Method of crystallizing thin films when manufacturing semiconductor devices
First Claim
1. A method of manufacturing a semiconductor device comprising the steps of:
- forming a non-single crystalline semiconductor film on an insulating surface;
providing said semiconductor film with a catalyst material which is capable of promoting crystallization of said semiconductor film;
performing a first crystallization of said semiconductor film provided with said catalyst material;
performing a second crystallization of said semiconductor film after said first crystallization in an atmosphere containing a halogen compound gas in order to reduce a concentration of said catalyst material in said semiconductor film.
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Abstract
After a pattern is transferred on silicon film crystallized by annealing, the silicon film is annealed by radiation of intense rays for a short time. Especially, in the crystallizing process by annealing, an element which promotes crystallization such as nickel is doped therein. The area not crystallized by annealing is also crystallized by radiation of intense rays and a condensed silicon film is formed.
After a metal element which promotes crystallization is doped, annealing by light for a short time is performed by radiating intense rays onto the silicon film crystallized by annealing in an atmosphere containing halide. After the surface of the silicon film is oxidized by heating or by radiating intense rays in a halogenated atmosphere and an oxide film is formed on the silicon film, the oxide film is then etched. As a result, nickel in the silicon film is removed.
169 Citations
50 Claims
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1. A method of manufacturing a semiconductor device comprising the steps of:
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forming a non-single crystalline semiconductor film on an insulating surface; providing said semiconductor film with a catalyst material which is capable of promoting crystallization of said semiconductor film; performing a first crystallization of said semiconductor film provided with said catalyst material; performing a second crystallization of said semiconductor film after said first crystallization in an atmosphere containing a halogen compound gas in order to reduce a concentration of said catalyst material in said semiconductor film. - View Dependent Claims (2, 3, 4, 5, 6, 7, 50)
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8. A method of manufacturing a semiconductor device comprising the steps of:
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forming a non-single crystalline semiconductor film on an insulating surface of a substrate; disposing a catalyst material in contact with said non-single crystalline semiconductor film; crystallizing said non-single crystalline semiconductor film by heating wherein said catalyst material functions to promote the crystallization; patterning said semiconductor film after the crystallization into at least one semiconductor island; and irradiating said semiconductor island with a light having a wavelength of 4 μ
m to 0.5 μ
m in order to further increase the crystallinity of said semiconductor island. - View Dependent Claims (9, 10, 11, 12, 13)
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14. A method of manufacturing a semiconductor device comprising the steps of:
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forming a non-single crystalline semiconductor film on an insulating surface of a substrate; disposing a catalyst material in contact with said non-single crystalline semiconductor film; crystallizing said non-single crystalline semiconductor film by heating wherein said catalyst material functions to promote the crystallization; patterning said semiconductor film after the crystallization into at least one semiconductor island; and irradiating said semiconductor island with a light having a wavelength of 4 μ
m to 0.5 μ
m in order to further increase the crystallinity of said semiconductor island,wherein said irradiating step is carried out in an atmosphere including at least one of a fluorine containing material or a chlorine containing material. - View Dependent Claims (15, 16, 17, 18, 19, 20, 21)
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22. A method of manufacturing a semiconductor device comprising the steps of:
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forming a non-single crystalline semiconductor film on an insulating surface of a substrate; disposing a catalyst material in contact with said non-single crystalline semiconductor film, said catalyst material being for promoting crystallization of said semiconductor film; crystallizing said non-single crystalline semiconductor film by heating wherein amorphous areas are left between crystals in the semiconductor film; patterning said semiconductor film after the crystallization into at least one semiconductor island; and irradiating said semiconductor island with a light in order to crystallize said amorphous areas remaining after the crystallizing step. - View Dependent Claims (23, 24, 25, 26, 27, 28, 29, 30)
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31. A method of manufacturing a semiconductor device comprising the steps of:
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forming a non-single crystalline semiconductor film on an insulating surface of a substrate; disposing a catalyst material in contact with a selected portion of said non-single crystalline semiconductor film, said catalyst material being for promoting crystallization of said semiconductor film; heating said non-single crystalline semiconductor film so that crystals grow horizontally from said selected portion toward a portion where said catalyst material is not disposed wherein amorphous areas are left between crystals in the semiconductor film; patterning said semiconductor film after the heating step into at least one semiconductor island; and irradiating said semiconductor island with a light in order to crystallize said amorphous areas remaining after the crystallizing step. - View Dependent Claims (32, 33, 34, 35, 36, 37, 38, 39)
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40. A method of manufacturing a semiconductor device comprising the steps of:
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forming a non-single crystalline semiconductor film on an insulating surface of a substrate; disposing a catalyst material in contact with a selected portion of said non-single crystalline semiconductor film, said catalyst material being for promoting crystallization of said semiconductor film; heating said non-single crystalline semiconductor film so that crystals grow horizontally from said selected portion toward a portion where said catalyst material is not disposed wherein amorphous areas are left between crystals in the semiconductor film; irradiating said semiconductor island with a light in order to crystallize said amorphous areas remaining after the crystallizing step, wherein said light has a wavelength of 4 μ
m to 0.5 μ
m. - View Dependent Claims (41, 42, 43, 44, 45, 46)
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47. A method of manufacturing a semiconductor device comprising the steps of:
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forming a non-single crystalline semiconductor film on an insulating surface of a substrate; disposing a catalyst material in contact with said non-single crystalline semiconductor film; crystallizing said non-single crystalline semiconductor film by heating wherein said catalyst material functions to promote the crystallization; irradiating said semiconductor island with a light having a wavelength of 4 μ
m to 0.5 μ
m in order to further increase the crystallinity of said semiconductor island,wherein said heating is carried out at a temperature of 400-650°
C. for at least four hours. - View Dependent Claims (48, 49)
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Specification