Water treatment process

• US 6,059,974 A
• Filed: 06/18/1998
• Issued: 05/09/2000
• Est. Priority Date: 06/19/1997
• Status: Expired due to Term

• Current Assignee: Applied Specialties, Inc.
• Original Assignee: Applied Specialties, Inc.
• Inventors: Scheurman, Clarence III
• Primary Examiner(s): CINTINS, IVARS C
• Application Number:
  US09/099,351
• Time in Patent Office: 691 Days
• Field of Search: 210/667, 210/676, 210/683, 210/687, 210/189, 210/269, 210/662, 210/665, 210/677
• US Class Current: 210/662
• CPC Class Codes: B01J 49/75 of water softeners
• CPC Class Codes: C02F 1/42 by ion-exchange ion-exchange in general B01J
• CPC Class Codes: C02F 1/66 by neutralisation; pH adjustment for degassing C02F1/20; using ion-exchange C02F1/42; for flocculation or precipitation of suspended impurities C02F1/52; for removing dissolved compounds C02F1/58

Abstract

An improved water softening process is provided which also reduces anion content. A first stream of water is passed through an anion-exchange unit to remove undesirable anions and raise the pH. The first stream of water is then provided to reactor/clarifier water softening equipment, where it acts as a source of hydroxyl ions. Preferably a second stream of water which did not pass through an anion-exchange unit is also provided to the water softening equipment. The streams of water are combined and processed through the softening equipment, where hardness ions are precipitated out, yielding softened water with reduced anion content. The anion-exchange system utilized preferably has a counter-current continuous resin train and a counter-current continuous resin regeneration unit.

Claims

1. A process for softening water comprising the steps of

(a) passing a first stream of water through an anion-exchange unit to raise the pH of said first stream and provide a second stream of water having a pH of at least 9.5, said anion-exchange unit being a unit adapted to release hydroxyl ions;

(b) providing said second stream of water to water softening equipment comprising reactor and clarifier sections, said second stream of water being used as the principal source of hydroxyl ions in said water softening equipment;

(c) processing a fourth stream of water through said water softening equipment, said fourth stream comprising said second stream; and

(d) operating said water softening equipment on said fourth stream of water to remove via precipitation reactions hardness ions from said fourth stream and to provide thereby a fifth stream of water.

2. A process according to claim 1, further comprising the step of combining said second stream of water with a third stream of water to yield said fourth stream of water, said third stream of water not having been passed through said anion-exchange unit.

3. A process according to claim 2, further comprising the step of providing an initial stream of water, said first stream of water being a portion of said initial stream, said third stream of water being a portion of said initial stream.

4. A process according to claim 2, wherein said anion-exchange unit is a counter-current continuous anion-exchange resin train.

5. A process according to claim 4, said anion-exchange unit utilizing anion-exchange resin, said process further comprising the step of regenerating said anion-exchange resin in a counter-current continuous resin regeneration unit.

6. A process according to claim 5, wherein said counter-current continuous resin regeneration unit comprises at least a first tank and a second tank, said process further comprising the steps of:

(e) adding used anion-exchange resin to said first tank, said used anion-exchange resin having been used in said anion-exchange unit;

(f) adding regenerant liquid from said second tank to said first tank;

(g) thereafter removing regenerant liquid from said first tank;

(h) transferring said used anion-exchange resin from said first tank to said second tank;

(i) thereafter adding regenerant liquid to said second tank, said regenerant liquid removed from said first tank being more exhausted than said regenerant liquid added to said first tank from said second tank, said regenerant liquid removed from said second tank to be added to said first tank being more exhausted than said regenerant liquid added to said second tank.

7. A process according to claim 4, wherein said counter-current continuous anion-exchange resin train comprises at least two separate tanks.

8. A process according to claim 4, wherein said counter-current continuous anion-exchange resin train comprises at least three separate tanks.

9. A process according to claim 2, said anion-exchange unit utilizing anion-exchange resin, said process further comprising the step of regenerating said anion-exchange resin in a counter-current continuous resin regeneration unit.

