Polyolefin film containing cycloolefin polymer, process for the production thereof, and the use thereof

• US 6,068,936 A
• Filed: 09/30/1996
• Issued: 05/30/2000
• Est. Priority Date: 09/28/1995
• Status: Expired due to Term

• Current Assignee: Ticona GmbH (Celanese Corporation)
• Original Assignee: Ticona GmbH (Celanese Corporation)
• Inventors: Schlogl, Gunter, Peiffer, Herbert, Osan, Frank, Dries, Thomas
• Primary Examiner(s): YAMNITZKY, MARIE ROSE
• Application Number:
  US08/722,976
• Time in Patent Office: 1,338 Days
• Field of Search: 264/131, 264/173, 264/173.12, 264/173.16, 264/176.1, 427/201, 427/203, 428/339, 428/349, 428/516, 428/910, 428/500, 428/515, 428/519, 428/523, 156/244.11, 525/210
• US Class Current: 428/500
• CPC Class Codes: C08J 2323/10 Homopolymers or copolymers of propene
• CPC Class Codes: C08J 5/18 Manufacture of films or sheets
• CPC Class Codes: C08L 23/10 Homopolymers or copolymers of propene
• CPC Class Codes: C08L 23/142 at least partially crystalline copolymers of propene with other olefins
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 45/00 Compositions of homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic ring system; Compositions of derivatives of such polymers of cyclic anhydrides or imides C08L35/00; of cyclic esters of polyfunctional acids C08L31/00
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/04 Polysiloxanes
• CPC Class Codes: Y10S 428/91 Product with molecular orientation
• CPC Class Codes: Y10T 428/31855 Of addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31909 Next to second addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31913 Monoolefin polymer
• CPC Class Codes: Y10T 428/31924 Including polyene monomers
• CPC Class Codes: Y10T 428/31938 Polymer of monoethylenically unsaturated hydrocarbon

Abstract

A polyolefin film which includes at least one layer containing polyolefin and cycloolefin polymer (COP), where the cycloolefin polymer is amorphous and has a mean molecular weight M_w in the range from 200 to 100,000, and this mean molecular weight M_w of the cycloolefin polymer is at most 50% of the mean molecular weight M_w of the polyolefin, and the cycloolefin polymer is a homopolymer or a copolymer containing at most 20% by weight of comonomer.

Claims

1. A film structure comprising a major amount of olefinic polymer which includes at least one mixed-polymer layer containing a non-cyclic polyolefin, hereafter referred to as a polyolefin, and a cycloolefin polymer, hereafter referred to as a COP, the polymer composition of said mixed-polymer layer being essentially homogeneous and comprising, based on the weight of said layer:

at least 50% by weight of polyolefin, and

a polyolefin-compatible amount, which is less than 50% by weight, of COP,

wherein said COP is essentially amorphous and has a mean molecular weight, M_w, in the range from 200 to 100,000, and the M_w of the COP ranges from 0.05 to at most 50% of the M_w of said polyolef in, said COP containing up to 20% by weight of comonomer.

2. A film structure as claimed in claim 1, wherein the mixed-polymer layer contains, based on the weight of said layer, from 60 to 99% by weight of a polyolefin and from 1 to 40% by weight of a COP.

3. A film structure as claimed in claim 1, wherein, in said mixed-polymer layer, the M_w of the polyolefin ranges from 150,000 to 400,000.

4. A film structure as claimed in claim 1, wherein, in said mixed-polymer layer, the polyolefin has a molecular weight distribution, M_w /M_n, which is in the range from about 2 to about 15.

5. A film structure as claimed in claim 1, wherein, in said mixed-polymer layer, the M_w of the COP is from 200 to 20,000.

6. A film structure as claimed in claim 1, wherein, in said mixed-polymer layer, the COP has a molecular weight distribution, M_w /M_n, which is in the range from 1 to 5.

7. A film structure as claimed in claim 1, wherein, in said mixed-polymer layer, the COP is polynorbornene, polydimethyloctahydronaphthalene, polycyclopentene or poly(5-methyl)norbornene.

8. A film structure as claimed in claim 1, wherein the film structure comprises a plurality of layers including a further layer which is essentially transparent, and the film structure has a haze, measured in accordance with ASTM-D 1003-52, of less than 3.0.

9. A film structure as claimed in claim 8, wherein said further layer contains from 75 to 100% by weight of an α

-olefinic polymer.

10. A film structure as claimed in claim 1, wherein the film structure comprises a plurality of layers including a further layer which is essentially opaque, and the film structure has a light transparency of less than 95%, measured in accordance with ASTM-D 1003-77.

11. A film structure as claimed in claim 10, wherein said further layer contains, based on the weight of the layer, from 1 to 25% by weight of vacuole-initiating filler or pigment or a mixture of said filler and said pigment.

12. A film structure as claimed in claim 1, wherein the polyolefin of said mixed-polymer layer is a propylene polymer having a molecular weight distribution, M_w /M_n, of about 2 to about 6.

13. A film structure as claimed in claim 1, wherein the film structure comprises a plurality of layers, and the layers other than said mixed-polymer layer comprise at least 75% of an olefinic polymer having 2 to 10 carbon atoms in the olefinic monomer.

14. A polyolefin film as claimed in claim 1, wherein the polyolefin of said mixed-polymer layer comprises a propylene polymer.

15. A polyolefin film structure as claimed in claim 14, wherein said propylene polymer has been peroxidically degraded.

16. A polyolefin film structure as claimed in claim 1, wherein said mixed-polymer layer is the sole layer of said film structure.

17. A polyolefin film structure as claimed in claim 1, wherein the film structure has been oriented, at least monoaxially.

18. A packaging material, twist-wrap film, barrier film, laminated film, or printed film comprising the film structure as claimed in claim 1.

19. A packaging material comprising a film structure as claimed in claim 1.

20. A process for the production of a film structure, comprising

preparing at least one polymeric mixture comprising, for each 100 parts by weight of polymer, at least 50 parts by weight of polyolefin, and a polyolefin-compatible amount, not exceeding 50 parts by weight, of cycloolefin polymer, hereafter COP, wherein said COP is essentially amorphous and has a mean molecular weight, M_w, in the range from 200 to 100,000, and the M_w of the COP ranges from 0.05 to at most 50% of the M_w of said polyolefin, said COP containing up to 20% by weight of comonomer, and wherein the resulting polymeric mixture is essentially homogeneous,

compressing and warming the resulting polymeric mixture in an extruder to form a melt,

extruding said melt through a flat-film die, alone or in combination with at least one additional melt, to obtain a film structure, wherein said extruding step is carried out at a temperature above the glass transition temperature of the COP,

taking off the resulting film structure over at least one roll, said film structure being essentially free of optical flaws caused by incompatibility,

optionally orienting said resulting film structure, and optionally heat-setting and surface-treating said resulting film structure.