Leak detection device, and fluid vessel assembly comprising same

• US 6,079,252 A
• Filed: 05/20/1998
• Issued: 06/27/2000
• Est. Priority Date: 05/20/1998
• Status: Expired due to Term

• Current Assignee: Life Safety Germany GmbH (Honeywell International Inc.)
• Original Assignee: Advanced Technology Materials, Inc. (Entegris Incorporated)
• Inventors: Lurcott, Steven M., Tabler, Terry A.
• Primary Examiner(s): Williams, Hezron
• Assistant Examiner(s): WIGGINS, JOHN DAVID
• Application Number:
  US09/082,269
• Time in Patent Office: 769 Days
• Field of Search: 73/40, 73/24.01, 73/40.5 R, 73/49.2, 73/49.3, 73/52, 73/40.5 A, 73/24.04, 73/592, 73/31.05, 73/31.06, 340/605
• US Class Current: 73/40
• CPC Class Codes: G01F 23/2966 making use of acoustical resonance or standing waves
• CPC Class Codes: G01M 3/24 using infrasonic, sonic, or ultrasonic vibrations
• CPC Class Codes: G01N 2291/014 Resonance or resonant frequency
• CPC Class Codes: G01N 2291/0215 Mixtures of three or more gases, e.g. air
• CPC Class Codes: G01N 2291/0256 Adsorption, desorption, surface mass change, e.g. on biosensors
• CPC Class Codes: G01N 2291/02836 Flow rate, liquid level
• CPC Class Codes: G01N 2291/0423 Surface waves, e.g. Rayleigh waves, Love waves
• CPC Class Codes: G01N 2291/0426 Bulk waves, e.g. quartz crystal microbalance, torsional waves
• CPC Class Codes: G01N 29/022 Fluid sensors based on microsensors, e.g. quartz crystal-microbalance [QCM], surface acoustic wave [SAW] devices, tuning forks, cantilevers, flexural plate wave [FPW] devices microdevices per se B81B
• CPC Class Codes: G01N 29/036 by measuring frequency or resonance of acoustic waves

Abstract

A leak detection device securable in detection proximity to a fluid vessel. The leak detection device includes a sensor element and a monitoring assembly. The sensor element has a monitorable characteristic, and the monitorable characteristic changes upon contact, immerson or in exposure to the fluid contained in the vessel. The monotoring assembly is responsive to the monitorable characteristic and produces an changing electrical output in response to change in the monitorable characteristic. The vessel and leak detection device may form an assembly including a shroud or cover over the detection device and a leak-susceptible portion of the vessel, to provide a microenvironment in which the detection device is operated.

Claims

1. A leak monnotoring fluid storage and dispensing apparatus comprising:

(a) a portable vessel having contents which comprise a hazardous gas; and

(b) a leak detection device secured to the vessel and arranged to detect leakage of said hazardous gas therefrom, said leak detection device comprising;

(i) a sensor element having a monitorable characteristic that changes upon exposure to the hazardous gas; and

(ii) a self-contained monitoring unit operatively coupled to the sensor element and arranged to respond to a change in the monitorable characteristic of the sensor element, by producing an output indicating the change in the monitorable characteristic.

2. The leak monitoring fluid storage and dispensing apparatus according to claim 1, wherein the monitorable characteristic includes at least one property selected from the group consisting of resonant frequency, color, texture, chemical resistance, magnetic state, density, and chemical compositional state.

3. The leak monitoring fluid storage and dispensing apparatus according to claim 1, wherein the monitorable characteristic comprises resonant frequency.

4. The leak monitoring fluid storage and dispensing apparatus according to claim 1, wherein the sensor element comprises a piezoelectric material.

5. The leak monitoring fluid storage and dispensing apparatus according to claim 1, wherein the sensor element comprises a quartz microbalance.

6. The leak monitoring fluid storage and dispensing apparatus according to claim 1, wherein the sensor element comprises a surface acoustic wave device.

7. The leak monitoring fluid storage and dispensing apparatus according to claim 1, wherein the self-contained monitoring unit comprises an electrical power supply.

