintaining operating temperature constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569
• CPC Class Codes: H01M 6/5055 End of discharge indicated by a voltage step

Abstract

The present invention relates to a new method of constructing and interrogating electrochemical cells, especially those having lithium thionyl chloride (Li/SOCl₂) chemistry, that permits rapid estimation of remaining discharge capacity. A preferred embodiment of the present invention employs cells with specially modified anode structures and a method for testing the state of charge and remaining life of these cells, as well as depassivating these cells, prior to their intended use or re-use. The test method can be performed using an inexpensive DC circuit and voltmeter at ambient conditions anytime prior to cell use or re-use. There is also disclosed an oilfield services downhole tool battery having a remaining life indicator comprising a housing containing one or more electrochemical cells having an internal anode means which selectively gets consumed at a predetermined state of discharge thereby creating a step change in the cell output voltage which is imperceptible to the tool while in operation at downhole temperatures, and which is capable of being detected at the surface under ambient temperatures upon administering of a suitable current load enabling the user to determine the remaining battery life at the surface prior to subsequent use or reuse of the battery in downhole oilfield services operations.

Claims

1. An oilfield services downhole tool battery having a remaining life indicator comprising:

a housing containing one or more electrochemical cells having an internal anode means which selectively gets consumed at a predetermined state of discharge thereby creating a step change in the cell'"'"'s output voltage which is greater under ambient temperatures than at downhole temperatures; and

remaining life indicator means for providing an indication of remaining life by detecting the step change in the cell'"'"'s output voltage at ambient temperature upon administering a suitable current load.

2. The oilfield services battery of claim 1 wherein each of said one or more electrochemical cells further comprise:

a) alkali anode means comprising a first member having a first mass and a first surface area exposed to the interior of said cell and a second member having a second mass and a second surface area integrally positioned with respect to said first member such that said first and second anode members comprise a composite structured anode pair, said first and second members being of the same electrochemically active material;

b) oxyhalide cathode means comprising one or more surface members having surface areas coextensive with said exposed surface areas of said anode means;

c) electrolyte means disposed between said coextensive surface areas of said anode means and said cathode means;

d) said anode means, cathode means and electrolyte means being formed of respective materials adapted to provide a substantially constant output voltage at downhole temperatures after depletion of one of said anode members; and

e) said one anode member being depleted prior to said other anode member to produce a step change in said output voltage from a higher substantially constant output voltage to a lower substantially constant output voltage when measured at ambient temperature.

3. The oilfield services battery of claim 2 wherein said first and second anode means comprise hollow cylindrical annular structures in coaxial relationship.

4. The oilfield services battery of claim 1 wherein said anode members are formed from an electrochemically active alkali or alkaline earth metal selected from the group consisting of lithium, sodium, potassium, calcium, their alloys and intermetallic compounds, and combinations thereof.

5. The oilfield services battery of claim 4 wherein the electrolyte means includes an oxyhalide depolarizer together with a Lewis acid and Lewis base solute.

6. The oilfield services battery of claim 5 wherein the oxyhalide depolarizer is selected from the group consisting of thionyl chloride, sulfuryl chloride and phosphoroxy chloride.

7. The oilfield services battery of claim 5 wherein the Lewis acid is aluminum chloride and the Lewis base is lithium chloride.

8. The oilfield services battery of claim 2 wherein said cathode means comprises a cylindrical structure inserted into a hollow cylindrical anode means.

9. The oilfield services battery of claim 2 wherein said cathode means and said electrolyte are liquid thionyl chloride and said anode means is lithium.

10. The oilfield services battery of claim 1 wherein the anode means comprises a continuous structure.

11. The oilfield services battery of claim 1 wherein the anode means comprises at least two anodes contained within individual electrochemical cell containers and coupled in parallel by electrically-connective means through their respective cell containers.

12. The oilfield services battery of claim 1 wherein the anode means comprises at least two anodes which are physically separated and coupled in parallel by electrically-connective means.

13. The oilfield services battery of claim 2 wherein said second anode is positioned behind said first anode and is not exposed to the interior of said cell until said first anode is substantially depleted.

14. The oilfield services battery of claim 2 wherein the mass of said first anode is substantially the same as the mass of said second anode and the surface area of said first anode is two times greater than the surface area of said second anode.

15. The oilfield services battery of claim 2 wherein the mass of said first anode is four times the mass of said second anode and the surface area of said second anode is 0.75 of the surface area of said first anode.

16. The oilfield services battery of claim 2 wherein the mass of said first anode is four times greater than the mass of said second anode and the surface area of said first anode is twice the surface area of said second anode.

19. The oilfield services battery of claim 2 wherein said anode means comprises a cylindrical structure inserted into a hollow cylindrical cathode means.

20. The oilfield services battery of claim 2 wherein said first anode nests behind said second anode and is also exposed to the interior of said cell.

21. The oilfield services battery of claim 2 wherein the mass of said first anode is an arbitrary ratio of the mass of said second anode and the surface area of said first anode is an arbitrary multiplier of the surface area of said second anode.

17. A method of determining the remaining life in an oilfield services battery prior to or after the use or reuse of said battery for downhole oilfield operations comprising the steps of:

a) providing an oilfield services downhole tool battery having a remaining life indicator comprising a housing containing one or more electrochemical cells having an internal anode means which selectively gets consumed at a predetermined state of discharge thereby creating a step change in the cell output voltage which is greater under ambient temperatures than at downhole temperatures and remaining life indicator means capable of detecting the step change in the cell output voltage at ambient temperatures upon administering a suitable current load;

b) interrogating said battery at the surface at ambient temperatures prior to use or reuse sufficient to acquire repeatable loaded voltage values; and

c) comparing the loaded voltage values with predetermined values of voltage versus capacity for said battery to determine whether said step change in output voltage has occurred indicating that a predetermined state of discharge has elapsed.

18. The method of claim 17 wherein the interrogating step further comprises the steps of:

a) connecting said battery to an interrogating device;

b) depassivating said battery by providing to said battery from said interrogating device a sufficient magnitude current pulse for a sufficient length of at a time until repeatable loaded voltage values are observed; and

c) measuring the cell'"'"'s voltage output.

22. An oilfield services downhole tool battery having a remaining life indicator comprising:

a housing;

an electrochemical cell having an internal anode configured to be selectively consumed at a predetermined state of discharge thereby creating a step change in the cell'"'"'s output voltage which is greater under ambient temperatures than under downhole temperatures; and

a remaining life indicator arranged to selectively apply a current load to the cell at ambient temperatures and provide an indication of remaining life by detecting the step change.