Epoxy/thermoplastic photocurable adhesive composition

• US 6,057,382 A
• Filed: 05/01/1998
• Issued: 05/02/2000
• Est. Priority Date: 05/01/1998
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Karim, Naimul, George, Clayton A., Meyer, Christopher M.
• Primary Examiner(s): Seidleck, James J.
• Assistant Examiner(s): McClendon, Sanza L.
• Application Number:
  US09/070,971
• Time in Patent Office: 732 Days
• Field of Search: 522/113, 522/122, 522/134, 522/143, 522/100, 522/102, 524/430, 524/379, 524/388, 525/107, 523/457, 523/420
• US Class Current: 522/122
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/22 Macromolecular compounds not provided for in C08L2666/16 - C08L2666/20
• CPC Class Codes: C08L 63/00 Compositions of epoxy resins; Compositions of derivatives of epoxy resins
• CPC Class Codes: C09J 131/04 Homopolymers or copolymers of vinyl acetate
• CPC Class Codes: C09J 163/00 Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
• CPC Class Codes: Y10T 428/31511 Of epoxy ether
• CPC Class Codes: Y10T 428/31573 Next to addition polymer of ethylenically unsaturated monomer
• CPC Class Codes: Y10T 428/31587 Hydrocarbon polymer [polyethylene, polybutadiene, etc.]

Abstract

A curable composition comprising a) a curable epoxy resin, a thermoplastic ethylene-vinyl acetate copolymer resin, and an effective amount of a photocatalyst for the curable epoxy resin, wherein the composition is free from hydrocarbon polyolefins and wherein the sum of a) and b) is 100 weight percent.

Claims

1. A curable composition formed by mixing components comprising:

a) from about 30 to about 70 weight percent of a curable epoxy resin;

b) from about 30 to about 70 weight percent of a thermoplastic ethylene-vinyl acetate copolymer resin containing at least 40 percent by weight vinyl acetate; and

c) an effective amount of a sulfonium or cationic organometallic salt photocatalyst for the curable epoxy resin, such that the total of components a) and b) is 100 weight percent and wherein the composition is free from hydrocarbon polyolefins and solvent and is a homogeneous mixture.

2. The curable composition according to claim 1 wherein said composition is a molten mixture.

3. The curable composition of claim 1 further comprising up to 50 percent by volume of one or more additives that alter the physical characteristics of the resulting cured composition.

4. The curable composition of claim 3 wherein the one or more additives comprises aluminum oxide.

5. The curable composition according to claim 1 wherein said composition is an unsupported film.

6. The curable composition of claim 1 wherein said composition is an adhesive film used in a tape or a protected film.

7. The curable composition according to claim 6 provided in a roll construction.

8. The curable composition according to claim 1 wherein the photocatalyst is a cationic organometallic salt.

9. The curable composition according to claim 10 wherein the cationic organometallic salt is selected from the group consisting of (η

⁶ -xylenes (mixed isomers))(η

⁵ -cyclopentadienyl)Fe⁺¹ SbF₆^-, (η

⁶ -xylenes (mixed isomers))(η

⁵ -cyclopentadienyl)Fe⁺¹ PF₆^-, (η

⁶ -xylene)(η

⁵ -cyclopentadienyl)Fe⁺¹ SbF₆^-, (η

⁶ -mesitylene)(η

⁵ -cyclopentadienyl)Fe⁺¹ SbF₆^- and mixtures thereof.

10. The curable composition according to claim 1 wherein said curable epoxy resin comprises at least one of an aliphatic, alicyclic, aromatic, and heterocyclic polyepoxide.

11. The curable composition of claim 1 wherein said composition is bonded to a substrate and cured.

12. The cured composition of claim 13 wherein said substrate is a metal or a polymer.

13. The curable composition according to claim 6 wherein said tape is bonded to a substrate and cured.

15. The curable composition of claim 1 wherein the composition further comprises a hydroxyl-containing material for retarding the cure rate.

14. A curable composition comprising an homogenous molten mixture containing:

a) from about 40 to about 60 weight percent of a curable epoxy resin;

b) from about 40 to about 60 weight percent of a thermoplastic ethylene-vinyl acetate copolymer resin wherein said copolymer contains at least 50 percent by weight vinyl acetate; and

c) an effective amount of an onium salt or a cationic organometallic salt photocatalyst for the curable epoxy resin, such that the total of components a) and b) is 100 weight percent, the components a), b) and c) are a homogeneous mixture, and wherein the composition is free from hydrocarbon polyolefins and solvent.