Liquid curable resin composition

• US 6,063,888 A
• Filed: 10/09/1998
• Issued: 05/16/2000
• Est. Priority Date: 04/09/1996
• Status: Expired due to Fees

• Current Assignee: Dsm Nv, JSR Corporation
• Original Assignee: Dsm Nv, JSR Corporation
• Inventors: Ukachi, Takashi, Komiya, Zen, Yamaguchi, Yoshikazu, Yoshizawa, Junji
• Primary Examiner(s): Seidleck, James J.
• Assistant Examiner(s): McClendon, Sanza L.
• Application Number:
  US09/168,938
• Time in Patent Office: 585 Days
• Field of Search: 522/99, 522/148, 522/172, 522/96, 522/91, 528/32, 428/380, 428/391, 428/403, 428/405, 428/407
• US Class Current: 528/32
• CPC Class Codes: C08G 18/289 containing silicon
• CPC Class Codes: C08G 18/672 Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
• CPC Class Codes: C08G 77/388 containing nitrogen
• CPC Class Codes: G02B 1/048 characterised by the cladding material
• CPC Class Codes: Y10T 428/2942 Plural coatings
• CPC Class Codes: Y10T 428/2962 Silane, silicone or siloxane in coating
• CPC Class Codes: Y10T 428/2991 Coated
• CPC Class Codes: Y10T 428/2995 Silane, siloxane or silicone coating
• CPC Class Codes: Y10T 428/2998 including synthetic resin or polymer

Abstract

A liquid radiation curable resin composition comprising a polydimethylsiloxane compound which has (i) at least two urethane bonds in one molecule, (ii) an unreactive organic group at at least one of the ends of the molecule, and (iii) a radical curable ethylenically unsaturated group at the other end of the molecule. The resin composition exhibits superior shelf life in a liquid state and produces cured products having slippery surface. It is suitable as a coating material for optical fibers.

Claims

1. A liquid radiation curable resin composition comprising a polydimethylsiloxane compound which has (i) at least two urethane bonds in one molecule, (ii) an unreactive organic group at at least one of the ends of the molecule, and (iii) a radical curable ethylenically unsaturated group at the other end of the molecule.

2. The liquid curable resin composition according to claim 1, wherein said polydimethylsiloxane compound has an organic group containing at least two urethane bonds and one or two radical curable ethylenically unsaturated groups at one end, an unreactive organic group terminating the other end, and a number average molecular weight of about 800-15,000, and said liquid curable resin composition containing the polydimethylsiloxane in an amount of about 0.05-15 wt %.

3. A liquid curable resin composition according to claim 1, wherein said radical curable ethylenically unsaturated group is an acrylate or methacrylate group.

4. A liquid curable resin composition according to claim 1, wherein the composition comprises a sufficient amount of said polydimethylsiloxane, that the cured resin has a surface slip characteristic between about 0.1-1.5 kg/cm².

5. The liquid curable resin composition according to claim 1, wherein said polydimethylsiloxane compound is prepared by reacting a silicone compound having a hydroxyl group at one end, a polyisocyanate compound, and a (meth)acrylate compound having a hydroxyl group.

6. The liquid curable resin composition according to claim 1, wherein said polydimethylsiloxane compound is prepared by reacting a silicone compound having a hydroxyl group at one end, a polyol compound, a polyisocyanate compound, and a (meth)acrylate compound having a hydroxyl group.

7. The liquid curable resin composition according to claim 5, wherein said silicone compound having a reactive hydroxyl group at one end is a polydimethylsiloxane which has a 3-(2'"'"'-hydroxyethoxy)propyl group or a 3-(2'"'"',3'"'"'-dihydroxypropyloxy)propyl group at one end and of which the other end is terminated with a trimethylsilyloxy group.

8. The liquid curable resin composition according to claim 1, further comprising a urethane (meth)acrylate compound prepared from a polyol, a diisocyanate, and a (meth)acrylate having a hydroxyl group.

9. The liquid curable resin composition according to claim 8 containing said urethane (meth)acrylate compound in an amount of about 90 wt % or less.

10. The liquid curable resin composition according to claim 8, further comprising a monofunctional or polyfunctional polymerizable monomer which contains a (meth)acryloyl group or a vinyl group.

11. The liquid curable resin composition according to claim 10 containing said monofunctional or polyfunctional polymerizable monomer in an amount of about 80 wt % or less.

14. Ribbon structure comprising a plurality of coated optical fibers and a matrix material as covering layer, the matrix being a radiation cured layer of a liquid curable resin composition according to claim 1.

15. Bundled ribbon structure, comprising a plurality of ribbons, each ribbon comprising a plurality of coated optical fibers and a cured matrix material that cover the plurality of coated optical fibers, the plurality of ribbons being bonded together by a radiation cured bundling material, the bundling material being a liquid curable resin composition according to any one of claim 1.

16. The liquid curable resin composition according to claim 6, wherein s a i d silicone compound having a reactive hydroxyl group at one end is a polydimethylsiloxane which has a 3-(2'"'"'-hydroxyethoxy)propyl group or a 3-(2'"'"',3'"'"'-dihydroxypropyloxy)propyl group at one end and of which the other end is terminated with a trimethylsilyloxy group.

12. Ribbon structure comprising a plurality of coated optical fibers and a matrix material as covering layer, the matrix being a radiation cured layer of a liquid curable resin composition comprising a polydimethylsiloxane compound which has (i) at least two urethane bonds in one molecule, (ii) an unreactive organic group at at least one of the ends of the molecule, and (iii) a radical curable ethylenically unsaturated group at the other end of the molecule.

13. Bundled ribbon structure, comprising a plurality of ribbons, each ribbon comprising a plurality of coated optical fibers and a cured matrix material that cover the plurality of coated optical fibers, the plurality of ribbons being bonded together by a radiation cured bundling material, the bundling material being a liquid curable resin composition comprising a polydimethylsiloxane compound which has (i) at least two urethane bonds in one molecule, (ii) an unreactive organic group at at least one of the ends of the molecule, and (iii) a radical curable ethylenically unsaturated group at the other end of the molecule.