8. The leak monitoring fluid storage and dispensing apparatus according to claim 7, wherein the electrical power supply comprises a battery.

9. The leak monitoring fluid storage and dispensing apparatus according to claim 1, wherein the self-contained monitoring unit comprises a microprocessor and embedded controller assembly.

10. The leak monitoring fluid storage and dispensing apparatus according to claim 1, wherein the self-contained monitoring unit comprises a power supply and electronic circuitry constructed and arranged to operate in an intermittently active mode, and in a power-down mode between successive active mode events.

11. The leak monitoring fluid storage and dispensing apparatus according to claim 1, wherein the self-contained monitoring unit comprises an alarm producing said output indicating the change in the monitorable characteristic.

12. The leak monitoring fluid storage and dispensing apparatus according to claim 11, wherein said alarm comprises an audible alarm.

13. The leak monitoring fluid storage and dispensing apparatus according to claim 11, wherein said alarm comprises a visible alarm.

14. The leak monitoring fluid storage and dispensing apparatus according to claim 1, wherein the self-contained monitoring unit comprises a battery power supply providing at least four months operating time in service.

15. The leak monitoring fluid storage and dispensing apparatus according to claim 1, wherein the sensor element comprises a mass-sensitive piezoelectric device.

16. The leak monitoring fluid storage and dispensing apparatus according to claim 15, wherein the self-contained monitoring unit comprises an oscillator/mixer coupled in frequency response-geneting relationship to the piezoelectric device, said oscillator/mixer being coupled to a low-pass filter to produce an output frequency response signal, and a signal-processing microprocessor arranged in receiving relationship to the output frequency response signal, producing said output indicative of the change in the monitorable characteristic, wherein said monitorable characteristic comprises frequency response of the piezoelectric device.

17. The leak monitoring fluid storage and dispensing apparatus according to claim 16, wherein the piezoelectric device comprises a quartz microbalance.

18. The leak monitoring fluid storage and dispensing apparatus according to claim 16, wherein the piezoelectric device comprises a surface acoustic wave transducer.

19. The leak monitoring fluid storage and dispensing apparatus according to claim 1, wherein the said vessel comprises a high pressure gas cylinder.

20. The leak monitoring fluid storage and dispensing apparatus according to claim 1, wherein the contents of the portable vessel comprise a sorbent medium holding a gas for which the sorbent medium has sorptive affinity.

21. The leak monitoring fluid storage and dispensing apparatus according to claim 1, wherein the portable vessel is a high pressure gas cylinder comprising a manual valve hand wheel or pneumatic valve operator, and the leak detection device is secured to a neck portion of the cylinder, beneath the manual valve hand wheel or pneumatic valve operator.

22. The leak monitoring fluid storage and dispensing apparatus according to claim 1, wherein said self-contained monitoring unit comprises a DC battery.

23. The leak monitoring fluid storage and dispensing apparatus according to claim 1, wherein the self-contained monitoring unit comprises an AC power source.

24. The leak monitoring fluid storage and dispensing apparatus of claim 1 wherein the leak detection device is in proximity to a vessel locus including a structure selected from the group consisting of:

joints, seams, ports, inlets, outlets and mechanical interconnections.

26. The vessel assembly according to claim 24, wherein the monitorable characteristic includes at least one property selected from the group consisting of resonant frequency, color, texture, chemical resistance, magnetic state, density, and chemical compositional state.

27. The vessel assembly according to claim 24, wherein the monitorable characteristic comprises resonant frequency.

25. A vessel assembly, comprising:

(a) a vessel; and

(b) a leak detection device secured in detection proximity to the vessel, said leak detection device comprising;

(i) a sensor element having at least one monitorable characteristic that changes upon exposure to the content of the vessel, wherein said sensor element is selected from the group consisting of;

quartz crystal microbalance;

SAW resonator;

sorbent material absorber; and

piezoelectric crystal; and

(ii) a self-contained monitoring unit operatively coupled to the sensor element and arranged to respond to a change in the monitorable characteristic of the sensor element, by producing an output indicative of the change in the monitorable characteristic, the self-contained monitoring unit comprising a power supply and electronic circuitry constructed and arranged to operate in an intermittently active mode, and in a power-down mode between successive active mode events.

