Low particulate igniter composition for a gas generant

• US 6,086,693 A
• Filed: 02/02/1999
• Issued: 07/11/2000
• Est. Priority Date: 02/02/1999
• Status: Expired due to Fees

• Current Assignee: Autoliv ASP Incorporated (Autoliv Incorporated), Orbital ATK Inc.
• Original Assignee: Autoliv ASP Incorporated (Autoliv Incorporated), Cordant Technologies, Inc. (Howmet Aerospace, Inc.)
• Inventors: Doll, Daniel W., Lund, Gary K., Taylor, Robert D., Mendenhall, Ivan V., Blau, Reed J.
• Primary Examiner(s): Jordan, Charles T.
• Assistant Examiner(s): Baker, Aileen J.
• Application Number:
  US09/243,557
• Time in Patent Office: 525 Days
• Field of Search: 149/22, 149/61, 149/62, 149/63, 149/66, 149/108.6, 149/109.6, 149/43
• US Class Current: 149/43
• CPC Class Codes: C06B 33/04 the material being an inorganic nitrogen-oxygen salt
• CPC Class Codes: C06C 9/00 Chemical contact igniters; Chemical lighters

Abstract

Igniter compositions and methods of processing are provided which produce or result in relatively little particulate material, as compared to typical igniter compositions used in association with vehicle occupant restraint airbag cushions.

Claims

1. An igniter composition comprising:

about 50 to about 75 composition weight percent of an oxidizer comprising strontium nitrate;

about 0.5 to about 35 composition weight percent of an Al/Mg alloy fuel component, said Al/Mg alloy fuel component having an Al content of about 50 to about 80 percent and a Mg content of about 50 to about 20 percent; and

about 1 to about 20 composition weight percent of a gas-producing fuel component.

2. The igniter composition of claim 1 wherein said oxidizer additionally comprises an alkali metal nitrate.

3. The igniter composition of claim 2 wherein no more than about 50 percent of said oxidizer is an alkali metal nitrate.

4. The igniter composition of claim 2 wherein the alkali metal nitrate is potassium nitrate.

5. The igniter composition of claim 1 wherein said Al/Mg alloy fuel component has an Al content of about 70 percent and a Mg content of about 30 percent.

6. The igniter composition of claim 1 wherein said gas-producing fuel component is selected from the group consisting of organic polymer binders, high energy nitro compounds, nitrate ester, guanidine nitrate, nitroamine compounds and mixtures thereof.

7. The igniter composition of claim 1 wherein said gas-producing fuel component is a water-soluble organic polymer binder.

8. The igniter composition of claim 7 wherein the water-soluble organic polymer binder is selected from the group consisting of polyacrylamide, polyacrylic acid and combinations thereof.

9. The igniter composition of claim 1 wherein no more than about 50 mass percent of the condensible combustion products melt at a temperature of less than about 2750 K.

10. The igniter composition of claim 9 additionally comprising up to about 10 composition weight percent of boron.

11. The igniter composition of claim 9 wherein no more than about 25 mass percent of the condensible combustion products melt at a temperature of less than about 2750 K.

12. The igniter composition of claim 11 additionally comprising up to about 10 composition weight percent of a metallic co-fuel selected from the group consisting of Zr, Ti, TiH₂, Si, ZrH₂ and mixtures thereof.

13. The igniter composition of claim 1 wherein said Al/Mg alloy fuel component has an Al content of about 70 to about 80 percent and a Mg content of about 30 to 20 percent, said igniter composition additionally comprising up to about 10 percent of boron, a metallic co-fuel selected from the group consisting of Zr, Ti, TiH₂, Si, ZrH₂ and mixtures thereof.

14. The igniter composition of claim 1 having a combustion flame temperature of at least about 2750 K.

15. A gas generating device containing the igniter composition of claim 1 in ignition communication with a gas generant material.

16. An inflatable vehicle occupant safety restraint system EA comprising:

the gas generating device of claim 15 connected in association with an inflatable airbag cushion for inflating the airbag cushion.

17. A reduced particulate igniter composition for a gas generant material, said igniter composition comprising:

about 50 to about 75 composition weight percent of an oxidizer comprising strontium nitrate and potassium nitrate, wherein no more than about 50 mass percent of the oxidizer is potassium nitrate;

about 0.5 to about 35 composition weight percent of an Al/Mg alloy fuel component having an Al content of about 50 to about 80 percent and a Mg content of about 50 to 20 percent; and

about 1 to about 20 composition weight percent of a gas-producing water-soluble organic polymer binder fuel component,

said igniter composition having a combustion flame temperature of at least about 2750 K and, upon combustion, said igniter composition produces combustion products including condensible combustion products and wherein no more than about 50 mass percent of the condensible combustion products melt at a temperature of less than about 2750 K.

18. The igniter composition of claim 17 wherein no more than about 25 mass percent of the condensible combustion products melt at a temperature of less than about 2750 K.

19. The igniter composition of claim 17 additionally comprising up to about 10 composition weight percent of a metallic co-fuel selected from the group consisting of Zr, Ti, TiH₂, Si, ZrH₂ and mixtures thereof.

20. A method of processing an igniter composition for a gas generant material, said method comprising the steps of:

admixing about 10 to about 20 weight percent water to an igniter composition precursor mix containing, on a water free basis, about 50 to about 75 percent of an oxidizer comprising strontium nitrate, about 0.5 to about 35 percent of an Al/Mg alloy fuel component and about 1 to about 20 percent of a gas-producing fuel component comprising a water-soluble organic polymer binder to form a moisture-containing igniter precursor mass; and

sizing and drying the moisture-containing igniter precursor mass to form a granular igniter material of selected particle size.

21. The method of claim 20 wherein the water-soluble organic polymer binder is selected from the group consisting of polyacrylamide, polyacrylic acid and combinations thereof.