Photocatalytically-activated self-cleaning appliances

• US 6,054,227 A
• Filed: 07/23/1997
• Issued: 04/25/2000
• Est. Priority Date: 03/14/1997
• Status: Expired due to Fees

• Current Assignee: PPG Industries Incorporated (Nouryon BV)
• Original Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Inventors: Heilman, Richard A., Greenberg, Charles B.
• Primary Examiner(s): Jones, Deborah
• Assistant Examiner(s): STEIN, STEPHEN J
• Application Number:
  US08/899,265
• Time in Patent Office: 1,007 Days
• Field of Search: 428/469, 428/471, 428/689, 428/699, 428/701, 428/472, 428/432, 428/333, 428/535, 428/702, 502/103, 502/300, 502/2, 252/62.3, 126/19 R, 126/273 R, 427/585, 427/236, 427/237, 427/239
• US Class Current: 428/701
• CPC Class Codes: B01J 35/30 characterised by their physical properties
• CPC Class Codes: C03C 17/23 Oxides C03C17/02 takes precedence
• CPC Class Codes: C03C 17/2456 Coating containing TiO2
• CPC Class Codes: C03C 17/256 Coating containing TiO2
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 2217/21 Oxides
• CPC Class Codes: C03C 2217/212 TiO2
• CPC Class Codes: C03C 2217/229 Non-specific enumeration
• CPC Class Codes: C03C 2217/71 Photocatalytic coatings
• CPC Class Codes: C03C 2218/112 by spraying
• CPC Class Codes: C03C 2218/113 by sol-gel processes
• CPC Class Codes: C03C 2218/152 by cvd
• CPC Class Codes: C03C 2218/154 by sputtering
• CPC Class Codes: C03C 2218/156 by magnetron sputtering

Abstract

An appliance is rendered self-cleaning of accumulated organic contaminants on one or more surfaces of the appliance, by coating such surfaces of the appliance with a photocatalytically-activated self-cleaning coating. Upon exposing such coated surfaces to radiation of the appropriate wavelength, for a sufficient interval of time, at least a portion of the organic contaminants present on the photocatalytically-activated self-cleaning coating are removed. The coated surface is thereby cleaned without the need of manual effort or high temperatures. The radiation is generally actinic radiation, and more particularly includes ultraviolet radiation.

Claims

1. A self-cleaning appliance comprising:

an appliance having at least one surface over which organic contaminants are expected to accumulate and a photocatalytically-activated self-cleaning coating of photocatalytically-activated self-cleaning oxides essentially free of a binder formed on the at least one surface from sol-gel, spray pyrolysis, chemical vapor deposition, and magnetron sputtering vacuum deposition over said surface.

2. The self-cleaning appliance of claim 1 wherein said photocatalytically-activated self-cleaning coating is a metal oxide selected from the group consisting of titanium oxides, iron oxides, silver oxides, copper oxides, tungsten oxides, aluminum oxides, silicon oxides, zinc oxides, zinc stannates, molybdenum oxides, strontium titanate and mixtures thereof.

3. The self-cleaning appliance of claim 2 wherein said metal oxide is a titanium oxide selected from the group consisting of anatase titanium dioxide, rutile titanium dioxide, brookite titanium dioxide and mixtures thereof.

4. The self-cleaning appliance of claim 3 wherein said self-cleaning coating is within the range of about 200 to 5000 Angstroms thick.

5. The self-cleaning appliance of claim 4 wherein said self-cleaning coating is at least about 500 Angstroms thick.

6. The self-cleaning appliance of claim 1 wherein said self-cleaning coating has a photocatalytically-activated self-cleaning activity reaction rate of at least about 2×

10^-3 cm^-1 min^-1.

11. The self-cleaning appliance of claim 1 wherein said self-cleaning coating is photocatalytically-activated to be self-cleaning upon irradiation with ultraviolet radiation.

14. The self-cleaning appliance of claim 1 further comprising a plurality of said surfaces, wherein said surfaces are the interior surfaces of a closable housing formed from five integrally connected walls and a door, wherein said self-cleaning coating is deposited over said surfaces.

15. The self-cleaning appliance of claim 14 wherein said appliance is an oven.

16. The oven of claim 15 wherein said self-cleaning coating is photocatalytically-activated to be self-cleaning upon irradiation with ultraviolet radiation.

17. The oven of claim 16 further comprising a means for irradiating said self-cleaning coating with ultraviolet radiation.

