Hardcoats for flat panel display substrates

• US 6,083,313 A
• Filed: 07/27/1999
• Issued: 07/04/2000
• Est. Priority Date: 07/27/1999
• Status: Expired due to Term

• Current Assignee: Sulzer Metaplas GmbH
• Original Assignee: Advanced Refractory Technologies, Inc.
• Inventors: Brodbeck, Cyndi, Venkatraman, Chandra
• Primary Examiner(s): BRUNSMAN, DAVID M
• Application Number:
  US09/361,006
• Time in Patent Office: 343 Days
• Field of Search: 106/287.14, 428/412, 428/446, 428/447
• US Class Current: 106/287.14
• CPC Class Codes: C08J 2483/00 Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
• CPC Class Codes: C08J 7/0427 with only one layer of a composition containing a polymer binder with more layers C08J7/042
• CPC Class Codes: C08J 7/043 Improving the adhesiveness of the coatings per se, e.g. forming primers adhesives in the form of films or foils characterised by the primer layers between the polymer carriers and the adhesives C09J7/50
• CPC Class Codes: C08J 7/046 Forming abrasion-resistant coatings; Forming surface-hardening coatings
• CPC Class Codes: C08J 7/048 Forming gas barrier coatings
• CPC Class Codes: Y10T 428/31507 Of polycarbonate
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane

Abstract

The present invention relates to a unique hard coating that provides the necessary characteristics for flat panel display plastic substrates because the coating is amorphous and is comprised of C, H, Si and O. The coating of the present invention is hard, optically transparent, scratch and abrasion resistant and hydrophobic. It is deposited by a low density, low temperature plasma enhanced chemical vapor deposition (PECVD) process and exhibits excellent barrier protection and reduced permeability to moisture, oxygen, helium and other vapors.

Claims

1. An abrasive resistant, transparent barrier coating for plastic substrates comprised of carbon, hydrogen, silicon and oxygen in an amorphous structure wherein said coating is deposited at a temperature of or below about 70°

C. and at a pressure in the range of from about 50 mTorr to about 500 mTorr and further said coating having the properties of Nanoindentation hardness in the range of about 2 to about 10 GPa.

2. The coating of claim 1 comprised of a glass-like Si--O network.

3. The coating of claim 1 comprised of a multi component structure comprising Si--O, C--H, Si--H and Si--C.

4. The coating of claim 3 wherein Si--O and C--H are predominant.

5. The coating of claim 1 wherein the carbon content is greater than about 25 atomic percent of the coating.

6. The coating of claim 1 wherein the carbon content is from about 25 atomic percent of the coating to about 65 atomic percent of the coating, the hydrogen content is at least about 1 atomic percent of the coating up to about 40 atomic percent of the coating, the silicon content is from about 10 atomic percent of the coating to about 30 atomic percent of the coating and the oxygen content ranges from about 8 atomic percent of the coating to about 40 atomic percent of the coating.

7. The coating of claim 1 wherein the density of the coating varies from about 1.7 gm/cc to about 2.0 gm/cc.

8. The coating of claim 1 wherein said coating is synthesized via a RF discharge plasma process.

9. The coating of claim 1 wherein said coating is deposited by a low density, low temperature plasma enhanced chemical vapor deposition process.

10. The coating of claim 1 wherein the coating has the properties of Nanoindentation hardness in the range of about 5 to about 7.5 GPa.

11. The coating of claim 1 wherein the coating has a UV transmission greater than 85% in the wavelength range of frog about 360 to about 900 nm.

12. The coating of claim 1 wherein the coating has a UV transmission greater than 90% in the wavelength range of frown about 400 to about 900 nm.

13. The coating of claim 1 wherein the coating has a surface energy of from about 27 to about 38 dyn/cm.

14. The coating of claim 1 wherein the coating has a water contact angle of from about 70 to about 90.

15. The coating of claim 1 wherein the coating has a film thickness from about 50 angstroms to about 10 micrometers.

16. The coating of claim 1 herein the coating is hydrophobic.

17. The coating of claim 1 wherein the coating is impermeable.