Process for the separation of gaseous mixtures by adsorption with pressure variation

• US 6,051,052 A
• Filed: 11/14/1997
• Issued: 04/18/2000
• Est. Priority Date: 11/15/1996
• Status: Expired due to Fees

• Current Assignee: L'Air Liquide Societe Anonyme Pour L'Etude et L'Exploitation Des Procedes Georges Claude (L'Air Liquide SA)
• Original Assignee: L'Air Liquide Societe Anonyme Pour L'Etude et L'Exploitation Des Procedes Georges Claude (L'Air Liquide SA)
• Inventors: Petit, Pierre, Monereau, Christian, Andreani, Philippe
• Primary Examiner(s): Spitzer, Robert H.
• Application Number:
  US08/970,431
• Time in Patent Office: 886 Days
• Field of Search: 95/96-98, 95/100-105, 95/130, 96/108, 96/109, 96/115, 96/130, 96/144
• US Class Current: 95/97
• CPC Class Codes: B01D 2256/12 Oxygen
• CPC Class Codes: B01D 2259/40016 with three sub-steps
• CPC Class Codes: B01D 2259/40075 More than ten
• CPC Class Codes: B01D 2259/40079 Co-current
• CPC Class Codes: B01D 2259/40081 Counter-current
• CPC Class Codes: B01D 53/0446 Means for feeding or distributing gases
• CPC Class Codes: B01D 53/053 with storage or buffer vessel

Abstract

A separation process, involving an adsorber containing at least one adsorbent with an inlet and outflow, involves the following stages of the cycle:--stage I, repressurization from the low pressure of the cycle;--stages II and III during one of which the high pressure of the cycle is reached; and stage IV, depressurization/purging, during which the low pressure of the cycle is reached. Each stage (I to IV) involves a fixed gas flow (F) at one end of the adsorber and a free gas flow (λ) at the other end of the adsorber, the fixed flows (F) addressing the inlet (E) and outlet (F) ends of the adsorber from one stage (I to IV) to the next. The process is particularly applicable to the production of oxygen from air.

Claims

1. A method for the separation of a gaseous mixture by adsorption under pressure variation between a cycle high pressure and a cycle low pressure in an adsorption unit including at least one adsorber containing at least one adsorbent and having an inlet and an outlet, using a repetitive cycle consisting of the following sequential successive stages:

stage I, repressurization from the low pressure of the cycle,

stages II and III, during one of which the high pressure of the cycle is reached,

stage IV, during which the low pressure of the cycle is reached, and including at least a sub-stage of depressurization and a subsequent sub-stage of purge/elution

wherein each stage (I to IV) involves a fixed gas flow at one end of the adsorber and a free gas flow at the other end of the adsorber, the fixed flows addressing, in alternation, the inlet and outlet of the adsorber from one stage (I to IV) to the next.

2. The method of claim 1, wherein the fixed flows are inflows for stages I and II and outflows for stages III and IV.

3. The method of claim 2, wherein the high pressure of the cycle is reached in stage III.

4. The method claim 2, wherein the fixed flow is a co-current inflow for stage II and comes from a volume of the gaseous mixture to be separated.

5. The method of claim 4, wherein a fixed inflow coming from a capacity enters counter-currently the adsorber at stage I.

6. The method of claim 5, wherein said capacity is fed by a fixed co-current outflow, during stage III.

7. The method of claim 5, wherein said capacity is fed by a free co-current outflow, during at least the final sub-stage of stage II.

8. The method of claim 2, wherein stage IV includes a final sub-stage with a free inflow entering counter-currently and coming from a capacity.

9. The method of claim 8, wherein said capacity is fed by a fixed co-current outflow, during stage III.

10. The method of claim 2, wherein the free flow in stage III is not nil.

11. The method of claim 2, wherein the gaseous mixture consists essentially of nitrogen and oxygen.

12. The method of claim 1, wherein each stage (I to IV) is divided into at least a first and a second sub-stage for the free flow which is, for each first and second sub-stage, selected from the flow group consisting of in, out and practically nil flows.

13. The method of claim 12, wherein each stage (I to IV) includes at least a third sub-stage for the free flow.

14. The method of claim 1, wherein each sub-stage has substantially a same duration.

15. The method of claim 1, wherein the cycle has a duration which is less than 200 seconds.

16. A method for the separation of a gaseous mixture by adsorption under pressure variation in an adsorption apparatus including at least one adsorber containing at least one adsorbent and having an inlet and an outlet, using a repetitive cycle consisting of the following sequential successive stages:

stage I, repressurization from a low pressure of the cycle,

stages II and III, during one of which a high pressure of the cycle is reached,

stage IV, depressurization/purging, during which the low pressure of the cycle is reached,

wherein each stage (I to IV) involves a fixed gas flow at one end of the adsorber and a free gas flow at the other end of the adsorber, the fixed flows addressing, in alternation, the inlet and outlet of the adsorber from one stage to the next, each stage divided into at least two sub-stages for the free flow, which is, for each sub-stage, selected from the flow group consisting of in, out and practically nil flows.

17. The method of claim 16, wherein the high pressure of the cycle is reached in stage III.

18. The method of claim 16, wherein the fixed flows are inflows for stages I and II and outflows for stages III and IV.

19. The method of claim 16, wherein each stage is divided into three sub-stages for the free flow.

20. The method of claim 16, wherein the fixed flow in stage II is an inflow from a volume of the gaseous mixture to be separated.

21. The method of claim 16, wherein the gaseous mixture to be separated is air and the fixed outflow in stage III is oxygen.