Optical film with increased gain at non-normal angles of incidence

• US 6,057,961 A
• Filed: 02/28/1997
• Issued: 05/02/2000
• Est. Priority Date: 02/29/1996
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Weber, Michael F., Ouderkirk, Andrew J., Nevitt, Timothy J., Stover, Carl A., Allen, Richard C., Majumdar, Biswaroop, Carlson, Lockwood W., Kotz, Arthur L.
• Primary Examiner(s): Schuberg, Darren E.
• Application Number:
  US08/807,930
• Time in Patent Office: 1,159 Days
• Field of Search: 359/491, 359/492, 359/494, 359/495, 359/500, 359/599, 349/87, 349/96, 349/194
• US Class Current: 359/489.12
• CPC Class Codes: G02B 5/3008 comprising dielectric particles, e.g. birefringent crystals embedded in a matrix
• CPC Class Codes: G02B 5/305 including organic materials, e.g. polymeric layers
• CPC Class Codes: G02B 5/3083 Birefringent or phase retarding elements G02B5/3008, G02B5/3016 take precedence; systems for polarisation control G02B27/286; manufacturing phase modulating patterns by lithographic processes G03F7/001
• CPC Class Codes: G02F 1/133545 Dielectric stack polarisers

Abstract

An optical film is provided which exhibits increased gain at nonnormal angles of incidence and which comprises a disperse phase of polymeric particles disposed within a continuous birefringent matrix. The film is oriented, typically by stretching, in one or more directions. The size and shape of the disperse phase particles, the volume fraction of the disperse phase, the film thickness, and the amount of orientation are chosen to attain a desired degree of diffuse reflection and total transmission of electromagnetic radiation of a desired wavelength in the resulting film.

Claims

1. A polarizer, comprising:

a polymeric continuous phase and a disperse phase disposed within said continuous phase,

wherein said polarizer has a relative gain at 60°

that is at least equal to the relative gain of said polarizer at normal incidence.

2. The polarizer of claim 1, wherein the difference between the relative gain of said polarizer at 60°

and the relative gain of said polarizer at normal incidence is at least about 0.1.

3. The polarizer of claim 1, wherein the difference between the relative gain of said polarizer at 60°

and the relative gain of said polarizer at normal incidence is at least about 0.2.

4. The polarizer of claim 1, wherein the difference between the relative gain of said polarizer at 60°

and the relative gain of said polarizer at normal incidence is at least about 0.3.

5. The polarizer of claim 1, wherein said continuous and disperse phases comprise first and second diverse thermoplastic polymers, respectively.

6. The polarizer of claim 5, wherein said first polymer is a polyester.

7. The polarizer of claim 5, wherein said polarizer further comprises a compatibilizer.

8. The polarizer of claim 1, wherein said disperse phase is randomly distributed throughout said continuous phase.

9. The polarizer of claim 1, wherein said polarizer comprises a plurality of layers arranged in a repeating sequence of at least a first and second layer type, and wherein said first layer type comprises said continuous and disperse phases.

10. A polarizer, comprising:

a polymeric first phase; and

a second phase, disposed within said first phase, said second phase being discontinuous along at least two of any three mutually perpendicular axes;

wherein said polarizer has a maximum relative gain as a function of angle within the range of 30°

to 60°

.

11. The polarizer of claim 10, wherein said second phase is present in an amount of about 5% to about 50% by volume relative to said first phase.

12. The polarizer of claim 10, wherein said second phase is present in an amount of about 15% to about 30% by volume relative to said first phase.

13. The polarizer of claim 10, wherein said polarizer is a film, and wherein the index difference between said first and second phases is less than about 0.05 along an axis perpendicular to the surface of said film.

14. The polarizer of claim 10, wherein said first phase has a larger birefringence than said second phase.

15. A polarizer, comprising:

a polymeric continuous phase; and

a disperse phase, disposed within said continuous phase;

wherein the average of the relative cain for said polarizer taken over the range of 30°

to 60°

is greater than the relative gain of said polarizer at normal incidence.

16. The polarizer of claim 15, wherein said continuous and disperse phases comprise first and second diverse polymers, respectively.

17. The polarizer of claim 16, further comprising a compatibilizer.

18. The polarizer of claim 15, further comprising a dichroic dye.

19. The polarizer of claim 15, wherein said polarizer comprises a plurality of layers arranged in a repeating sequence of at least a first and second layer type, and wherein said first layer type comprises said continuous and disperse phases.

20. The polarizer of claim 15, wherein said polarizer is a film, and wherein the difference in indices of refraction between said continuous and disperse phases for visible light polarized along an axis perpendicular to the surface of said film is less than about 0.05.

21. The polarizer of claim 20, therein said polarizer has a total diffuse reflectivity of at least about 30%.

22. A polarizer, comprising:

a birefringent polymeric continuous phase; and

a disperse phase, disposed within said continuous phase;

wherein said polarizer has a maximum relative gain as a function of angle within the range of 30°

to 60°

, and wherein said polarizer has a total diffuse reflectivity of at least about 30%.