10. A process according to claim 9, wherein said counter-current continuous resin regeneration unit comprises at least a first tank and a second tank, said process further comprising the steps of:

(e) adding used anion-exchange resin to said first tank, said used anion-exchange resin having been used in said anion-exchange unit;

(f) adding regenerant liquid from said second tank to said first tank;

(g) thereafter removing regenerant liquid from said first tank;

(h) transferring said used anion-exchange resin from said first tank to said second tank;

(i) thereafter adding regenerant liquid to said second tank, said regenerant liquid removed from said first tank being more exhausted than said regenerant liquid added to said first tank from said second tank, said regenerant liquid removed from said second tank to be added to said first tank being more exhausted than said regenerant liquid added to said second tank.

11. A process according to claim 10, wherein said counter-current continuous resin regeneration unit comprises at least 5 tanks.

12. A process according to claim 2, further comprising the steps of combining said second and third streams of water in a first mixing tank and monitoring and controlling the pH of the contents of said first mixing tank so as to maintain said pH between 10 and 12.5.

13. A process according to claim 12, further comprising the steps of passing said fourth stream of water from said first mixing tank to a second mixing tank, injecting carbon dioxide into said fourth stream of water, and monitoring and controlling the pH of said fourth stream of water in said second mixing tank so as to maintain said pH between 10 and 11.

14. A process according to claim 2, wherein said first stream, prior to passing through said anion-exchange unit, and said third stream together have an aggregate initial concentration of magnesium, said fifth stream of water having a magnesium concentration at least 90% less than said initial magnesium concentration.

15. A process according to claim 14, wherein said first stream, prior to passing through said anion-exchange unit, and said third stream together have aggregate initial concentrations of calcium, chloride and sulfate, said fifth stream of water having a calcium concentration at least 90% less than said initial calcium concentration, a chloride concentration at least 20% less than said initial chloride concentration, and a sulfate concentration at least 40% less than said initial sulfate concentration.

16. A process according to claim 2, wherein said first stream, prior to passing through said anion-exchange unit, and said third stream together have an aggregate initial concentration of calcium, said fifth stream of water having a calcium concentration at least 90% less than said initial calcium concentration.

17. A process according to claim 2, wherein said first stream, prior to passing through said anion-exchange unit, and said third stream together have an aggregate initial concentration of chloride, said fifth stream of water having a chloride concentration at least 20% less than said initial chloride concentration.

18. A process according to claim 2, wherein said first stream, prior to passing through said anion-exchange unit, and said third stream together have an aggregate initial concentration of sulfate, said fifth stream of water having a sulfate concentration at least 40% less than said initial sulfate concentration.

19. A process according to claim 2, wherein said first stream, prior to passing through said anion-exchange unit, and said third stream together have an aggregate initial concentration of barium, said fifth stream of water having a barium concentration at least 90% less than said initial barium concentration.

20. A process according to claim 2, wherein said first stream, prior to passing through said anion-exchange unit, and said third stream together have an aggregate initial concentration of cyanide, said fifth stream of water having a cyanide concentration at least 40% less than said initial cyanide concentration.

21. A process according to claim 2, wherein said first stream, prior to passing through said anion-exchange unit, and said third stream together have an aggregate initial concentration of silica, said fifth stream of water having a silica concentration at least 50% less than said initial silica concentration.

22. A process according to claim 2, further comprising processing said fourth stream of water through said water softening equipment at a flow rate of at least 50 gallons per minute.

23. A process according to claim 2, the flow rate of said second stream of water being not more than 50% of the flow rate of said fourth stream of water.

24. A process according to claim 2, wherein a portion of said fifth stream of water is utilized to provide said first stream of water.

25. A process according to claim 2, wherein said second stream of water has a pH of at least 12.

26. A process according to claim 2, said fifth stream of water being a stream flowing at a rate of 20-5000 gallons per minute.

27. A process according to claim 2, said fifth stream of water being a stream flowing at a rate of 50-1000 gallons per minute.

28. A process according to claim 2, wherein 25-50% of said fourth stream of water has passed through said anion-exchange unit.

29. A process according to claim 1, wherein said second stream of water has a pH of at least 10.6.

30. A process according to claim 1, wherein said second stream of water has a pH of at least 11.3.

31. A process according to claim 1, said process being free from a step of passing a stream of water through a cation-exchange unit.

32. A process according to claim 1, wherein said second stream of water has a pH of at least 12.

33. A process according to claim 1, wherein said second stream of water has a pH of 12-12.8.

34. A process according to claim 1, wherein said second stream of water has a pH of 11-13.1.