Liquid-crystalline resin compositions and moldings

• US 6,075,114 A
• Filed: 06/29/1998
• Issued: 06/13/2000
• Est. Priority Date: 04/25/1997
• Status: Expired due to Term

• Current Assignee: Toray Industries Incorporated
• Original Assignee: Toray Industries Incorporated
• Inventors: Inoue, Toshihide, Makabe, Yoshiki, Umetsu, Hideyuki
• Primary Examiner(s): Boykin, Terressa M.
• Application Number:
  US09/091,435
• Time in Patent Office: 715 Days
• Field of Search: 528/183, 528/193, 528/194, 528/271, 528/272
• US Class Current: 528/272
• CPC Class Codes: C08K 2003/026 Phosphorus
• CPC Class Codes: C08K 3/02 Elements
• CPC Class Codes: C08K 3/32 Phosphorus-containing compounds
• CPC Class Codes: C08L 67/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds C08L67/06 takes precedence
• CPC Class Codes: C08L 77/12 Polyester-amides

Abstract

A liquid-crystalline resin composition comprising 100 parts by weight of a semi-aromatic liquid-crystalline polyester and/or a semi-aromatic liquid-crystalline polyester-amide, from 0.001 to 5 parts by weight of at least one or more compounds selected from phosphorous acid, hypophosphorous acid and their salts, and from 0.01 to 10 parts by weight of red phosphorus has good flame retardancy, low anisotropy, good heat resistance and good hydrolysis resistance, and is useful as engineering plastic.

Claims

1. A liquid-crystalline resin composition comprising 100 parts by weight of a semi-aromatic liquid-crystalline compound selected from the group consisting of polyester and polyester-amide, from 0.001 to 5 parts by weight of at least one or more compounds selected from the group consisting of phosphorous acid and hypophosphorous acid and their salts with a metal selected from the group consisting of Group I and Group II metals, and from 0.01 to 10 parts by weight of red phosphorus.

5. The liquid-crystalline resin composition as claimed in claim 1, wherein the red phosphorus is coated with a thermosetting resin.

6. The liquid-crystalline resin composition as claimed in claim 1, which further contains from 5 to 200 parts by weight of an inorganic filler relative to 100 parts by weight of said liquid-crystalline resin composition of claim 1.

7. The liquid-crystalline resin composition as claimed in claim 1, wherein said semi-aromatic liquid-crystalline polyester is has structural units selected from the group consisting of (I), (III) and (IV), and structural units of the following (I), (II), (III) and (IV):

##STR6## where R₁ represents one or more groups selected from the group consisting of the following ##STR7## R₂ represents one or more groups selected from the group consisting of the following;

##STR8## X represents a hydrogen atom or a chlorine atom; and

the total of the structural units (II) and (III) is substantially equimolar to the structural units (IV).

8. The liquid-crystalline resin composition as claimed in claim 1, which further contains from 0.01 to 20 parts by weight of a metal oxide relative to 100 parts by weight of a polymer selected from the group consisting of semi-aromatic liquid-crystalline polyester and semi-aromatic liquid-crystalline polyester-amide.

9. The liquid-crystalline resin composition as claimed in claim 8, wherein said metal oxide is selected from the group consisting of cadmium oxide, zinc oxide, cuprous oxide, cupric oxide, ferrous oxide, ferric oxide, cobalt oxide, manganese oxide, molybdenum oxide, tin oxide and titanium oxide.

10. The liquid-crystalline resin composition as claimed in claim 8, wherein said metal oxide is selected from the group consisting of cuprous oxide, cupric acid and titanium oxide.

12. A resin molding produced by molding the liquid-crystalline resin composition of claim 1.

13. The resin molding as claimed in claim 12, which is of a size for use in electric and electronic elements.

2. A liquid-crystalline resin composition comprising a semi-aromatic liquid-crystalline compound selected from the group consisting of polyester and polyester-amide, which has a phosphorus content of from 0.01 to 15% by weight, and a metal selected from the group consisting of Group I and Group II metals in a content of from 5 to 15000 ppm, the ratio of said phosphorus content (a) to said metal content (b) being not smaller than 1.5.

3. The liquid-crystalline resin composition as claimed in claim 2, wherein said phosphorus content is derived from at least one or more compounds selected from the group consisting of phosphorous acid, hypophosphorous acid and their salts, and red phosphorus.

4. The liquid-crystalline resin composition as claimed in claim 2, wherein said metal component is derived from one or more metal-containing compounds selected from the group consisting of Group I and Group II metal salts of phosphorous acid, Group I and Group II metal salts of hypophosphorous acid, and Group I and Group II metal salts of compounds except phosphorous acid and hypophosphorous acid.

11. A method for producing a liquid-crystalline resin composition, comprising adding to a polymer selected from the group consisting of a semi-aromatic liquid-crystalline polyester and a semi-aromatic liquid-crystalline polyester-amide, at least one or more compounds of phosphorous acid, hypophosphorous acid and their metal salts in an amount of from 0.001 to 5 parts by weight relative to 100 parts by weight of said polymer, and adding thereto red phosphorus in an amount of from 0.01 to 10 parts by weight relative to the same after the completion of the polymerization.