Liquid-crystalline resin and thermoplastic resin composition

• US 6,046,300 A
• Filed: 12/18/1998
• Issued: 04/04/2000
• Est. Priority Date: 12/26/1997
• Status: Expired due to Term

• Current Assignee: Toray Industries Incorporated
• Original Assignee: Toray Industries Incorporated
• Inventors: Sugimura, Masahiro, Makabe, Yoshiki, Umetsu, Hideyuki
• Primary Examiner(s): BOYKIN, TERRESSA M
• Application Number:
  US09/215,075
• Time in Patent Office: 473 Days
• Field of Search: 528/176, 528/193, 528/271, 528/272
• US Class Current: 528/176
• CPC Class Codes: C08G 63/60 derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds
• CPC Class Codes: C08L 101/00 Compositions of unspecified macromolecular compounds
• CPC Class Codes: C08L 2666/18 Polyesters or polycarbonates according to C08L67/00 - C08L69/00; Derivatives thereof
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers

Abstract

A liquid-crystalline resin with ester bonds, which has a hydroxyl terminal concentration of not smaller than 15×10^-6 equivalents/g, and a thermoplastic resin composition comprising the liquid-crystalline resin.

Claims

1. A liquid-crystalline resin having ester bonds, which has a hydroxyl terminal concentration of not smaller than about 15×

10^-6 equivalents/g and up to 1000×

10^-6 equivalents/g.

2. The liquid-crystalline resin as claimed in claim 1, which contains p-hydroxybenzoic acid residues.

3. The liquid-crystalline resin as claimed in claim 1, which contains ethylenedioxy units.

4. The liquid-crystalline resin as claimed in claim 1, which comprises a liquid-crystalline polyester having structural units of the following (I), (III) and (IV), and/or a liquid-crystalline polyester having structural units of the following (I), (II), (III) and (IV):

##STR9## wherein R1 represents at least one or more groups selected from the following group consisting of;

##STR10## R2 represents at least one or more groups selected from the following group consisting of;

##STR11## X represents a hydrogen atom or a chlorine atom.

5. The liquid-crystalline resin as claimed in claim 4, wherein the total of the structural units (I) and (II) is 35 to 95 mol % of the total of the structural units (I), (II) and (III), the structural units (III) are 5 to 65 mol % of the total of the structural units (I), (II) and (III), the molar ratio of the structural units (I) to (II), (I)/(II), is 70/30 to 95/5, and the structural units (IV) are substantially equimolar to the total of the structural units (II) and (III).

6. A liquid-crystalline resin composition comprising 100 parts by weight of the liquid-crystalline resin of claim 1, and 5 to 300 parts by weight of a filler.

7. A thermoplastic resin composition comprising 100 parts by weight of a thermoplastic resin and 0.01 to 30 parts by weight of the liquid-crystalline resin of claim 1.

8. A thermoplastic resin composition as claimed in claim 7, further comprising 5 to 300 parts by weight of a filler relative to 100 parts by weight of the total amounts of the thermoplastic resin and the liquid-crystalline resin.

9. The thermoplastic resin composition as claimed in claim 7, wherein the liquid-crystalline resin has a number-average molecular weight of not larger than 5000.

11. Moldings of the thermoplastic resin composition of claim 7.

12. Films of the thermoplastic resin composition of claim 7.

13. Fibers of the thermoplastic resin composition of claim 7.

14. The thermoplastic resin composition of claim 7, further comprising not more than about 100 ppm by weight of red phosphorus.

15. The thermoplastic resin composition of claim 14, further comprising by weight about 0.01 to about 20 percent of at least one metal oxide relative to said liquid-crystalline resin.

16. The thermoplastic resin composition of claim 7, further comprising by weight about 0.01 to about 10 percent of at least one fluorine resin relative to said liquid-crystalline resin.

17. The liquid-crystalline resin of claim 1, produced by a process comprising:

a) carrying out a polycondensation reaction of appropriate reactants to produce a conventional polyester; and

b) adding to said polyester by weight about 0.01 to about 5 percent of at least one substance selected from the group consisting of water and glycol.

18. The liquid-crystalline resin of claim 17, further processed by melting and pelletizing in a kneader or extruder at a temperature in a range of about 180°

C. to about 380°

C.

19. The liquid-crystalline resin of claim 1, wherein said number-average molecular weight is at least 500.

10. A thermoplastic resin composition comprising 100 parts by weight of a thermoplastic resin and 0.01 to 30 parts by weight of a liquid-crystalline resin having a hydroxyl terminal concentration of not smaller than 15×

10^-6 equivalents/g, of which the tensile strength as measured according to the method of ASTM D638 (for a sheet sample of the composition having a thickness of 1/8 inches) is at least 5% higher than that of the thermoplastic resin not combined with the liquid-crystalline resin.

20. A liquid-crystalline resin having ester bonds, which is produced by deacetylating polycondensation, which has a hydroxyl terminal concentration of not smaller than 1.5×

10^-6 equivalents/g and up to 1000×

10^-6 equivalents/g.