Method of making a high performance ultracapacitor

• US 6,059,847 A
• Filed: 07/26/1996
• Issued: 05/09/2000
• Est. Priority Date: 10/07/1994
• Status: Expired due to Fees

• Current Assignee: Tesla Inc.
• Original Assignee: Maxwell Energy Products Incorporated
• Inventors: Dispennette, John M., Farahmandi, C. Joseph
• Primary Examiner(s): Niebling, John F.
• Assistant Examiner(s): NGUYEN, HA T
• Application Number:
  US08/686,580
• Time in Patent Office: 1,383 Days
• Field of Search: 29/25.03, 361/502, 361/503, 361/509, 361/512, 361/522, 361/529
• US Class Current: 29/25.03
• CPC Class Codes: H01G 11/24 characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
• CPC Class Codes: H01G 11/26 characterised by their structure, e.g. multi-layered, porosity or surface features
• CPC Class Codes: H01G 11/28 arranged or disposed on a current collector; Layers or phases between electrodes and current collectors, e.g. adhesives
• CPC Class Codes: Y02E 60/13 Energy storage using capacitors

Abstract

A high performance double layer capacitor having an electric double layer formed in the interface between activated carbon and an electrolyte is disclosed. The high performance double layer capacitor includes a pair of aluminum impregnated carbon composite electrodes having an evenly distributed and continuous path of aluminum impregnated within an activated carbon fiber preform saturated with a high performance electrolytic solution. The high performance double layer capacitor is capable of delivering at least 5 Wh/kg of useful energy at power ratings of at least 600 W/kg.

Claims

1. A method of making a double layer capacitor comprising the steps of:

impregnating an activated carbon fiber preform with an evenly distributed and continuous path of aluminum, thereby forming an aluminum impregnated carbon fiber preform;

bonding a current collector plate on a surface of said aluminum impregnated carbon fiber preform;

aligning a pair of aluminum impregnated carbon fiber preforms having been bonded to a respective current collector plate together, wherein said pair of aluminum impregnated carbon fiber preforms have non-bonded surfaces facing one another;

placing an ionically conductive separator between said facing surfaces of said pair of aluminum impregnated carbon fiber preforms; and

saturating said pair of aluminum impregnated carbon fiber preforms and said ionically conductive separator with an electrolyte solution.

2. The method of making a double layer capacitor according to claim 1 further comprising the step of sealably packaging said double layer capacitor within a housing.

3. The method of making a double layer capacitor according to claim 1 further comprising the step of controlling porosity of said aluminum impregnated carbon fiber preform during said impregnation step.

4. The method of making a double layer capacitor according to claim 3 wherein the step of impregnating an activated carbon fiber preform with an evenly distributed and continuous path of aluminum further comprises plasma spraying molten aluminum into said activated carbon fiber preform.

5. The method of making a double layer capacitor according to claim 4 wherein the step of controlling porosity of said aluminum impregnated carbon fiber preform further includes adjusting a standoff distance between a plasma spray unit and said carbon fiber preform.

6. The method of making a double layer capacitor according to claim 4 wherein the step of controlling porosity of said aluminum impregnated carbon fiber preform further includes controlling a sweep rate of a plasma spray unit relative to said carbon fiber preform.

7. The method of making a double layer capacitor according to claim 4 wherein the step of controlling porosity of said aluminum impregnated carbon fiber preform further includes controlling a delivery temperature and pressure of said molten aluminum to said activated carbon fiber preform.

8. The method of making a double layer capacitor according to claim 3 wherein the step of impregnating an activated carbon fiber preform with an evenly distributed and continuous path of aluminum further comprises immersing said activated carbon fiber preform into a bath of molten aluminum.

9. The method of making a double layer capacitor according to claim 3 wherein the step of controlling porosity of said aluminum impregnated carbon fiber preform further includes cycling pressure of said molten aluminum impregnating said activated carbon fiber preform.

