Electrochemical fuel cell stack with improved reactant manifolding and sealing

• US 6,066,409 A
• Filed: 07/16/1998
• Issued: 05/23/2000
• Est. Priority Date: 07/16/1997
• Status: Expired due to Term

• Current Assignee: BDF IP Holdings Ltd. (Superior Plus Corporation)
• Original Assignee: Ballard Power Systems Corporation (Superior Plus Corporation)
• Inventors: Wozniczka, Boguslaw M., Voss, Henry H., Chow, Clarence Y., Ronne, Joel A.
• Primary Examiner(s): Bell, Bruce F.
• Application Number:
  US09/116,270
• Time in Patent Office: 677 Days
• Field of Search: 429/32, 429/36, 429/38, 429/39
• US Class Current: 429/434
• CPC Class Codes: H01M 2008/1095 Fuel cells with polymeric electrolytes
• CPC Class Codes: H01M 2300/0082 Organic polymers
• CPC Class Codes: H01M 8/0271 Sealing or supporting means around electrodes, matrices or membranes
• CPC Class Codes: H01M 8/0273 with sealing or supporting means in the form of a frame
• CPC Class Codes: H01M 8/242 comprising framed electrodes or intermediary frame-like gaskets H01M8/2425, H01M8/244 take precedence
• CPC Class Codes: H01M 8/247 Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
• CPC Class Codes: H01M 8/248 Means for compression of the fuel cell stacks
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y10T 29/49108 Electric battery cell making
• CPC Class Codes: Y10T 29/4911 including sealing

Abstract

An electrochemical fuel cell stack with improved reactant manifolding and sealing includes a pair of separator plates interposed between adjacent membrane electrode assemblies. Passageways fluidly interconnecting the anodes to a fuel manifold and interconnecting the cathodes to an oxidant manifold are formed between adjoining non-active surfaces of the pairs of separator plates. The passageways extend through one or more ports penetrating the thickness of one of the plates thereby fluidly connecting the manifold to the opposite active surface of that plate, and the contacted electrode. The non-active surfaces of adjoining separator plates in a fuel cell stack cooperate to provide passageways for directing both reactants from respective stack fuel and oxidant supply manifolds to the appropriate electrodes. The fuel and oxidant reactant streams passageways are fluidly isolated from each other, although they both traverse adjoining non-active surfaces of the same pair of plates. The present manifolding configuration simplifies the sealing mechanisms associated with the stack manifolds because reactant streams are not directed between the separator plates and resilient MEA seals. Coolant passages may also be conveniently provided between adjoining non-active surfaces of the pairs of separator plates.

Claims

1. An electrochemical fuel cell stack comprising:

(a) a plurality of membrane electrode assemblies each comprising an anode, a cathode, and an ion exchange membrane interposed between said anode and cathode;

(b) a pair of separator plates interposed between adjacent pairs of said plurality of membrane electrode assemblies, said pair of separator plates comprising;

an anode plate having an active surface contacting an anode, and an oppositely facing non-active surface, and

a cathode plate having an active surface contacting a cathode, and an oppositely facing non-active surface adjoining said non-active surface of said anode plate; and

(c) a fuel supply manifold for directing a fuel stream to at least one of said anodes, and an oxidant supply manifold for directing an oxidant stream to at least one of said cathodes, and fuel and oxidant stream passageways fluidly connecting said fuel and oxidant supply manifolds to an anode and a cathode, respectively,

wherein said fuel and oxidant stream passageways each traverse a portion of said adjoining non-active surfaces of a pair of said separator plates.

2. The electrochemical fuel cell stack of claim 1 further comprising an oxidant exhaust manifold for directing an oxidant stream from at least one of said cathodes, wherein an oxidant stream passageway fluidly interconnecting said oxidant exhaust manifold to a cathode traverses a portion of adjoining non-active surfaces of a pair of said separator plates.

3. The electrochemical fuel cell stack of claim 1 further comprising a fuel exhaust manifold for directing a fuel stream from at least one of said anodes, wherein a fuel stream passageway fluidly interconnecting said fuel exhaust manifold to an anode traverses a portion of adjoining non-active surfaces of a pair of said separator plates.

4. The electrochemical fuel cell stack of claim 1 wherein passages for a coolant are formed between cooperating non-active surfaces of a pair of said separator plates.

5. The electrochemical fuel cell stack of claim 1 wherein at least one coolant channel is formed in said active surface of at least one of said cathode plates.

6. The electrochemical fuel cell stack of claim 1 wherein at least one coolant channel is formed in said active surface of at least one of said anode plates.

7. The electrochemical fuel cell stack of claim 1 wherein at least one fuel flow field channel is formed in said active surface of each anode plate, said at least one fuel flow field channel capable of distributing a fuel stream from said fuel supply manifold across at least a portion of the contacted anode, and at least one oxidant flow field channel is formed in said active surface of each cathode plate, said at least one oxidant flow field channel capable of distributing an oxidant stream from said oxidant supply manifold across at least a portion of the contacted cathode.

8. The electrochemical fuel cell stack of claim 1 wherein, for each of said pairs of separator plates, said adjoining non-active surfaces of said anode plate and said cathode plate are bonded together.

9. The electrochemical fuel cell stack of claim 8 wherein said adjoining non-active surfaces are bonded together using an electrically conductive adhesive.

10. The electrochemical fuel cell stack of claim 1 wherein said oxidant supply manifold and said fuel supply manifold are internal manifolds comprising aligned openings formed in said plurality of membrane electrode assemblies and said separator plates.

11. The electrochemical fuel cell stack of claim 1 wherein said oxidant supply manifold and said fuel supply manifold are external manifolds extending from an edge face of said fuel cell stack.

12. The electrochemical fuel cell stack of claim 1 wherein said passageways comprise open-faced channels formed in the non-active surface of one plate of said pair of separator plates.

13. The electrochemical fuel cell stack of claim 1 wherein said passageways comprise open-faced channels formed in the non-active surfaces of both plates of said pair of separator plates.