Semiconducting oxide gas sensors

• US 6,046,054 A
• Filed: 12/09/1997
• Issued: 04/04/2000
• Est. Priority Date: 02/19/1994
• Status: Expired due to Term

• Current Assignee: Life Safety Distribution AG (Honeywell International Inc.)
• Original Assignee: Capteur Sensors & Analysers Ltd. (Honeywell International Inc.)
• Inventors: Dawson, Darryl Hirst, McGeehin, Peter, Moseley, Patrick Timothy, Henshaw, Geoffrey Stephen, Gellman, Laura Jane, Williams, David Edward
• Primary Examiner(s): Soderquist, Arlen
• Application Number:
  US08/987,539
• Time in Patent Office: 847 Days
• Field of Search: 422/90, 422/95, 422/98, 436/106, 436/113, 436/116-122, 436/124, 436/127, 436/128, 436/131, 436/132-134, 436/136-137, 436/139-142, 436/149, 436/151, 73/31.05, 73/31.06, 204/153.13, 204/153.1, 204/153.14, 204/153.16, 338/24, 340/605, 340/634
• US Class Current: 436/121
• CPC Class Codes: G01N 27/12 of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid , for detecting components in the fluid
• CPC Class Codes: Y10T 436/184 Only hydrogen sulfide
• CPC Class Codes: Y10T 436/186 Sulfur dioxide
• CPC Class Codes: Y10T 436/20 Oxygen containing
• CPC Class Codes: Y10T 436/200833 Carbonyl, ether, aldehyde or ketone containing
• CPC Class Codes: Y10T 436/203332 Hydroxyl containing
• CPC Class Codes: Y10T 436/204165 Ethanol
• CPC Class Codes: Y10T 436/204998 Inorganic carbon compounds
• CPC Class Codes: Y10T 436/205831 Carbon monoxide only
• CPC Class Codes: Y10T 436/208339 Fuel/air mixture or exhaust gas analysis
• CPC Class Codes: Y10T 436/21 Hydrocarbon
• CPC Class Codes: Y10T 436/212 Aromatic
• CPC Class Codes: Y10T 436/214 Acyclic [e.g., methane, octane, isoparaffin, etc.]
• CPC Class Codes: Y10T 436/216 Unsaturated [e.g., ethylene, diene, etc.]

Abstract

The selectivity of response of resistive gas sensors to specific gases or vapors is improved by the selection of specified gas-sensitive materials which are not previously known for the applications described, which include detection of hydrocarbons in the presence of CO, H₂ S, SO₂, chlorine, NO₂, CO₂ (especially in low concentrations), CFC'"'"'s, ammonia, free oxygen by determination of partial pressures, and numerous organic gases and vapors.

Claims

1. In the method of detecting the presence of a target gas, wherein said method comprises the steps of exposing a sensor to an atmosphere that may contain said target gas, and measuring the electrical resistance of said sensor, the improvement wherein said sensor includes a sensor element formed of Cr.sub.(2-x) Ti_x O₃, where 0.3 ≦

x≦

0.05, and said target gas is a hydrocarbon other than methane, alcohols, aldehydes, ketones, ethers, esters, hydrogen sulphide, sufphur dioxide or carbon monoxide.

2. In the method claimed in claim 1, the improvement wherein 0.3 ≦

x≦

0.1.

3. In the method as claimed in claim 1, the improvement wherein said sensor element has a microstructure in which the average crystallite diameter and average pore diameter are both smaller than 1 micrometer.

4. In the method as claimed in claim 1, the further improvement wherein said sensor element includes a heating element for heating said sensor element, and electrical connecting means connected to said sensor element and said heating element, said connecting means comprising first connection means connected to said sensor element, and a common connecting means connected to both said sensor element and said heating element.

5. In the method as claimed in claim 4, the improvement wherein one of said elements is overlaid on the other of said elements so that said elements work as two resistors in parallel, said first connection means comprising a further connection common to both said elements.

6. In the method as claimed in claim 1, the improvement wherein said sensor comprises a sensor array, and said sensor element formed of Cr.sub.(2-x) Ti_x O₃, constitutes a first sensor in said sensor array, and at least one further sensor element having a characteristic response different from the response of said first sensor.

7. In the method as claimed in claim 6, the further improvement wherein said further sensor element is formed of Fe.sub.(1-y) Cr_y NbO₄, where 0≦

y≦

1 for distinguishing between ammonia and organic vapor.

8. In the method as claimed in claim 6, the further improvement wherein said further sensor element is formed of CrNbO₄.

9. In the method as claimed in claim 6, the improvement wherein said further sensor element is formed of SnO₂.

10. In the method as claimed in claim 6, the further improvement wherein said further sensor has a sensor element formed of BaSn.sub.(1-z) Sb₂ O₃ where 0≦

z≦

0.1, and said first sensor element is a sensor responsive to reactive an/or flammable gases but substantially non-responsive to carbon dioxide at low concentrations to which said further sensor shows a significant response.

11. In the method as claimed in claim 6, the improvement wherein said array includes a humidity sensor arranged for mitigating the effects of relative humidity.