Apparatus for photocatalytic fluid purification

• US 6,063,343 A
• Filed: 06/12/1998
• Issued: 05/16/2000
• Est. Priority Date: 10/25/1996
• Status: Expired due to Term

• Current Assignee: Ephraim Heller
• Original Assignee: E. Heller & Company
• Inventors: Bonnecaze, Roger, Haugsjaa, Paul, Sitkiewitz, Steven, Heller, Ephraim, Heller, Adam, Say, James
• Primary Examiner(s): MCKANE, ELIZABETH L
• Application Number:
  US09/097,320
• Time in Patent Office: 704 Days
• Field of Search: 422/121, 422/122, 422/24, 422/23, 422/186, 422/186.06, 422/186.3, 210/748
• US Class Current: 422/186.3
• CPC Class Codes: B01D 2255/802 Photocatalytic
• CPC Class Codes: B01D 53/885 Devices in general for catalytic purification of waste gases
• CPC Class Codes: B01J 19/122 Incoherent waves gamma-radiation B01J19/082
• CPC Class Codes: B01J 35/30 characterised by their physical properties
• CPC Class Codes: B01J 35/39 Photocatalytic properties
• CPC Class Codes: C02F 1/32 with ultraviolet light
• CPC Class Codes: C02F 1/725 by catalytic oxidation
• CPC Class Codes: C02F 2305/10 Photocatalysts

Abstract

A compact, efficient reactor for the photocatalyzed conversion of contaminants in a fluid stream. The reactor includes a photocatalyst disposed on a support structure with a light source in optical proximity to the support structure to activate the photocatalyst. In one embodiment of the invention, the support structure includes multiple non-intersecting fins oriented parallel to the general flow direction of the fluid stream to provide a reactor with low pressure drop and adequate mass transfer of the contaminant to the photocatalyst disposed on the surface of the fins. The light source includes one or more lamps that may penetrate the fins to provide efficient illumination of the photocatalyst. The fins may be flat or pleated. In an alternative embodiment, the fins are pleated and composed of a porous material. These fins are oriented so that the fluid stream flows through the fins. In another embodiment, the support structure includes one or more cylinders having pleated inner surfaces with longitudinal lamps disposed within the cylinders. The photocatalyst is deposited on the inner surface of the cylinder to convert contaminants flowing through the cylinder. The reactor is designed for ease of support structure or light source removal or replacement and may be used as a modular subassembly in a larger fluid purification unit.

Claims

1. A reactor for use in the photocatalyzed conversion of contaminants in a fluid stream having a general flow direction, the reactor comprising:

a light source;

photocatalyst; and

at least 20 non-intersecting fins for placement within the fluid stream to provide support for the photocatalyst, the fins being oriented substantially parallel to the general flow direction of the fluid stream and substantially orthogonal to the light source, the fins being configured so that the light source illuminates the photocatalyst with light having a wavelength capable of activating the photocatalyst.

2. The reactor of claim 1, having at least 100 non-intersecting fins.

3. The reactor of claim 1, wherein the fins have a thickness of less than 0.2 cm.

4. The reactor of claim 1, wherein the fins are square, rectangular or circular.

5. The reactor of claim 1, wherein the fins have a reflective surface.

6. The reactor of claim 5, wherein the reflective surface comprises reflective aluminum or magnesium.

7. The reactor of claim 1, wherein the fins have multiple openings therethrough.

8. The reactor of claim 1, wherein the photocatalyst is disposed on a front surface, a back surface, or on both the front and back surfaces of the fins.

9. The reactor of claim 1, wherein the photocatalyst comprises photocatalytic particles bound by a substantially nonoxidizable binder.

10. The reactor of claim 1, wherein the light source comprises a source of UV light, visible light, or both.

11. The reactor of claim 1, wherein the light source provides an average activating light intensity ranging from 0.1 to 10 mW/cm².

12. A reactor for use in the photocatalyzed conversion of contaminants in a fluid stream having a general flow direction, the reactor comprising:

one or more fins for placement within the fluid stream, each fin comprising at least 20 pleats for contact with the fluid stream, each fin further comprising a porous material through which the fluid stream can flow,

photocatalyst disposed on the fins; and

a light source comprising one or more longitudinal lamps wherein each lamp has a longitudinal axis, at least one of the lamps being oriented with respect to each fin so that the longitudinal axis of the oriented lamp is perpendicular to the pleats of the fin to provide light to illuminate the photocatalyst.

13. The reactor of claim 12, wherein each fin comprises at least 100 pleats.

14. The reactor of claim 12, wherein each pleat is at least 2 cm deep.

15. The reactor of claim 12, wherein the pleats have an angle therebetween which is 20°

or less.

16. The reactor of claim 12, further comprising a post-filter disposed in the reactor within the fluid stream past the fins.

17. A reactor system comprising:

a reactor chamber having an inlet port and an outlet port;

a plurality of substantially parallel fins disposed in the reactor chamber;

photocatalyst disposed on the fins; and

a light source arranged orthogonal to the fins to illuminate the photocatalyst;

wherein a general flow of a fluid through the reactor chamber comprises entering the reactor chamber through the inlet port, flowing substantially parallel to the fins, and exiting through the outlet port.

18. The reactor system of claim 17, wherein the system further comprises a blower to facilitate the general flow of the fluid.

19. The reactor system of claim 17, further comprising a pre-filter disposed in the reactor chamber, wherein the general flow of the fluid through the reactor chamber further comprises flowing through the pre-filter before flowing parallel to the fins.