28. The vessel assembly according to claim 25, wherein the sensor element comprises a piezoelectric material.

29. The vessel assembly according to claim 25, wherein the sensor element comprises a quartz microbalance.

30. The vessel assembly according to claim 25, wherein the sensor element comprises a surface acoustic wave device.

31. The vessel assembly according to claim 25, wherein the self-contained monitoring unit comprises an electrical power supply.

32. The vessel assembly according to claim 31, wherein the electrical power supply comprises a battery.

33. The vessel assembly according to claim 25, wherein the self-contained monitoring unit comprises a microprocessor and embedded controller assembly.

34. The vessel assembly according to claim 25, wherein the self-contained monitoring unit comprises an alarm producing said output indicating the change in the monitorable characteristic.

35. The vessel assembly according to claim 34, wherein said alarm comprises an audible alarm.

36. The vessel assembly according to claim 34, wherein said alarm comprises a visible alarm.

37. The vessel assembly according to claim 25, wherein the self-contained monitoring unit comprises a battery power supply providing at least four months operating time in service.

38. The vessel assembly according to claim 25, wherein the sensor element comprises a mass-sensitive piezoelectric device.

39. The vessel assembly according to claim 38, wherein the self-contained monitoring unit comprises an oscillator/mixer coupled in frequency response-generating relationship to the piezoelectric device, said oscillator/mixer being coupled to a low-pass filter to produce an output frequency response signal, and a signal-processing microprocessor arranged in receiving relationship to the output frequency response signal, producing said output indicative of the change in the monitorable characteristic, wherein said monitorable characteristic comprises frequency response of the piezoelectric device.

40. The vessel assembly according to claim 25, wherein said vessel comprises a high pressure gas cylinder.

41. The vessel assembly according to claim 25, wherein the contents of said vessel comprise a sorbent medium holding a gas for which the sorbent medium has sorptive affinity.

42. The vessel assembly according to claim 25, wherein said self-contained monitoring unit comprises a DC battery.

43. The vessel assembly according to claim 25, wherein the self-contained monitoring unit comprises an AC power source.

44. The vessel assembly according to claim 25, containing a high pressure gas.

45. The vessel assembly according to claim 25, containing a high pressure liquid.

46. The vessel assembly according to claim 25, further comprising a shroud overlying a valve assembly of said vessel, said shroud defining therein an enclosed volume, with said leak detection device disposed in said interior volume.

47. The vessel assembly according to claim 38, wherein the vessel comprises a high pressure gas cylinder with a valve head assembly including a valve hand wheel or pneumatic valve operator, wherein the leak detection device is secured to the valve head and underlies said manual valve hand wheel or pneumatic valve operator.

48. The vessel assembly according to claim 47, wherein said leak detection device has a lateral extent which is generally not in excess of the lateral extent of the manual valve hand wheel or pneumatic valve operator.

49. The vessel assembly according t o claim 25, wherein the leak detection device is secured to the vessel.

50. The vessel assembly of claim 25 wherein the leak detection device is secured to the vessel.

74. The vessel assembly of claim 25 wherein the leak detection device is secured to the vessel.

75. The vessel assembly of claim 74 wherein the leak detection device is secured to the neck portion of the vessel.

51. A leak monitoring fluid storage and dispensing apparatus comprising:

(a) a portable vessel; and

(b) a leak detection device mounted to the vessel, said leak detection device comprising;

(i) a sensor element having at least one monitorable characteristic that changes upon exposure to the fluid content of the vessel, wherein said sensor element is selected from the group consisting of;

a quartz crystal microbalance;

a SAW resonator;

a piezoelectric crystal; and

a sorbent material absorber, and wherein said monitorable characteristic is selected from the group consisting of;

resonant frequency, color, texture, chemical resistance, magnetic state, density, and chemical composition; and

(ii) a self-contained monitoring unit operatively coupled to the sensor element and arranged to respond to a change in the monitorable characteristic of the sensor element, by producing an output indicating the change in the monitorable characteristic, the self-contained monitoring unit comprising a power supply and electronic circuitry constructed and arranged to operate in an intermittently active mode, and in a power-down mode between successive active mode events.