10. The method of making a double layer capacitor according to claim 3 wherein the step of controlling porosity of said aluminum impregnated carbon fiber preform further includes applying ultrasonic vibrations to said activated carbon fiber preform during said impregnation step.

11. The method of making a double layer capacitor according to claim 1 further comprising the step of immersing said activated carbon fiber preform into a molten metal infiltrate composed of a wetting agent prior to impregnating said activated carbon fiber preform with aluminum.

12. The method of making a double layer capacitor according to claim 11 wherein said wetting agent is selected from a group consisting of Tin-Titanium, Copper-Tin-Titanium, Tantalum, Titanium-Carbon, Titanium-Nitrogen, Titanium-Nitrogen-Carbon, Silicon-Carbon, and mixtures thereof.

13. The method of making a double layer capacitor according to claim 1 wherein the step of saturating said aluminum impregnated carbon fiber preforms and separator with said electrolyte solution further comprises saturating said aluminum impregnated carbon fiber preform and separator with said electrolyte solution utilizing a vacuum infiltration process.

14. The method of making a double layer capacitor according to claim 1 wherein the step of bonding a current collector plate on a surface of said aluminum impregnated carbon fiber preform further comprises pressing said aluminum impregnated carbon fiber preform against an aluminum foil at a bonding temperature well below a melting point of aluminum in an inert atmosphere.

15. The method of making a double layer capacitor according to claim 14 wherein said bonding temperature is between about 300°

C. and 600°

C.

16. The method of making a double layer capacitor according to claim 14 further comprising the step of etching surfaces of said aluminum foil prior to said bonding.

17. The method of making a double layer capacitor according to claim 16 wherein the step of etching said aluminum foil further comprises immersing the aluminum foil in a solution of sodium dichromate in sulfuric acid.

18. The method of making a double layer capacitor according to claim 14 further comprising the step of reducing any aluminum oxide layers from said aluminum foil with an argon ion sputtering technique prior to said bonding.

19. The method of making a double layer capacitor according to claim 1 wherein said impregnating step further comprises impregnating an activated carbon fiber preform, having a surface area greater than 500 m² /g, with said evenly distributed and continuous path of aluminum.

20. The method of making a double layer capacitor according to claim 1 further comprising the step of maintaining a porosity of an impregnated portion of said aluminum impregnated carbon fiber preform during said impregnation step.

21. The method of making a double layer capacitor according to claim 1 wherein said impregnating comprises impregnating said activated carbon fiber preform with said evenly distributed and continuous path of aluminum, thereby forming said aluminum impregnated carbon fiber preform, wherein a porosity of the said activated carbon fiber preform having been impregnated is defined by a weight ratio of said aluminum to activated carbon fiber less than 1.3.

22. The method of making a double layer capacitor according to claim 1 wherein said impregnating comprises impregnating said activated carbon fiber preform with said evenly distributed and continuous path of aluminum, thereby forming said aluminum impregnated carbon fiber preform, wherein aluminum is forced between interstices of carbon fibers within said activated carbon fiber preform.

23. The method of making a double layer capacitor according to claim 1 wherein said impregnating comprises spraying said evenly distributed and continuous path of aluminum deep into interstices of each of said pair of activated carbon fiber preforms, thereby reducing the carbon to carbon contacts and decreasing the internal resistance of each of said pair of activated carbon fiber preforms.

24. The method of making a double layer capacitor according to claim 1 wherein said double layer capacitor is capable of delivering at least 5 Wh/kg of useful energy at power ratings of at least 600 W/kg.

25. A method of forming a diffusion bond between an aluminum foil current collector plate and an aluminum/carbon composite electrode comprising the steps of:

reducing any aluminum oxide layers from said aluminum foil current collector plate; and

pressing said aluminum/carbon composite electrode against said aluminum foil current collector plate at a bonding temperature well below a melting point of aluminum in an inert atmosphere such that aluminum atoms fill voids at an interface of said aluminum/carbon composite electrode and aluminum foil current collector plate to adhere said aluminum foil to said carbon electrode while preventing formation of aluminum carbide at said interface.

