Pigment composition and aqueous pigment dispersion prepared therefrom

• US 6,056,814 A
• Filed: 11/17/1998
• Issued: 05/02/2000
• Est. Priority Date: 12/08/1997
• Status: Expired due to Term

• Current Assignee: TOYO Ink Manufacturing Company Limited (artience Co. Ltd.)
• Original Assignee: TOYO Ink Manufacturing Company Limited (artience Co. Ltd.)
• Inventors: Chiba, Ataru, Kato, Mikiya, Tsuchida, Junichi
• Primary Examiner(s): GREEN, ANTHONY J
• Application Number:
  US09/192,562
• Time in Patent Office: 532 Days
• Field of Search: 106/412, 106/499, 106/493, 106/494, 106/495, 106/496, 106/497, 106/498, 540/122
• US Class Current: 106/412
• CPC Class Codes: C09B 67/0002 Grinding; Milling with solid grinding or milling assistants
• CPC Class Codes: C09B 67/0016 of phthalocyanines
• CPC Class Codes: C09B 67/0021 Flushing of pigments

Abstract

The present invention provide a pigment composition and a method for producing same at low cost, which has the same or more excellent quality compared with those produced by a salt milling process which has been commonly used. The pigment composition is produced by dry-milling a pigment in the presence of a surfactant and a water-soluble resin, said surfactant and said water-soluble resin being contained in amounts of 1 to 20% by weight and 2 to 50% by weight respectively based on an amount of the pigment. The pigment composition according to the present invention is readily dispersed into an aqueous system to obtain an aqueous pigment dispersion.

Claims

1. A pigment composition in a powder form produced by dry-milling a pigment in the presence of a surfactant and a water-soluble resin, said surfactant and said water-soluble resin being contained in amounts of 1 to 20% by weight and 2 to 50% by weight respectively based on an amount of the pigment,

wherein the surfactant has a property of improving the affinity of the pigment and the water-soluble resin,

wherein the water-soluble resin has a property of coating and adhering to the surface of the pigment, and

wherein the pigment has a property of being dry-millable.

2. The pigment composition according to claim 1, wherein said surfactant is an aromatic compound to which an ethylene oxide is added.

3. The pigment composition according to claim 1, wherein said water-soluble resin has an acid group and is soluble in water in the presence of an alkali.

4. The pigment composition according to claim 1, wherein said water-soluble resin is a solid resin.

5. The pigment composition according to claim 1, wherein said pigment is a crude pigment.

6. The pigment composition according to claim 1, wherein said pigment is a condensed polycyclic pigment.

7. The pigment composition according to claim 6, wherein said condensed polycyclic pigment comprises a copper phthalocyanine.

8. The pigment composition according to claim 1, wherein the pigment has particle surfaces thereof coated with the surfactant and the water-soluble resin and has an average particle diameter of 10-300 nm.

9. An aqueous pigment dispersion produced by dispersing the pigment composition of claim 1 in water, wherein the pigment has an average particle diameter of between 10 and 300 nm.

10. An aqueous pigment dispersion produced by dispersing the pigment composition of claim 3 in water in the presence of an alkali, wherein the pigment has an average particle diameter of between 10 and 300 nm.

11. The pigment composition according to claim 1, wherein said dry-milling is carried out in the presence of heat.

12. The pigment composition according to claim 11, wherein said pigment is treated under heat at temperatures between 30 and 150°

C. simultaneously when said dry-milling is carried out.

13. A method for producing a pigment composition in a powder form, said method comprising the steps of:

(a) dry-milling a pigment in the presence of a surfactant and a water-soluble resin to obtain a milled substance, the surfactant and the water-soluble resin being contained in amounts of 1 to 20% by weight and 2 to 50% by weight respectively based on an amount of said pigment,

wherein the surfactant has a property ot improving the affinity of the pigment and the water-soluble resin,

wherein the water-soluble resin has a property of coating and adhering to the surface of the pigment, and

wherein the pigment has a property of being dry-millable; and

(b) carrying, out the dry-milling in the presence of heat, and/or heating the milled substance after the dry-milling.

14. The method according to claim 13, wherein said pigment is treated under heat at temperatures between 30 and 150°

C. simultaneously when said dry-milling is carried out.

15. The method according to claim 13, wherein said milled substance is treated under heat at temperatures between 50 and 150°

C. after said dry-milling is carried out.

16. The method according to claim 13, wherein said dry-milling is performed using a milling apparatus selected from the group consisting of an attritor, a ball mill, and a vibrating mill.

17. The method according to claim 13, wherein said dry-milling is performed in the absence of any water-soluble inorganic salts.

18. The method according to claim 13, wherein said dry-milling step (a) comprises:

(1) dry-milling said pigment in the presence of said water-soluble resin and in the absence of said surfactant to prepare an intermediate milled substance; and

consecutively,

(2) further dry-milling said intermediate milled substance after said surfactant is added to said intermediate milled substance to obtain said milled substance.

19. The method according to claim 13, wherein said surfactant is an aromatic compound to which an ethylene oxide is added.

20. The method according to claim 13, wherein said water-soluble resin has an acid group and is soluble in water in the presence of an alkali.

21. The method according to claim 13, wherein said water-soluble resin is a solid resin.

22. The method according to claim 13, wherein said pigment is a crude pigment.

23. The method according to claim 13, wherein said pigment is a condensed polycyclic pigment.

24. The method according to claim 23, wherein said condensed polycyclic pigment comprises a copper phthalocyanine.

25. A method for preparing an aqueous pigment dispersion comprising a step of dispersing the pigment composition produced by the method of claim 13 in water.

26. The method according to claim 25, wherein said dispersion in water is performed in the presence of an alkali.