Self supporting hollow fiber membrane and method of construction

• US 6,074,718 A
• Filed: 02/06/1996
• Issued: 06/13/2000
• Est. Priority Date: 02/06/1996
• Status: Expired due to Fees

• Current Assignee: Koch Membrane Systems, Inc. (KOCH Industries Incorporated)
• Original Assignee: Koch Membrane Systems, Inc. (KOCH Industries Incorporated)
• Inventors: Puglia, John P., McKinley, David F.
• Primary Examiner(s): COPENHEAVER, BLAINE R
• Application Number:
  US08/597,609
• Time in Patent Office: 1,589 Days
• Field of Search: 210/500.23, 210/500.27, 210/500.35, 210/500.42, 428/36.5, 428/304.4, 428/373, 428/398
• US Class Current: 428/36.5
• CPC Class Codes: B01D 69/08 Hollow fibre membranes manufacture of hollow fibres D01D5/24, D01F1/08
• CPC Class Codes: B01D 71/34 Polyvinylidene fluoride
• CPC Class Codes: Y10T 428/1376 Foam or porous material containing
• CPC Class Codes: Y10T 428/2929 Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
• CPC Class Codes: Y10T 428/2975 Tubular or cellular

Abstract

A method for constructing a polyvinylidene fluoride based hollow fiber membrane from a polymer mixture using temperatures not greater than 80° C., the mixture comprising polyvinylidene fluoride, a pore forming agent, and a solvent. The mixture can also comprise a second polymer selected from the group comprising polymethylmethacrylate, polyvinylformal, polyvinyl alcohol, polyhexafluoropropylene, polydiacetylene, cellulose and copolymers thereof. The hollow fiber membranes formed using the controlled temperatures of this invention have acceptable strength characteristics and asymmetrical pore structures which provide a low transmembrane pressure drop.

Claims

1. A semipermeable hollow fiber ultrafiltration membrane for liquid/liquid separation formed from a composition comprising an engineering thermoplastic resin, wherein the thermoplastic resin is polyvinylidene fluoride, a pore forming agent, and a solvent capable of solubilizing the polyvinylidene fluoride and the pore forming agent, the membrane having an asymmetrical pore structure to provide a low transmembrane pressure drop, a porosity in the range of about 25% to about 60%, and pore sizes in the range of from about 0.003 to about 1 micron in diameter, wherein the membrane is capable of functioning as a liquid/liquid ultrafiltration separation membrane absent further treatment.

2. The semipermeable hollow fiber membrane as set forth in claim 1, further comprising a second thermoplastic resin blended with the polyvinylidene fluoride, wherein the second resin is selected from the group consisting of polymethylmethacrylate, polyvinylformal, polyvinyl alcohol, polyhexafluoropropylene, polydiacetylene, cellulose and copolymers thereof.

3. The semipermeable hollow fiber ultrafiltration membrane as set forth in claim 1, wherein the composition comprises about 5% to about 48% by weight polyvinylidene fluoride, about 1% to about 25% by weight pore forming agent, and about 45% to about 80% by weight solvent.

4. The semipermeable hollow fiber ultrafiltration membrane as set forth in claim 1, wherein the membrane has a burst pressure in the range of about 325 psi to about 390 psi.

5. A semipermeable hollow fiber ultrafiltration membrane for liquid/liquid separation constructed in accordance with a method comprising the steps of:

a) preparing a fiber forming material by contacting and mixing an engineering thermoplastic resin, a pore forming agent, and a solvent capable of solubilizing the thermoplastic resin and the pore forming agent, at a temperature between about 4° and

80°

C., to form a homogeneous solution, wherein the thermoplastic resin comprises polyvinylidene fluoride;

b) maintaining the solution at a temperature ranging from about 4°

to about 80°

C. during the mixing;

c) extruding the solution through a spinneret to form a hollow fiber; and

d) removing the solvent and pore forming agent from the solution to form a semipermeable hollow fiber ultrafiltration membrane having an asymmetrical pore structure,

the membrane having a porosity in the range of about 25% to about 60%, and pore sizes in the range of from about 0.003 to about 1 micron in diameter, and wherein the membrane is capable of functioning as a liquid/liquid ultrafiltration separation membrane absent further treatment.

6. The semipermeable hollow fiber membrane as set forth in claim 5, wherein the solution further comprises a second thermoplastic resin selected from the group consisting of polymethylmethacrylate, polyvinylformal, polyvinyl alcohol, polyhexafluoropropylene, polydiacetylene, cellulose, and copolymers thereof.

7. The semipermeable hollow fiber ultrafiltration membrane as set forth in claim 5, wherein the composition comprises about 5% to about 48% by weight polyvinylidene fluoride, about 1% to about 25% by weight pore forming agent, and about 45% to about 80% by weight solvent.

8. The semipermeable hollow fiber ultrafiltration membrane as set forth in claim 5, wherein the membrane has a burst pressure in the range of about 325 psi to about 390 psi.