26. The method of forming a diffusion bond between an aluminum foil current collector plate and an aluminum/carbon composite electrode according to claim 25 wherein said step of reducing said oxide layer comprises etching surfaces of said aluminum foil current collector plate.

27. The method of forming a diffusion bond between an aluminum foil current collector plate and an aluminum/carbon composite electrode according to claim 26 wherein the step of etching said aluminum foil current collector plate further comprises immersing said aluminum foil current collector plate in a solution of sodium dichromate in sulfuric acid.

28. The method of forming a diffusion bond between an aluminum foil current collector plate and an aluminum/carbon composite electrode according to claim 25 further comprising the step of reducing any aluminum oxide layers from said aluminum foil current collector plate with an argon ion sputtering technique.

29. The method of forming a diffusion bond between an aluminum foil current collector plate and an aluminum/carbon composite electrode according to claim 25 wherein said bonding temperature is between about 300°

C. and 600°

C.

30. The method of forming a diffusion bond between an aluminum foil current collector plate and an aluminum/carbon composite electrode according to claim 25 wherein said aluminum foil current collector plate has a thickness of between about 0.5 mils and 3.0 mils.

31. The method of forming a diffusion bond between an aluminum foil current collector plate and an aluminum/carbon composite electrode according to claim 25 wherein said bonding pressure is between about 3 and 400 psi.

32. A method of making a double layer capacitor comprising the steps of:

impregnating a pair of activated carbon fiber preforms with aluminum;

pressing a pair of current collector plates each onto a respective surface of respective ones of said pair of activated carbon fiber preforms;

aligning the pair of activated carbon fiber preforms together wherein said respective ones of said pair of activated carbon fiber preforms have respective non-bonded surfaces facing one another;

placing an ionically conductive separator between said non-bonded surfaces of said respective ones of said pair of activated carbon fiber preforms; and

saturating said pair of activated carbon fiber preforms and the ionically conductive separator with an electrolyte solution.

33. The method of making a double layer capacitor according to claim 32 further comprising the step of sealably packaging said double layer capacitor within a housing.

34. The method of making a double layer capacitor according to claim 32 further comprising the step of controlling porosity of said pair of activated carbon fiber preforms during said impregnation step.

35. The method of making a double layer capacitor according to claim 34 wherein the step of impregnating the pair of activated carbon fiber preforms further comprises impregnating the pair of activated carbon fiber performs with an evenly distributed and continuous path of aluminum by plasma spraying molten aluminum into each of said pair of activated carbon fiber preforms.

36. The method of making a double layer capacitor according to claim 35 wherein the step of controlling porosity of said pair of activated carbon fiber preforms further includes adjusting a standoff distance between a plasma spray unit and one of said pair of activated carbon fiber preforms.

37. The method of making a double layer capacitor according to claim 35 wherein the step of controlling porosity of said pair of activated carbon fiber preforms further includes controlling a sweep rate of a plasma spray unit relative to each of said pair of activated carbon fiber preforms.

38. The method of making a double layer capacitor according to claim 35 wherein the step of controlling porosity of said pair of activated carbon fiber preforms further includes controlling a delivery temperature and pressure of said molten aluminum to each of said pair of activated carbon fiber preform.

39. The method of making a double layer capacitor according to claim 34 wherein the step of impregnating said pair of activated carbon fiber preforms further comprises impregnating the pair of activated carbon fiber performs with an evenly distributed and continuous path of aluminum by immersing each of said pair of activated carbon fiber preforms into a bath of molten aluminum.

40. The method of making a double layer capacitor according to claim 34 wherein the step of controlling porosity of said pair of aluminum impregnated carbon fiber preforms further includes cycling pressure of said molten aluminum impregnating said pair of activated carbon fiber preforms.

41. The method of making a double layer capacitor according to claim 34 wherein the step of controlling porosity of said pair of aluminum impregnated carbon fiber preforms further includes applying ultrasonic vibrations to said pair of activated carbon fiber preforms during said impregnation step.

