Waterless lithographic printing plates
First Claim
1. A media/fluid material set for use in preparing a waterless lithographic printing plate, comprising:
- (a) a media comprising a support that bears a hydrophilic receiving surface; and
,(b) a fluid material comprising a liquid carrier medium and a reactive component, which reactive component comprises a transition metal complex of a fluorinated organic acid, said reactive component reacting after application of said fluid material on said receiving surface, thereby forming an ink-releasing layer on said receiving surface;
wherein the hydrophilic receiving surface of said support further comprises a catalyst to increase the rate of reaction.
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Accused Products
Abstract
Provided is a media-fluid material set which comprises a media with a support that bears a hydrophilic receiving surface together with a fluid material comprising a liquid carrier medium and a reactive transition metal complex of a fluorinated organic acid. After application of the fluid material to the hydrophilic receiving surface, the reactive complex reacts to form an ink-releasing layer. Such a media-fluid material set can be advantageously used in preparing waterless lithographic printing plates with ink-releasing layers comprising such fluorinated reaction products. Also provided are imaged waterless lithographic printing plates with such ink-releasing layers made by an ink jet printing application or by laser-induced thermal ablation, and methods of making such waterless lithographic printing plates.
9 Citations
89 Claims
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1. A media/fluid material set for use in preparing a waterless lithographic printing plate, comprising:
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(a) a media comprising a support that bears a hydrophilic receiving surface; and
,(b) a fluid material comprising a liquid carrier medium and a reactive component, which reactive component comprises a transition metal complex of a fluorinated organic acid, said reactive component reacting after application of said fluid material on said receiving surface, thereby forming an ink-releasing layer on said receiving surface; wherein the hydrophilic receiving surface of said support further comprises a catalyst to increase the rate of reaction. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21)
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22. An ink-releasing plate for use in preparing a waterless lithographic printing plate, comprising:
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(a) a support that bears a hydrophilic surface; and
,(b) an ink-releasing layer overlying the hydrophilic surface of said support;
said ink-releasing layer comprising a reaction product of a transition metal complex of a fluorinated organic acid;
wherein said ink-releasing layer further is capable of being imaged using laser-induced thermal ablation, which ablation removes said ink-releasing layer in exposed regions thereof to thereby reveal the hydrophilic surface of said support;wherein said ink-releasing layer further comprises a sensitizer to increase the rate of imaging by said ablation. - View Dependent Claims (23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34)
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35. An imaged waterless lithographic printing plate comprising:
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(a) a support that bears a hydrophilic surface in the ink-receiving areas of said support; and
,(b) an ink-releasing layer in a desired imagewise pattern overlying the hydrophilic surface of said support;
said layer comprising a reaction product of a transition metal complex of a fluorinated organic acid;wherein said imaged plate is prepared by the steps of providing a lithographic plate blank comprising said support and forming an image on the hydrophilic surface of said support with an ink jet printer in an ink jet printing application, wherein an ink jet fluid marking material utilized in said ink jet printer comprises a liquid carrier medium and a reactive component, which reactive component comprises a transition metal complex of a fluorinated organic acid, said reactive component reacting upon exposure to an energy source after ink jet printing, thereby forming said ink-releasing layer in said desired imagewise pattern overlying the hydrophilic surface of said support. - View Dependent Claims (36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47)
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48. A method of preparing an ink-releasing plate for use in preparing a waterless lithographic printing plate, said method comprising the steps of:
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(a) providing a support that bears a hydrophilic receiving surface; (b) applying a fluid material comprising a liquid carrier medium and a reactive component, which reactive component comprises a transition metal complex of a fluorinated organic acid, to said receiving surface; (c) removing said liquid carrier medium; and
,(d) reacting said reactive component, thereby forming an ink-releasing layer on said receiving surface; wherein said fluid material of step (b) is an ink jet fluid marking material and the application of said fluid material to said receiving surface in step (b) is carried out by an ink jet printing application. - View Dependent Claims (49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59)
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- 60. A method of preparing an imaged waterless lithographic printing plate, comprising providing a lithographic plate blank having a support that bears a hydrophilic receiving surface and forming an image on the hydrophilic receiving surface of said support with an ink jet printer in an ink jet printing application, wherein an ink jet fluid marking material utilized in said ink jet printer comprises a liquid carrier medium and a reactive component, which reactive component comprises a transition metal complex of a fluorinated organic acid, said reactive component reacting upon exposure to an energy source after ink jet printing, thereby forming an ink-releasing layer in a desired pattern on said support.
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76. A method of preparing an imaged waterless lithographic printing plate, comprising the steps of:
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(a) providing a support that bears a hydrophilic receiving surface; (b) applying a fluid material comprising a liquid carrier medium and a reactive component, which reactive component comprises a transition metal complex of a fluorinated organic acid, to said receiving surface; (c) removing said liquid carrier medium; (d) reacting said reactive component, thereby forming an ink-releasing layer on said receiving surface; and
,(e) exposing said layer to laser-induced thermal ablation in a desired imagewise pattern, thereby removing said layer in the exposed regions thereof to thereby reveal the hydrophilic surface of said support in said desired imagewise pattern. - View Dependent Claims (77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88, 89)
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Specification