Material analysis

• US 6,072,853 A
• Filed: 06/08/1998
• Issued: 06/06/2000
• Est. Priority Date: 09/27/1995
• Status: Expired due to Term

• Current Assignee: Schlumberger Technology Corporation (SLB)
• Original Assignee: Schlumberger Technology Corporation (SLB)
• Inventors: Hall, Christopher
• Primary Examiner(s): Church, Craig E.
• Application Number:
  US09/043,493
• Time in Patent Office: 729 Days
• Field of Search: 378/70-81
• US Class Current: 378/73
• CPC Class Codes: G01N 23/207 Diffractometry using detectors, e.g. using a probe in a central position and one or more displaceable detectors in circumferential positions

Abstract

A method and apparatus for analyzing drill core rock samples is described, utilizing a collimated beam of polychromatic X-ray photons of a brightness of at least 10¹⁵ photons/sec/mrad² /0.1% bandwidth and energies of at least 20 keV. A suitable source of such X-rays is a synchrotron.

Claims

1. A method of determining characteristics of a test crystalline material in which method a sample of the material is illuminated with a collimated beam of polychromatic X-ray photons, to produce diffracted X-rays, measurements are taken of the produced diffracted X-rays with an energy-dispersive detector receiving them via a collimator, and by comparing the found measurements with similar data defining known, reference materials, there are determined the required characteristics of the test material, which method is characterized in that

the test crystalline material is a drill core rock sample of a cylindrical shape having a core axis;

the beam of X-ray photons has a brightness of at least 10¹⁵ photons/sec/mrad² /0.1% bandwidth and energies of at least 20 keV;

and further characterized in that the relative position of the sample and the beam is moved in the direction of the core axis so as to determine characteristics of a plurality of portions along the core axis of the rock sample.

2. A method as claimed in claim 1, wherein the test material is a length of the drill core.

3. A method as claimed in claim 1, wherein for a high resolution system the X-ray beam is from 0.5 to 0.02 mm wide.

4. A method as claimed in claim 1, wherein the intensity of the X-rays is at least 10¹⁷ photons/sec/mrad² /0.1% bandwidth.

5. A method as claimed in claim 1, wherein the source of the X-rays is a synchrotron.

6. A method as claimed in claim 1, wherein the energy-dispersive detector is a semiconductor device.

7. A method as claimed in claim 1, wherein there are detected and measured those diffracted X-rays that have been transmitted through the sample.

8. A method as claimed claim 1, wherein:

first, by directing the detector collimator to point at a small spot at a known depth within the sample, and by rotating the sample, measurement by measurement, on a convenient axis, there is obtained a sequence of diffraction patterns defining a narrow ring of sample material;

next, by re-directing the detector collimator to point at a spot immediately adjacent the first (in a depth sense) and repeating the rotation, there is obtained a second sequence defining a second ring next to (and co-planar with) and contiguous with the first;

and by repeating this a sufficient number of times there is gained information about a disc of material--a "slice" through the sample;

and finally, by repeating this whole process several times, each after changing the relative positions of the sample and X-ray illuminator/detector by a small amount, there is obtained information about a series of slices along the length of the sample.

9. Apparatus for use in a method of determining characteristics of a drill core rock sample comprising:

a collimated beam source of polychromatic X-ray photons of a brightness of at least 10¹⁵ photons/sec/mrad² /0.1% bandwidth and energies of at least 20 keV;

mounting means for mounting a cylindrically shaped solid drill rock sample core having a core axis in the line of the X-rays from the source, whereby the X-rays may be diffracted by the test sample;

collimation means for collimating some of the diffracted X-rays into a narrow parallel beam;

an energy-dispersive detector receiving the collimated diffracted X-rays, and making measurements thereof;

comparison means for comparing the thus-made measurements with similar data defining known, reference materials, and thereby for determining the required characteristics of the test material; and

means for changing the relative positions of the rock sample and the beam so as to cause the rock sample to translocate in the direction of the core axis.

10. Apparatus as claimed in claim 9, wherein the X-ray source provides a beam of from 0.5 to 0.02 mm wide.

11. Apparatus as claimed in claim 9, wherein the X-ray source provides X-rays of at least 10¹⁷ photons/sec/mrad² /0.1% bandwidth.

12. Apparatus as claimed in claim 9, wherein the X-ray source is a synchrotron.

13. Apparatus as claimed in claim 9, wherein the energy-dispersive detector is a semiconductor device.

14. Apparatus as claimed in claim 9, wherein the mounting means is a table on which the test sample can be secured, which table is moveable so as to cause the sample to rotate about an axis and so as to cause the sample to translocate along a line.

15. Apparatus as claimed in claim 14, wherein the rotation and translocation are stepwise.