52. The leak monitoring fluid storage and dispensing apparatus of claim 51 wherein the leak detection device is secured to the vessel.

53. A leak detection device securable in detection proximity to a vessel, said leak detection device comprising:

(a) a sensor element comprising a mass-sensitive piezoelectric device having a monitorable characteristic that changes upon exposure to the content of the vessel; and

(b) a self-contained monitoring unit operatively coupled to the sensor element and arranged to respond to a change in the monitorable characteristic of the sensor element, by producing an output indicative of the change in the monitorable characteristic, said unit comprising an oscillator/mixer coupled in frequency response-generating relationship to the piezoelectric device, said oscillator/mixer being coupled to a low-pass filter to produce an output frequency response signal, and a signal-processing microprocessor arranged in receiving relationship to the output frequency response signal, producing said output indicative of the change in the monitorable characteristic, wherein said monitorable characteristic comprises frequency response of the piezoelectric device.

54. The leak detection device according to claim 53, wherein the piezoelectric device comprises a quartz microbalance.

55. The leak detection device according to claim 53, wherein the piezoelectric device comprises a surface acoustic wave transducer.

56. The leak detection device of claim 53 wherein the leak detection device is securable to the vessel.

57. A leak detection device constructed and arranged for securement to a neck portion of a gas cylinder, beneath a manual valve hand wheel or pneumatic valve operator of a high pressure gas cylinder, said leak detection device comprising:

(a) a sensor clement having a monitorable characteristic that changes upon exposure to the content of the vessel; and

(b) a self-contained monitoring unit operatively coupled to the sensor element and arranged to respond to a change in the monitorable characteristic of the sensor element, by producing an output indicative of the change in the monitorable characteristic.

58. A vessel assembly, comprising:

(a) a vessel; and

(b) a leak detection device secured in detection proximity to the vessel, said leak detection device comprising;

(i) a sensor element comprising a mass-sensitive piezoelectric device having a monitorable characteristic that changes upon exposure to the content of the vessel; and

(ii) a self-contained monitoring unit operatively coupled to the sensor element and arranged to respond to a change in the monitorable characteristic of the sensor element, by producing an output indicative of the change in the monitorable characteristic, the self-contained monitoring unit comprising a power supply and electronic circuitry constructed and arranged to operate in an intermittently active mode, and in a power-down mode between successive active mode events.

59. The vessel assembly according to claim 58, wherein the piezoelectric device comprises a quartz microbalance.

60. The vessel assembly according to claim 58, wherein the piezoelectric device comprises a surface acoustic wave transducer.

61. The vessel assembly of claim 58 wherein the leak detection device is secured to the vessel.

62. A vessel assembly, comprising:

(a) a vessel; and

(b) a leak detection device secured in detection proximity to the vessel, said leak detection device comprising;

(i) a sensor element comprising a mass-sensitive piezoelectric device having a frequency response that changes upon exposure to the content of the vessel;

(ii) a self-contained monitoring unit operatively coupled to the sensor element and arranged to respond to a change in the frequency response of the mass-sensitive piezoelectric device, by producing an output indicative of the change in the frequency response of the mass-sensitive piezoelectric device;

(iii) an oscillator/mixer coupled in frequency response-generating relationship to tile piezoelectric device, said oscillator/mixer being coupled to a low-pass filter to produce an output frequency response signal; and

(iv) a signal-processing microprocessor arranged in receiving relationship to the output frequency response signal, producing said output indicative of the change in the frequency response of the mass-sensitive piezoelectric device.

