Optical compensatory sheet having an orientation layer activated by irradiation of light, process and preparation of the same and liquid crystal display

• US 6,061,113 A
• Filed: 02/09/1998
• Issued: 05/09/2000
• Est. Priority Date: 02/07/1997
• Status: Expired due to Term

• Current Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Original Assignee: Fuji Photo Film Co Limited (Fujifilm Holdings Corporation)
• Inventors: Kawata, Ken
• Primary Examiner(s): Sikes, William L.
• Assistant Examiner(s): CHOWDHURY, TARIFUR RASHID
• Application Number:
  US09/020,404
• Time in Patent Office: 820 Days
• Field of Search: 349/117, 349/118, 349/120, 349/121, 349/177, 349/123, 349/124, 428/1, 359/494, 359/500
• US Class Current: 349/117
• CPC Class Codes: C09K 2323/05 Bonding or intermediate layer characterised by chemical composition, e.g. sealant or spacer
• CPC Class Codes: G02B 5/3016 involving passive liquid crystal elements optical properties of liquid crystals G02F1/0063; polarising elements associated with active liquid crystal devices G02F1/133528
• CPC Class Codes: G02F 2413/105 with varying inclination in thickness direction, e.g. hybrid oriented discotic LC

Abstract

An optical compensatory sheet comprises a transparent support, an orientation layer and an optically anisotropic layer in order. The optically anisotropic layer contains an aligned and fixed discotic liquid crystal compound. The orientation layer has a function of aligning the discotic liquid crystal compound. The function of the orientation layer is activated by irradiating the layer with light from a single direction. The present specification also discloses a process for the preparation of the optical compensatory sheet and a liquid crystal display using the optical compensatory sheet.

Claims

1. An optical compensatory sheet comprising a transparent support, an orientation layer and an optically anisotropic layer in order, said orientation layer containing a light-sensitive polymer, and said optically anisotropic layer containing an aligned and fixed discotic liquid crystal compound, wherein the light-sensitive polymer is a polymer chemically binding a photochromic compound.

2. The optical compensatory sheet as defined in claim 1, wherein the transparent support is made of a plastic film.

3. The optical compensatory sheet as defined in claim 1, wherein the transparent support is made of a continuous film.

4. The optical compensatory sheet as defined in claim 1, wherein the aligned discotic liquid crystal compound is fixed by polymerization.

5. The optical compensatory sheet as defined in claim 1, wherein the aligned discotic liquid crystal compound is in the form of a discotic nematic phase.

6. The optical compensatory sheet as defined in claim 1, wherein the light-sensitive polymer is a hydrophilic polymer chemically binding a photochromic compound.

7. The optical compensatory sheet as defined in claim 6, wherein the light-sensitive polymer is polyvinyl alcohol chemically binding a photochromic compound.

8. The optical compensatory sheet as defined in claim 7, wherein the polyvinyl alcohol is bound to the photochromic compound by a chemical bond of Ph-CO--O-P1 in which Ph is the photochromic compound and P1 is the main chain of the polyvinyl alcohol.

9. A process for the preparation of an optical compensatory sheet, which comprises the steps in order of:

(1) forming a layer containing a light-sensitive polymer on a transparent support, wherein the light-sensitive polymer is a polymer chemically binding a photochromic compound;

(2) irradiating the layer containing the light-sensitive polymer with light applied in a single direction;

(3) forming a layer containing a discotic liquid crystal compound having a polymerizable group and a photo polymerization initiator on the layer containing the light-sensitive polymer; and

(4) irradiating the layer containing the discotic liquid crystal compound and the photo polymerization initiator with light.

10. The process defined in claim 9, wherein the transparent support is made of a continuous film.

11. The process defined in claim 9, wherein the layer containing the light-sensitive polymer is irradiated with light applied in a single direction over the layer at the step of (2).

12. The process defined in claim 9, wherein the layer containing the light-sensitive polymer is irradiated with natural light applied in a single direction at the step of (2).

13. The process defined in claim 9, wherein the layer containing the light-sensitive polymer is irradiated with light applied in a single direction while heating the layer at a temperature of 40 to 250°

C. at the step of (2).

14. The process defined in claim 9, wherein the layer containing the discotic liquid crystal compound and the photo polymerization initiator is heated at a temperature of 70 to 300°

C. between the steps of (3) and (4) or simultaneously with the step of (4).

15. A liquid crystal display comprising a liquid crystal cell, a polarizing sheet and an optical compensatory sheet provided between the liquid crystal cell and the polarizing sheet, wherein the optical compensatory sheet comprises a transparent support, an orientation layer and an optically anisotropic layer in order, said optically anisotropic layer containing an aligned and fixed discotic liquid crystal compound, and said orientation layer containing a light-sensitive polymer, and wherein the light-sensitive polymer is a polymer chemically binding a photochromic compound.

16. The liquid crystal display as defined in claim 15, wherein the liquid crystal cell comprises a pair of substrates, each of which has an orientation layer, a rod-like liquid crystal compound provided between the orientation layers of the substrates and an electrode layer.

17. The liquid crystal display as defined in claim 16, wherein the orientation layer of the liquid crystal cell is formed by rubbing a polyvinyl alcohol or polyimide membrane.