Burn rate-enhanced high gas yield non-azide gas generants

• US 6,083,331 A
• Filed: 09/08/1999
• Issued: 07/04/2000
• Est. Priority Date: 12/28/1998
• Status: Expired due to Term

• Current Assignee: Autoliv ASP Incorporated (Autoliv Incorporated)
• Original Assignee: Autoliv ASP Incorporated (Autoliv Incorporated)
• Inventors: Taylor, Robert D., Mendenhall, Ivan V.
• Primary Examiner(s): Jordan, Charles T.
• Assistant Examiner(s): FELTON, AILEEN BAKER
• Application Number:
  US09/391,163
• Time in Patent Office: 300 Days
• Field of Search: 149/46, 149/109.6, 556/110, 556/118, 423/351, 423/387, 423/395, 423/397
• US Class Current: 149/109.6
• CPC Class Codes: C06B 23/007 Ballistic modifiers, burning rate catalysts, burning rate depressing agents, e.g. for gas generating
• CPC Class Codes: C06B 31/28 the salt being ammonium nitrate
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

Gas generant compositions and methods of processing are provided which produce or result in a relatively high burning rate and low burning rate pressure exponent, while also desirably providing a high gas output, as compared to normal or typical gas generant formulations such as used in association with vehicle occupant restraint airbag cushions.

Claims

1. In a method of forming a burn rate-enhanced high gas yield non-azide gas generant which includes a gas generating fuel and between about 15 and about 55 wt % of a metal amine nitrate oxidizer wherein the metal of the metal amine nitrate is selected from the group of copper and zinc, the steps of:

adding ammonium nitrate and a material containing the metal of the metal amine nitrate with a first gas generant precursor material to form a second gas generant precursor material and

heating the second gas generant precursor material to form a gas generant material containing between about 15 and about 55 wt % of;

copper diamine dinitrate, where the metal is copper and

zinc diamine dinitrate, where the metal is zinc.

2. The method of claim 1 additionally comprising the step of spray drying the second gas generant precursor material prior to said heating step.

3. The method of claim 1 wherein the metal amine nitrate oxidizer is copper diamine dinitrate.

4. The method of claim 1 wherein the metal amine nitrate oxidizer is zinc diamine dinitrate.

5. The method of claim 1 wherein said heating step comprises heating the second gas generant precursor material to a temperature of at least about 160°

C.

6. The method of claim 1 wherein the metal of the metal amine nitrate is copper and the material added with the ammonium nitrate is selected from the group consisting of Cu metal, Cu₂ O, CuO and Cu(OH)₂.

7. The method of claim 6 wherein Cu₂ O is the material added with the ammonium nitrate.

8. The method of claim 1 wherein the first gas generant precursor material comprises a gas generating fuel comprising guanidine nitrate.

9. The method of claim 8 wherein the first gas generant precursor material comprises dicyandiamide with the guanidine nitrate gas generating fuel additionally being formed upon said heating step.

10. The method of claim 1 wherein the first gas generant precursor material comprises a non-azide gas generating fuel.

11. The method of claim 10 wherein the first gas generant precursor material comprises a nitrogen-containing organic fuel.

12. The method of claim 11 wherein the nitrogen-containing organic fuel is selected from the group consisting of aminoguanidine nitrate, triaminoguanidine nitrate, nitroguanidine, dicyandiamide, triazalone, nitrotriazalone, tetrazoles and mixtures thereof.

13. The method of claim 10 wherein the first gas generant precursor material comprises dicyandiamide.

14. The method of claim 10 wherein the first gas generant precursor material comprises a tetrazole complex of at least one transition metal.

15. The method of claim 10 wherein the first gas generant precursor material comprises a tetrazole complex of at least one transition metal selected from the group consisting of copper, cobalt, and zinc.

16. The method of claim 10 wherein the first gas generant precursor material comprises a metallic fuel material.

17. The method of claim 16 wherein the metallic fuel material is selected from the group consisting of silicon, aluminum, boron, magnesium, alloys of aluminum and magnesium and combinations thereof.

18. A method of forming a burn rate-enhanced high gas yield non-azide gas generant which includes a non-azide gas generating fuel and a metal amine nitrate oxidizer wherein the metal of the metal amine nitrate oxidizer is selected from the group of copper and zinc, the method comprising:

adding ammonium nitrate and a material containing the metal of the metal amine nitrate oxidizer with a first gas generant precursor material containing a non-azide gas generating fuel to form a second gas generant precursor material and

heating the second gas generant precursor material to form a gas generant material containing copper diamine dinitrate, where the metal of the metal amine nitrate oxidizer is copper and zinc diamine dinitrate, where the metal of the metal amine nitrate oxidizer is zinc.

19. The method of claim 18 wherein prior to said heating, said method additionally comprises spray drying a water slurry containing the second gas generant precursor material.

20. The method of claim 18 wherein the burn rate-enhanced high gas yield non-azide gas generant contains no more than about 55 wt % of the metal amine nitrate oxidizer.