63. The vessel assembly of claim 62 wherein the leak detection device is secured to the vessel.

64. A vessel assembly, comprising:

(a) a high pressure gas cylinder; and

(b) a leak detection device secured to a neck portion of the cylinder, beneath a manual valve hand wheel or pneumatic valve operator, said leak detection device comprising;

(i) a sensor element having a monitorable characteristic that changes upon exposure to the content of the vessel; and

(ii) a self-contained monitoring unit operatively coupled to the sensor element and arranged to respond to a change in the monitorable characteristic of the sensor element, by producing an output indicative of the change in the monitorable characteristic.

65. A vessel assembly, comprising:

(a) a vessel;

(b) a leak detection device secured in detection proximity to the vessel, said leak detection device comprising;

(i) a sensor element having a monitorable characteristic that changes upon exposure to the content of the vessel; and

(ii) a self-contained monitoring unit operatively coupled to the sensor element and arranged to respond to a change in the monitorable characteristic of the sensor element, by producing an output indicative of the change in the monitorable characteristic; and

(c) a shroud overlying a valve assembly of the vessel, said shroud defining therein an enclosed volume, with said leak detection device disposed in said interior volume.

66. The vessel assembly of claim 65 wherein the leak detection device is secured to the vessel.

67. A vessel assembly, comprising:

(a) a high pressure gas cylinder and a valve head assembly including a valve hand wheel or pneumatic valve operator; and

(b) a self-contained leak detection device secured is secured to the valve head and underlying said manual valve hand wheel or pneumatic valve operator, said leak detection device comprising;

(i) a sensor element having a monitorable characteristic that changes upon exposure to the content of the vessel; and

(ii) a monitoring unit operatively coupled to the sensor element and arranged to respond to a change in the monitorable characteristic of the sensor element, by producing an output indicative of the change in the monitorable characteristic.

68. The vessel assembly according to claim 67, wherein the leak detection device has a lateral extent which is generally not in excess of the lateral extent of the manual valve hand wheel or pneumatic valve operator.

69. A leak monitoring fluid storage and dispensing apparatus comprising:

(a) a fluid-containing vessel gas cylinder with a valve head assembly including a valve hand wheel or pneumatic valve operator; and

(b) a leak detection device secured to the valve head in detection proximity to a mechanical interconnection of the vessel, and underlying the manual valve hand wheel or pneumatic valve operator, said leak detection device comprising;

(i) a sensor element having a monitorable characteristic that changes upon exposure to the fluid content of the vessel; and

(ii) a self-contained monitoring unit operatively coupled to the sensor element and arranged to respond to a change in the monitorable characteristic of the sensor element, by producing an output indicating the change in the monitorable characteristic.

70. The leak monitoring fluid storage and dispensing apparatus of claim 69 wherein the leak detection device is secured to the vessel.

71. A leak detection device securable in detection proximity to a vessel, said leak detection device comprising:

(a) a sensor element comprises a mass-sensitive piezoelectric device having frequency response that changes upon exposure to the content of the vessel; and

(b) a self-contained monitoring unit;

(i) operatively coupled to the sensor element and arranged to respond to a change in the frequency response of the mass-sensitive piezoelectric device, by producing an output indicative of the change in frequency response of the mass-sensitive piezoelectric device;

(ii) comprising an oscillator/mixer coupled in frequency response-generating relationship to the piezoelectric device and coupled to a low-pass filter to produce an output frequency response signal; and

(iii) comprising a signal-processing microprocessor arranged to receive the output frequency response signal and to produce the output indicative of the change in the frequency response of the mass-sensitive piezoelectric device.

72. The leak detection device of claim 71 wherein the leak detection device is securable to the vessel.

73. A vessel assembly, comprising:

(a) a high pressure gas cylinder; and

(b) a leak detection device secured in detection proximity to a neck portion of the cylinder, beneath a manual valve hand wheel or pneumatic valve operator, said leak detection device comprising;

(i) a sensor element having a monitorable characteristic that chances upon exposure to the content of the vessel; and

(ii) a self-contained monitoring unit operatively coupled to the sensor element and arranged to respond to a change in the monitorable characteristic of the sensor element, by producing an output indicative of the change in the monitorable characteristic.