Acicular calcite and aragonite calcium carbonate

• US 6,071,336 A
• Filed: 09/05/1996
• Issued: 06/06/2000
• Est. Priority Date: 09/05/1996
• Status: Expired due to Fees

• Current Assignee: Minerals Technologies Incorporated
• Original Assignee: Minerals Technologies Incorporated
• Inventors: Fairchild, George Henry, Thatcher, Richard Louis
• Primary Examiner(s): Dunn, Tom
• Assistant Examiner(s): Hendrickson, Stuart L.
• Application Number:
  US08/711,427
• Time in Patent Office: 1,370 Days
• Field of Search: 423/430, 423/432, 106/464
• US Class Current: 106/464
• CPC Class Codes: C01F 11/182 Preparation of calcium carbonate by carbonation of aqueous solutions and characterised by an additive other than CaCO3-seeds
• CPC Class Codes: C01P 2004/10 extending in one dimension, e.g. needle-like
• CPC Class Codes: C01P 2004/12 with a cylindrical shape
• CPC Class Codes: C01P 2004/45 Aggregated particles or particles with an intergrown morphology
• CPC Class Codes: C01P 2004/50 Agglomerated particles
• CPC Class Codes: C01P 2004/61 Micrometer sized, i.e. from 1-100 micrometer
• CPC Class Codes: C01P 2006/12 Surface area

Abstract

The present invention relates to a calcium carbonate composition having both calcite and aragonite crystalline morphology. More particularly, the present invention relates to an acicular calcite and an acicular aragonite product and a method for the production of the same and the use of such as fillers, additives and modifiers of consumer and commercial products such as toothpaste, paper, plastics and sealants. The acicular calcite/aragonite composition of the present invention provides a balance of properties such as sheet bulk, strength, stiffness, and sizing, when employed as a filler for paper. As a coating pigment, the acicular calcite/aragonite product of the present invention provides gloss characteristics suitable for dull and matte grades of low gloss coated paper. Upon further processing such as milling, grinding, or other means of comminution, the resulting product provides gloss characteristics suitable for high gloss coated paper. For paint formulations, the acicular calcite/aragonite composition of the present invention provides properties such as low sheen and high contrast ratio. As an additive in polymers, the acicular calcite/aragonite product of the present invention imparts reinforcing properties, rigidity, and impact strength, including sealant applications.

Claims

1. A composition comprising a water soluble aluminum compound and spherical clusters of acicular calcite and acicular aragonite calcium carbonate, wherein the ratio of acicular calcite and acicular aragonite is from about 25 percent calcite and 75 percent aragonite to about 75 percent calcite and 25 percent aragonite and the spherical clusters consist of rod-shaped or needle-shaped acicular crystals, said spherical clusters being of average equivalent spherical diameter of from about 2.0 microns to about 8.0 microns and a specific surface area of from about 5.0 m² /g to about 10 m² /g and wherein said rod-shaped or needle-shaped crystals being of a length of from about 1.0 microns to about 4.0 microns and a width of from about 0.1 microns to about 0.5 microns.

2. The composition according to claim 1 wherein the water soluble aluminum compound is selected from the group consisting of anhydrous aluminum chloride, aluminum chloride hydrate, polyaluminum chloride, aluminum nitrate, sodium aluminum sulfate, potassium aluminum sulfate, ammonium aluminum sulfate, anhydrous aluminum sulfate, and aluminum sulfate hydrate.

3. The composition according to claim 2 wherein the water soluble aluminum compound is aluminum sulfate hydrate.

4. The composition according to claim 3 wherein the amount of water soluble aluminum compound ranges from about 1.5 percent to about 3.0 percent, based on the dry weight of clustered acicular calcite and acicular aragonite crystals.