Hydrophilic film and method for forming same on substrate

• US 6,071,606 A
• Filed: 08/26/1997
• Issued: 06/06/2000
• Est. Priority Date: 08/26/1996
• Status: Expired due to Fees

• Current Assignee: Central Glass Company Limited, Nissan Motor Co., Ltd.
• Original Assignee: Central Glass Company Limited, Nissan Motor Co., Ltd.
• Inventors: Sugawara, Satoko, Seino, Takashi, Kai, Yasuaki, Makita, Kensuke, Yamazaki, Seiji
• Primary Examiner(s): Speer, Timothy M.
• Application Number:
  US08/917,617
• Time in Patent Office: 1,015 Days
• Field of Search: 428/325, 428/428, 428/432
• US Class Current: 428/325
• CPC Class Codes: C03C 17/007 containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
• CPC Class Codes: C03C 17/256 Coating containing TiO2
• CPC Class Codes: C03C 17/3411 with at least two coatings of inorganic materials C03C17/36, C03C17/42 take precedence
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 2217/23 Mixtures
• CPC Class Codes: C03C 2217/45 Inorganic continuous phases
• CPC Class Codes: C03C 2217/475 Inorganic materials
• CPC Class Codes: C03C 2217/478 Silica
• CPC Class Codes: C03C 2218/113 by sol-gel processes
• CPC Class Codes: C23C 18/1216 Metal oxides C23C18/1212 takes precedence
• CPC Class Codes: C23C 18/1225 Deposition of multilayers of inorganic material
• CPC Class Codes: C23C 18/1254 Sol or sol-gel processing
• CPC Class Codes: C23C 26/00 Coating not provided for in groups C23C2/00 - C23C24/00
• CPC Class Codes: Y10T 428/252 Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]

Abstract

The invention relates to a hydrophilic film formed on a substrate. This film has a hydrophilic outermost layer having a matrix phase containing titania and a disperse phase constituted of at least one compound of silica and alumina. The matrix phase may further contain an amorphous metal oxide. With this, the outermost layer becomes superior in abrasion resistance. The at least one compound of the disperse phase may be a non-spherical colloidal silica. With this, the outermost layer becomes substantially improved in scratch resistance. The outermost layer is formed on the substrate by a method including sequential steps of (a) providing a sol mixture including a first sol containing a precursor of the titania and a second sol containing the at least one compound; (b) coating the substrate with the sol mixture, thereby to form thereon a precursory film; and (c) baking the precursory film into the outermost layer.

Claims

1. A hydrophilic article comprising:

a substrate; and

a hydrophilic film formed on the substrate,

wherein the film has a hydrophilic outermost layer, wherein the outermost layer has a matrix phase and a disperse phase distributed over the matrix phase, wherein the matrix phase comprises a combination of titania and an amorphous metal oxide and the disperse phase comprises at least one compound which is selected from the group consisting of silica and alumina and is in a form of particles, wherein the amorphous metal oxide has a particle diameter that is less than that of the at least one compound.

2. A hydrophilic film according to claim 1, wherein said amorphous metal oxide is in an amount of from 10 to 25 mol %, based on a total number of moles of said titania and said amorphous metal oxide.

3. A hydrophilic film according to claim 1, wherein said at least one compound is in an amount of from 10-50 wt %, based on a total weight of said hydrophilic outermost layer.

4. A hydrophilic film according to claim 1, wherein said substrate is made of a soda-lime glass.

5. A hydrophilic film according to claim 4, wherein said hydrophilic film further has an intermediate layer interposed between said substrate and said outermost layer, said intermediate layer being made of a metal oxide, such that there is prevented a migration of a sodium ion from said substrate to said outermost layer.

6. A hydrophilic film according to claim 5, wherein said metal oxide of said intermediate layer is one selected from the group consisting of silica, alumina and a double oxide of silica and alumina.

7. A hydrophilic film according to claim 1, wherein said titania is an anatase-type titania.

8. A hydrophilic film according to claim 1, wherein said amorphous metal oxide is at least one selected from the group consisting of silica, alumina, zirconia and mixtures of at least two of these.

9. A hydrophilic article according to claim 1, which is an automotive window glass pane.

10. A hydrophilic article according to claim 1, which is an automotive outside mirror.

11. A hydrophilic article comprising:

a substrate; and

a hydrophilic film formed on the substrate,

wherein the film has a hydrophilic outermost layer, wherein the outermost layer has a matrix phase and a disperse phase distributed over the matrix phase, wherein the matrix phase comprises a combination of titania and an amorphous metal oxide and the disperse phase comprises at least one compound which is selected from the group consisting of silica and alumina and is in a form of particles, wherein the amorphous metal oxide has a particle diameter that is less than that of the said at least one compound, the outermost layer prepared by a method comprising the sequential steps of;

(a) providing a sol mixture including a first sol containing a precursor of the titania, a second sol containing the at least one compound, and a third sol containing a precursor of the amorphous metal oxide;

(b) coating the substrate with the sol mixture, thereby to form thereon a precursory film; and

(c) baking the precursory film into the outermost layer.

12. A hydrophilic film according to claim 11, wherein said at least one compound is a colloidal silica which is in a non-spherical form.

13. A hydrophilic film according to claim 12, wherein said outermost layer contains 20-70 wt % of said colloidal silica.

14. A hydrophilic film according to claim 12, wherein said colloidal silica includes an elongate portion which has a diameter of from 5 to 50 nm and an axial length of from 40 to 500 nm.

15. A hydrophilic film according to claim 11, wherein said outermost layer has a thickness of from 20 to 500 nm.

16. A hydrophilic film according to claim 11, wherein said hydrophilic film has a metal oxide interlayer which is directly formed on said substrate, prior to the step (b), such that said metal oxide interlayer is interposed between said substrate and said outermost layer.

17. A hydrophilic film according to claim 11, wherein the step (c) is conducted at a temperature of from 300 to 850°

C.

18. A hydrophilic film according to claim 11, wherein the step (c) is conducted at a temperature of from 400 to 850°

C.

19. A hydrophilic article according to claim 11, wherein said at least one compound has a particle diameter of from 1 to 60 nm.