42. The method of making a double layer capacitor according to claim 32 further comprising the step of immersing said pair of activated carbon fiber preforms into a molten metal infiltrate composed of a wetting agent prior to impregnating said pair of activated carbon fiber preforms with aluminum.

43. The method of making a double layer capacitor according to claim 42 wherein said wetting agent is selected from a group consisting of Tin-Titanium, Copper-Tin-Titanium, Tantalum, Titanium-Carbon, Titanium-Nitrogen, Titanium-Nitrogen-Carbon, Silicon-Carbon, and mixtures thereof.

44. The method of making a double layer capacitor according to claim 32 wherein the step of saturating said pair of activated carbon fiber preforms and said ionically conductive separator with said electrolyte solution further comprises saturating said pair of activated carbon fiber preforms and separator with said electrolyte solution utilizing a vacuum infiltration process.

45. The method of making a double layer capacitor according to claim 32 wherein the step of pressing said pair of current collector plates further comprises bonding said pair of current collector plates each onto said respective surface of said respective ones of said pair of activated carbon fiber preforms by pressing said aluminum impregnated carbon fiber preform against an aluminum foil at a bonding temperature well below a melting point of aluminum in an inert atmosphere.

46. The method of making a double layer capacitor according to claim 45 wherein said bonding temperature is between about 300°

C. and 600°

C.

47. The method of making a double layer capacitor according to claim 45 further comprising etching surfaces of said aluminum foil prior to said bonding.

48. The method of making a double layer capacitor according to claim 47 wherein the step of etching said aluminum foil further comprises immersing the aluminum foil in a solution of sodium dichromate in sulfuric acid.

49. The method of making a double layer capacitor according to claim 45 further comprising the step of reducing any aluminum oxide layers from said aluminum foil with an argon ion sputtering technique prior to said bonding.

50. The method of making a double layer capacitor according to claim 32 wherein said impregnating step further comprises impregnating said pair of activated carbon fiber preforms, having a surface area greater than 500 m² /g, with aluminum.

51. The method of making a double layer capacitor according to claim 32 further comprising the step of maintaining a porosity of impregnated portions of said pair of activated carbon fiber preforms during said impregnation step.

52. The method of making a double layer capacitor of claim 32 wherein said impregnating comprises impregnating said pair of activated carbon fiber preforms with aluminum, wherein a porosity of the said pair of activated carbon fiber preforms having been impregnated is defined by a weight ratio of said aluminum to activated carbon fiber less than 1.3.

53. The method of making a double layer capacitor of claim 32 wherein said impregnating comprises impregnating said pair of activated carbon fiber preforms with aluminum, wherein said aluminum is forced between interstices of carbon fibers within said activated carbon fiber preform.

54. The method of making a double layer capacitor of claim 32 wherein said impregnating comprises spraying said evenly distributed and continuous path of aluminum deep into interstices of said activated carbon fiber preform, thereby reducing the carbon to carbon contacts and decreasing the internal resistance of said activated carbon fiber preform.

55. The method of making a double layer capacitor according to claim 32 wherein said double layer capacitor is capable of delivering at least 5 Wh/kg of useful energy at power ratings of at least 600 W/kg.

56. A method of making a double layer capacitor comprising the steps of:

forming the double layer capacitor, wherein the double layer capacitor has an electrode capacitance of greater than 30 farads/cm³ and a cell resistivity of less than 15 ohm-cm comprising;

impregnating a pair of activated carbon fiber preforms with aluminum;

pressing a pair of current collector plates each onto a respective surface of respective ones of said pair of activated carbon fiber preforms;

aligning the pair of activated carbon fiber preforms together wherein said respective ones of said pair of activated carbon fiber preforms have respective non-bonded surfaces facing one another;

placing an ionically conductive separator between said non-bonded surfaces of said respective ones of said pair of activated carbon fiber preforms; and

saturating said pair of activated carbon fiber preforms and the ionically conductive separator with an electrolyte solution.