Process for selective hydrogenation of a hydrocarbon cut containing at least three carbon atoms

• US 6,072,091 A
• Filed: 08/26/1997
• Issued: 06/06/2000
• Est. Priority Date: 12/27/1995
• Status: Expired due to Term

• Current Assignee: Institut Francais Du Petrole
• Original Assignee: Institut Francais Du Petrole
• Inventors: Cosyns, Jean, Lebas, Etienne, Nocca, Jean-Luc, Didillon, Blaise, Montecot, Francoise
• Primary Examiner(s): Yildirim, Bekir L.
• Application Number:
  US08/894,691
• Time in Patent Office: 1,015 Days
• Field of Search: 585/258, 585/259, 585/261, 585/264, 585/275, 585/277, 585/841, 208/144
• US Class Current: 585/259
• CPC Class Codes: B01D 3/009 in combination with chemical reactions
• CPC Class Codes: B01J 8/0257 in a cylindrical annular shaped bed
• CPC Class Codes: B01J 8/0278 Feeding reactive fluids for solid material B01J8/0015
• CPC Class Codes: C07C 11/09 Isobutene
• CPC Class Codes: C07C 5/02 by hydrogenation simultaneous hydrogenation and dehydrogenation C07C5/52
• CPC Class Codes: C07C 5/2767 Changing the number of side-chains
• CPC Class Codes: C10G 45/00 Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
• CPC Class Codes: C10G 45/40 containing platinum group metals or compounds thereof
• CPC Class Codes: C10G 45/44 Hydrogenation of the aromatic hydrocarbons
• CPC Class Codes: C10G 49/002 Apparatus for fixed bed hydrotreatment processes
• CPC Class Codes: Y02P 20/10 Process efficiency
• CPC Class Codes: Y10S 203/06 Reactor-distillation

Abstract

A process for the treatment of a feed comprising at least hydrocarbons containing at least 3 to 10 carbon atoms per molecule, including acetylenic and diolefinic hydrocarbons, comprises passing the feed into a distillation zone associated with a selective hydrogenation reaction zone comprising at least one catalytic hydrogenation bed which is internal to or external of the distillation zone, in which hydrogenation of at least a portion of the acetylenic and diolefinic hydrocarbons contained in the feed is carried out in the presence of a gas stream rich in hydrogen. The process is particularly suitable for the treatment of products from catalytic cracking.

Claims

1. A process for selectively hydrogenating at least one of acetylenic and diolefinic hydrocarbons present in a feed comprising hydrocarbons of from 3-10 carbon atoms, said process comprising:

at a feedpoint, passing said feed into a distillation zone including a rectifying zone, wherein liquid flows therein;

drawing off at least one intermediate level of the rectifying zone at least one side stream representing a major portion of the liquid flowing in the rectification section zone at said level;

sending said at least one side stream to at least one separate selective hydrogenation reaction zone comprising at least one catalytic bed being fed with a gas stream rich in hydrogen so as to produce a hydrogenated effluent, said at least one selective hydrogenation zone being at least partially internal to and in communication with the distillation zone;

introducing at least a major portion of the hydrogenated effluent of said at least one selective hydrogenation reaction zone into the rectifying section of the distillation zone to ensure continuity of the distillation; and

recovering a distillate highly depleted in acetylenic and/or diolefinic hydrocarbons at the head of the distillation zone and, at the bottom of the distillation zone, a residue depleted in acetylenic and/or diolefinic hydrocarbons,

with the provision that vapor in the distillation zone is maintained out of contact with all selective hydrogenation reaction zones.

2. A process according to claim 1, wherein the acetylenic and/or diolefinic hydrocarbons to be selectively hydrogenated contain at most 5 carbon atoms, said process conducted so as to cause an effluent which is highly depleted in acetylenic and/or diolefinic hydrocarbons containing at most 5 carbon atoms to leave the head of the distillation column and an effluent which is also depleted in said acetylenic and/or olefinic compounds to leave the bottom of the distillation column.

3. A process according to claim 1, characterized in that said at least one selective hydrogenation zone comprises 1 to 4 catalytic beds.

4. A process according to claim 1, characterized in that the selective hydrogenation zone in communication with the distillation zone is completely internal to said distillation zone.

5. A process according to claim 1, comprising at least two selective hydrogenation reaction zones, at least one zone being internal to the distillation zone and at least one other zone being external of said distillation zone.

6. A process according to claim 1, characterized in that the catalyst is a supported catalyst comprising at least one noble metal from group VIII.

7. A process according to claim 6, characterized in that the catalyst is a palladium catalyst.

8. A process according to claim 3, wherein the acetylenic and/or diolefinic hydrocarbons to be selectively hydrogenated contain at most 5 carbon atoms, said process conducted so as to cause an effluent which is highly depleted in said acetylenic and/or diolefinic hydrocarbons containing at most 5 carbon atoms to leave the head of the distillation column and an effluent which is also depleted in said acetylenic and/or olefinic compounds to leave the bottom of the distillation column.

9. A process according to claim 2, wherein the acetylenic and/or diolefinic hydrocarbons to be selectively hydrogenated contain at most 5 carbon atoms, said process conducted so as to cause an effluent which is highly depleted in acetylenic and/or diolefinic hydrocarbons containing at most 5 carbon atoms to leave the head of the distillation column and an effluent which is also depleted in said acetylenic and/or olefinic compounds to leave the bottom of the distillation column.

10. A process according to claim 2, characterized in that the selective hydrogenation zone in communication with the distillation zone is internal to said distillation zone.

11. A process according to claim 2, characterized in that the selective hydrogenation zone in communication with the distillation zone is external to said distillation zone.

12. A process according to claim 1, comprising at least two selective hydrogenation reaction zones, at least one selective hydrogenation zone being internal to the distillation zone and at least one other selective hydrogenation zone being external of said distillation zone.

13. A process according to claim 8, characterized in that the selective hydrogenation zone in communication with the distillation zone is internal to said distillation zone.

14. A process according to claim 8, characterized in that the selective hydrogenation zone in communication with the distillation zone is external to said distillation zone.

15. A process according to claim 8, comprising at least two selective hydrogenation reaction zones, at least one selective hydrogenation zone being internal to the distillation zone and at least one other selective hydrogenation zone being external of said distillation zone.

16. A process according to claim 9, characterized in that the selective hydrogenation zone in communication with the distillation zone is internal to said distillation zone.

17. A process according to claim 9, characterized in that the selective hydrogenation zone in communication with the distillation zone is external to said distillation zone.

18. A process according to claim 9, comprising at least two selective hydrogenation reaction zones, at least one selective hydrogenation zone being internal to the distillation zone and at least one other selective hydrogenation zone being external of said distillation zone.

19. A process according to claim 1, comprising at least two of said side streams, each side stream being passed to a separate selective hydrogenation zone.

20. A process according to claim 1, wherein said at least one side stream is removed from the distillation zone at above the feedpoint.

21. A process according to claim 1, wherein all side streams are removed from the distillation zone at above the feedpoint.