Low profile battery and method of making same

• US 6,045,942 A
• Filed: 12/15/1997
• Issued: 04/04/2000
• Est. Priority Date: 12/15/1997
• Status: Expired due to Fees

• Current Assignee: Avery Dennison Corporation
• Original Assignee: Avery Dennison Corporation
• Inventors: Miekka, Frederick Noah, Billester, Stephen E. M.
• Primary Examiner(s): Nuzzolillo, Maria
• Assistant Examiner(s): O MALLEY, JENNIFER L
• Application Number:
  US08/990,898
• Time in Patent Office: 841 Days
• Field of Search: 429/124, 429/127, 429/162, 429/219, 429/220, 429/224, 429/229, 429/231.6, 29/623.1, 29/623.3, 29/623.5
• US Class Current: 429/124
• CPC Class Codes: H01M 6/40 Printed batteries , e.g. thin film batteries

Abstract

An ultra thin primary battery construction is disclosed along with a method for making same. The battery itself is a laminate construction consisting of a polymer film casing, printed thin film electrodes, and an aqueous electrolyte which is in intimate contact with the active surfaces of both electrodes. In this system, the electrodes themselves consist of a non-reactive conductive ink base having active electrode materials embedded into its surface. The anode to cathode electrode geometry may take one of many forms, however for ease of manufacturing, the anode and cathode electrodes face each other in an offset configuration that eliminates the need for a porous separator. The method of manufacture involves first forming the electrodes onto a polymer film followed by adding the appropriate aqueous electrolyte, and finally sealing the battery. The process for forming the electrodes themselves involves printing a polymer film with a layer of conductive ink, sprinkling an excess of active electrode material in powder form onto the wet surface of the freshly printed ink, drying or curing the ink, and finally removing any loose particles from the surface.

Claims

1. A thin film primary battery comprising a non-conductive film substrate, thin film electrodes printed upon the substrate, aqueous electrolyte, and a sealing thin film layer sealing the battery, wherein the thin film electrodes are prepared comprising the steps of printing electrically conductive ink onto said substrate, embedding active electrode material into the wet surface of the printed conductive ink and drying the conductive ink, wherein a common cathodic electrode is employed with two or more chemically different anodic electrodes to allow for multiple voltage outputs from the same battery.

2. The battery of claim 1, wherein the cathodic electrodes and anodic electrodes are printed on separate substrates.

3. The battery of claim 2, wherein the separate substrates are assembled with the electrode sides confronting each other and the electrodes being offset.

4. The battery of claim 1, wherein the cathodic and anodic electrodes are physically spaced by their respective locations on a substrate without a porous separator.

5. The battery of claim 1 wherein the electrodes are stacked atop one another with a porous separator disposed therebetween.

6. The battery of claim 1 wherein the active electrode material for the common cathodic electrode is silver oxide, the active electrode material for one anodic electrode is magnesium, the active electrode material for the other anodic electrode is zinc, and the electrolyte is aqueous potassium hydroxide.

7. The battery of claim 1 wherein said electrically conductive ink is electrically conductive silver based metallic ink.

8. The battery of claim 1 wherein the step of drying the conductive ink includes curing.

9. The battery of claim 1 wherein the step of embedding includes sprinkling active electrode material on the wet electrically conductive ink.

10. The battery of claim 1 wherein the active electrode material is in the form of a powder.

11. The battery of claim 1 wherein the substrate is provided with a pressure sensitive adhesive on the side opposite the electrode.

12. A thin film primary battery comprising a non-conductive film substrate, thin film electrodes printed upon the substrate, aqueous electrolyte, and a sealing thin film layer sealing the battery, wherein the thin film electrodes are prepared comprising the steps of printing electrically conductive ink onto said substrate, embedding active electrode material into the wet surface of the printed conductive ink and drying the conductive ink, wherein a common anodic electrode is employed with two or more chemically different cathodic electrodes to allow for multiple voltage outputs from the same battery.

13. The battery of claim 12 wherein the active electrode material for the common anodic electrode is zinc, the active electrode material for one cathodic electrode is silver oxide, the active electrode material for the other cathodic electrode is copper oxide, and the electrolyte is potassium hydroxide.

14. A thin film battery comprising a pair of confronting non-conductive film substrates, a cathodic thin film electrode printed upon one of the substrates and an anodic thin film electrode printed on the other substrate, the orientation of the anodic and cathodic electrodes on the respective substrates being staggered so that they lie substantially in the same plane and are separated by a gap substantially filled with an aqueous electrolyte disposed between the substrates, wherein a common cathodic electrode is employed with two or more chemically different anodic electrodes to allow for multiple voltage outputs from the same battery.

15. The battery of claim 14, wherein the gap is sized to provide a battery having a specific current limit.

16. The battery of claim 14, wherein the electrodes include an electrically conductive layer of a chemically inactive electrode material having an active metal material embedded therein.

17. A thin film battery comprising a pair of confronting non-conductive film substrates, a cathodic thin film electrode printed upon one of the substrates and an anodic thin film electrode printed on the other substrate, the orientation of the anodic and cathodic electrodes on the respective substrates being staggered so that they lie substantially in the same plane and are separated by a gap substantially filled with an aqueous electrolyte disposed between the substrates, wherein a common anodic electrode is employed with two or more chemically different cathodic electrodes to allow for multiple voltage outputs from the same battery.

18. The battery of claim 17, wherein the gap is sized to provide a battery having a specific current limit.

19. The battery of claim 17, wherein the electrodes include an electrically conductive layer of a chemically inactive electrode material having an active metal material embedded therein.