Hydrophilic polymeric phase inversion membrane

• US 6,071,406 A
• Filed: 08/20/1999
• Issued: 06/06/2000
• Est. Priority Date: 11/12/1996
• Status: Expired due to Fees

• Current Assignee: Whatman, Inc. (General Electric Co. (Italy))
• Original Assignee: Whatman, Inc. (General Electric Co. (Italy))
• Inventors: Tsou, Dean T.
• Primary Examiner(s): Fortuna, Ana
• Application Number:
  US09/308,020
• Time in Patent Office: 291 Days
• Field of Search: 210/500.27, 210/500.36, 210/500.41, 210/500.43, 210/500.38, 264/41, 264/48, 264/49
• US Class Current: 210/500.41
• CPC Class Codes: B01D 2323/02 Hydrophilization
• CPC Class Codes: B01D 67/0018 Thermally induced processes [TIPS]
• CPC Class Codes: B01D 71/68 Polysulfones; Polyethersulfones

Abstract

A process for rendering hydrophilic a separation membrane having a hydrophobic matrix polymer comprises doping the membrane solvent system with a cyclic ester additive which is compatible with the matrix polymer and adding a wetting agnet additive, such that the resulting membrane is instantaneously wetted. The invention further relates to the membrne formed in accord with this process.

Claims

1. A process for rendering hydrophilic a separation membrane having a hydrophobic matrix polymer comprising preparing a membrane solvent system, said system comprising a hydrophobic bulk matrix polymer which absorbs less than 0.5% of its weight of water over a 24 hour period and 4% or less of its weight of water at equilibrium, and a block copolymer wetting agent having hydrophobic and hydrophilic polymer units, and doping said membrane solvent system with γ

-butyrolactone additive which is compatible with the bulk matrix polymer and which is capable of positioning the hydrophilic portion of the block copolymer at the matrix-solvent interface during membrane preparation, such that the resulting membrane is substantially instantaneously wetted as compared to the wetting rate of the same membrane solvent system without the γ

-butyrolactone additive.

2. The process of claim 1 wherein the hydrophobic matrix polymer is polyethersulfone.

4. The process of claim 1 wherein the block copolymer wetting agent additive includes hydrophobic units comprising alkyl group-containing units selected from the group consisting of propylene oxide and butylene oxide and hydrophilic units comprising ethylene oxide.

5. The process of claim 4 wherein the block copolymer wetting agent additive comprises repeating sequences of propylene oxide-ethylene oxide-propylene oxide block copolymer units.

3. The process of claim 3 wherein the γ

-butyrolactone is added as at least 7.5% of the membrane solvent system.

6. An instantaneous wetting filtration membrane comprising a hydrophobic polymer in combination with a block copolymer wetting agent and γ

-butyrolactone solvent additive, the additive being compatible with the matrix polymer and enhancing the capability of the wetting agent to render the matrix polymer hydrophilic and instantaneously wetted.

7. The filtration membrane of claim 6 wherein the hydrophobic matrix polymer is polyethersulfone.

8. The filtration membrane of claim 6 wherein the block copolymer wetting agent comprises hydrophobic units and hydrophilic units.

9. The filtration membrane of claim 6 wherein the block copolymer comprises alkyl group containing hydrophobic units selected from propylene oxide and butylene oxide and hydrophilic ethylene oxide units.

10. The filtration membrane of claim 6 wherein the block copolymer wetting agent is a propylene oxide-ethylene oxide-propylene oxide block copolymer.

11. The filtration membrane of claim 10 wherein the membrane is substantially permanently hydrophilic.