Wide-band two-layer antireflection coating for optical surfaces

• US 6,066,401 A
• Filed: 02/25/1998
• Issued: 05/23/2000
• Est. Priority Date: 02/25/1998
• Status: Expired due to Fees

• Current Assignee: National Research Council Canada
• Original Assignee: National Research Council Canada
• Inventors: Stilburn, James
• Primary Examiner(s): Jones, Deborah
• Assistant Examiner(s): RESNICK, JASON D
• Application Number:
  US09/030,395
• Time in Patent Office: 818 Days
• Field of Search: 428/689, 428/702, 428/212, 428/701, 428/699, 428/432, 428/692, 359/359, 359/580, 359/586, 359/589
• US Class Current: 428/432
• CPC Class Codes: B32B 17/10174 Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• CPC Class Codes: C03C 17/3452 comprising a fluoride
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree

Abstract

A process for forming a two-layer coating on glass or another substrate involves applying first a layer of light metal fluoride on the substrate and subsequently a layer of a porous metal oxide e.g. silica. The metal fluoride layer may be applied by using the sol-gel technique or by other methods e.g. vacuum deposition. The metal oxide layer is preferably applied by a sol-gel technique, by either a dip coating or spin coating. Each layer is preferably about one quarter-wavelength thick. The refractive index of the first layer is lower than that of the substrate, and the second layer has lower refractive index than the first layer. This dependence minimizes reflection of the coating over a broad wavelength range.

Claims

1. A two-layer antireflective coating on a substrate, comprising:

a first layer of a light metal fluoride applied on the surface of the substrate, and

a second layer of a porous metal oxide applied over the metal fluoride layer, the refractive index of said coating being substantially uniform throughout each of said layers and decreasing from said metal fluoride layer to said metal oxide layer.

2. The coating according to claim 1 wherein the refractive index of said first layer is lower than the refractive index of said substrate.

3. The coating according to claim 1 wherein the thickness of said first layer and said second layer is about one quarter-wavelength at a wavelength where a reflection minimum is desired.

4. The coating according to claim 1 wherein said substrate is selected from the group consisting of glass, plastic and a crystalline material.

5. The coating according to claim 1 wherein said light metal fluoride is selected from the group consisting of magnesium fluoride, lithium fluoride, sodium fluoride, potassium fluoride, calcium fluoride, strontium fluoride or barium fluoride.

6. The coating according to claim 1 wherein said metal oxide is one or more of the oxides of silicon, aluminum and titanium.

7. The coating according to claim 6 wherein the metal oxide is silica.