18. The oven of claim 17 wherein said ultraviolet radiation means is integral with said appliance.

7. A self-cleaning appliance comprising:

an appliance having at least one surface over which organic contaminants are expected to accumulate;

a photocatalytically-activated self-cleaning coating of photocatalytically-activated self-cleaning oxides formed on the at least one surface from sol-gel, spray pyrolysis, chemical vapor deposition, or magnetron sputtering vacuum deposition over said surface; and

a diffusion barrier layer between said surface and said self-cleaning coating.

8. The self-cleaning appliance of claim 7 wherein said diffusion barrier layer functions as a sodium ion diffusion barrier layer, wherein said sodium ion diffusion barrier layer is a metal oxide selected from the group consisting of amorphous metal oxides, crystalline metal oxides and mixtures thereof.

9. The self-cleaning appliance of claim 8 wherein said sodium ion diffusion barrier layer is selected from the group consisting of cobalt oxides, chromium oxides, iron oxides, tin oxides, silicon oxides, titanium oxides, zirconium oxides, fluorine doped tin oxides, aluminum oxides, magnesium oxides, zinc oxides, magnesium/aluminum oxides, zinc/tin oxides and mixtures thereof.

10. The self-cleaning appliance of claim 7 wherein said diffusion barrier layer is at least about 100 Angstroms thick.

12. A self-cleaning appliance comprising:

an appliance having at least one surface over which organic contaminants are expected to accumulate;

a photocatalytically-activated self-cleaning coating of photocatalytically-activated self-cleaning oxides formed on the at least one surface from sol-gel, spray pyrolysis, chemical vapor deposition, or magnetron sputtering vacuum deposition over said surface; and

a means for irradiating said self-cleaning coating with ultraviolet radiation.

13. The self-cleaning appliance of claim 12 wherein said ultraviolet radiation means is integral with said appliance.

19. A method of making a self-cleaning appliance comprising the steps of:

assembling a plurality of component parts of said appliance to form said appliance;

identifying surfaces of said component parts on which organic contaminants are expected to accumulate;

selecting at least a portion of said identified surfaces to be photocatalytically self-cleaning;

forming on said surface a photocatalytically-activated self-cleaning coating of photocatalytically-activated self-cleaning oxides formed from sol-gel, spray pyrolysis, chemical vapor deposition, or magnetron sputtering vacuum deposition over said selected surfaces.

20. The method of claim 19 wherein said identifying, selecting and forming steps are practiced prior to said assembling step.

21. The method of claim 19 wherein said identifying, selecting and forming steps are practiced subsequent to said assembling step.

22. The method of claim 19 wherein said self-cleaning coating is formed over said selected surfaces by a process selected from the group consisting of chemical vapor deposition, spray pyrolysis and magnetron sputter vacuum deposition.

23. The method of claim 22 wherein said self cleaning coating is a metal oxide selected from the group consisting of titanium oxides, iron oxides, silver oxides, copper oxides, tungsten oxides, aluminum oxides, silicon oxides, zinc oxides, zinc stannates, molybdenum oxides, strontium titanate and mixtures thereof.

24. The self-cleaning appliance of claim 23 wherein said metal oxide is a titanium oxide selected from the group consisting of anatase titanium dioxide, rutile titanium dioxide, brookite titanium dioxide and mixtures thereof.

25. A self-cleaning appliance comprising:

an appliance having at least one surface over which organic contaminants are expected to accumulate and

a photocatalytically-activated self-cleaning coating over said surface, and

a diffusion barrier layer between said surface and said self-cleaning coating that functions as a sodium ion diffusion barrier layer, wherein said sodium ion diffusion barrier layer is a metal oxide selected from the group consisting of crystalline metal oxides, amorphous metal oxides other than titanium oxide, zirconium oxide and titanium zirconium oxides, and mixtures thereof.

26. A self-cleaning appliance comprising:

an appliance having at least one surface over which organic contaminants are expected to accumulate and

a photocatalytically-activated self-cleaning coating over said surface, and

a diffusion barrier layer between said surface and said self-cleaning coating that functions as a sodium ion diffusion barrier layer, wherein said sodium ion diffusion barrier layer is a metal oxide selected from the group consisting of cobalt oxides, chromium oxides, iron oxides, tin oxides, silicon oxides, fluorine doped tin oxides, aluminum oxides, magnesium oxides, zinc oxides, magnesium/aluminum oxides, zinc/tin oxides and mixtures thereof and mixtures with titanium oxide, zirconium oxide and titanium and zirconium oxides.