Hydrophilic article and method for producing same

• US 6,071,623 A
• Filed: 07/15/1998
• Issued: 06/06/2000
• Est. Priority Date: 02/13/1998
• Status: Expired due to Fees

• Current Assignee: Central Glass Company Limited, Nissan Motor Co., Ltd.
• Original Assignee: Central Glass Company Limited, Nissan Motor Co., Ltd.
• Inventors: Kai, Yasuaki, Yamazaki, Seiji, Sugawara, Satoko
• Primary Examiner(s): Speer, Timothy M.
• Application Number:
  US09/115,740
• Time in Patent Office: 692 Days
• Field of Search: 428/428, 428/432, 428/701, 428/702, 428/325, 427/163.1, 427/165, 427/168, 427/169, 427/372.2, 427/397.7, 65/60.52
• US Class Current: 428/428
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 2217/71 Photocatalytic coatings
• CPC Class Codes: C23C 18/1216 Metal oxides C23C18/1212 takes precedence
• CPC Class Codes: C23C 18/1225 Deposition of multilayers of inorganic material
• CPC Class Codes: C23C 18/1245 Inorganic substrates other than metallic
• CPC Class Codes: Y10T 428/252 Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]

Abstract

The invention relates to a hydrophilic article having (a) a substrate; (b) a first layer formed on the substrate; and (c) a second layer formed on the first substrate. The first layer contains (1) an amorphous silica and (2) at least one first amorphous metal oxide selected from titania and alumina. The second layer has (1) a matrix phase constituted of a crystalline titania and at least one second amorphous metal oxide and (2) a dispersed phase constituted of ultrafine particles made of at least one material selected from silica and alumina. The hydrophilic article is excellent in durability, since the second layer is superior in adhesion to the first layer. The hydrophilic article can be produced by a method including steps of (a) providing a first solution containing a precursor of the amorphous silica and a precursor of the at least one first amorphous metal oxide; (b) applying the first solution to the substrate, thereby to form a first precursory layer; (c) providing a second solution containing a precursor of the crystalline titania, the ultrafine particles, and a precursor of the at least one second amorphous metal oxide; (d) applying the second solution to the first precursory layer, thereby to form a second precursory layer; and (e) baking the first and second precursory layers into the first and second layers.

Claims

1. A hydrophilic article comprising:

(a) a substrate;

(b) a first layer formed on said substrate, said first layer comprising (1) an amorphous silica and (2) at least one first amorphous metal oxide selected from the group consisting of titania and alumina; and

(c) a second layer formed on said first layer, said second layer comprising (1) a matrix phase constituted of a crystalline titania and at least one second amorphous metal oxide and (2) a dispersed phase constituted of ultrafine particles made of at least one material selected from the group consisting of silica and alumina.

2. A hydrophilic article according to claim 1, wherein said first layer contains 45-92 wt % of said amorphous silica and 8-55 wt % of said at least one first amorphous metal oxide, based on a total weight of said amorphous silica and said at least one first amorphous metal oxide.

3. A hydrophilic article according to claim 1, wherein said second layer contains 40-92 wt % of said crystalline titania, 3-30 wt % of said ultrafine particles, and 5-30 wt % of said at least one second amorphous metal oxide, based on a total weight of said titania, said ultrafine particles and said at least one second amorphous metal oxide.

4. A hydrophilic article according to claim 1, wherein said at least one second amorphous metal oxide is selected from the group consisting of silica, alumina and zirconia.

5. A hydrophilic article according to claim 1, wherein each of said first and second layers has a thickness of from about 50 to about 200 nm.

6. A hydrophilic article according to claim 1, wherein said substrate comprises an alkali component.

7. A hydrophilic article according to claim 6, wherein said substrate is made of a soda-lime glass containing sodium as said alkali component.

8. A hydrophilic article according to claim 1, wherein said crystalline titania of said second layer is an anatase-type titania.

9. A hydrophilic article according to claim 1, wherein said ultrafine particles have a particle diameter of not greater than about 1 μ

m.

10. A hydrophilic article according to claim 1, wherein said ultrafine particles are made of colloidal silica.

11. A method for producing a hydrophilic article, said hydrophilic article comprising (a) a substrate;

(b) a first layer formed on said substrate, said first layer comprising (1) an amorphous silica and (2) at least one first amorphous metal oxide selected from the group consisting of titania and alumina; and

(c) a second layer formed on said first layer, said second layer comprising (1) a matrix phase constituted of a crystalline titania and at least one second amorphous metal oxide and (2) a dispersed phase constituted of ultrafine particles made of at least one material selected from the group consisting of silica and alumina, said method comprising steps of;

(a) providing a first solution comprising a precursor of said amorphous silica and a precursor of said at least one first amorphous metal oxide;

(b) applying said first solution to said substrate, thereby to form a first precursory layer;

(c) providing a second solution comprising a precursor of said crystalline titania, said ultrafine particles, and a precursor of said at least one second amorphous metal oxide;

(d) applying said second solution to said first precursory layer, thereby to form a second precursory layer; and

(e) baking said first and second precursory layers into said first and second layers.

12. A method according to claim 11, wherein said precursor of said amorphous silica is selected from the group consisting of silicon nitrates, organosilicates, silicon acetylacetonates and silicon alkoxides, and wherein said precursor of said at least one first amorphous metal oxide is selected from the group consisting of titanium nitrates, aluminum nitrates, titanium salts prepared by combining titanium hydroxides and organic acids, aluminum salts prepared by combining aluminum hydroxides and organic acids, titanium acetylacetonates, aluminum acetylacetonates, titanium alkoxides, and aluminum alkoxides.

13. A method according to claim 11, wherein the step (e) is conducted at a temperature of from 380 to 750°

C.

14. A method according to claim 11, wherein said substrate comprises an alkali component.

15. A method according to claim 14, wherein said substrate is made of a soda-lime glass containing sodium as said alkali component.

16. A method according to claim 11, wherein, prior to the step (d), said first precursory layer is dried at a temperature of from room temperature to about 300°

C., and wherein, prior to the step (e), said second precursory layer is dried at a temperature of from room temperature to about 300°

C.