Coated fiber strands, composites and cables including the same and related methods

• US 6,087,000 A
• Filed: 12/18/1997
• Issued: 07/11/2000
• Est. Priority Date: 12/18/1997
• Status: Expired due to Fees

• Current Assignee: PPG Industries Incorporated (Nouryon BV)
• Original Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Inventors: Schell, Philip L., Girgis, Mikhail M.
• Primary Examiner(s): Krynski, William
• Assistant Examiner(s): GRAY, JILL M
• Application Number:
  US08/993,026
• Time in Patent Office: 936 Days
• Field of Search: 428/372, 428/375, 428/373, 428/378, 428/392, 428/394
• US Class Current: 428/392
• CPC Class Codes: C03C 25/1065 Multiple coatings
• CPC Class Codes: G02B 6/4432 with fibre reinforcements
• CPC Class Codes: G02B 6/4486 Protective covering
• CPC Class Codes: Y10T 428/2927 including structurally defined particulate matter
• CPC Class Codes: Y10T 428/2929 Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
• CPC Class Codes: Y10T 428/2933 Coated or with bond, impregnation or core
• CPC Class Codes: Y10T 428/2938 Coating on discrete and individual rods, strands or filaments
• CPC Class Codes: Y10T 428/2964 Artificial fiber or filament
• CPC Class Codes: Y10T 428/2967 Synthetic resin or polymer

Abstract

The present invention provides fiber strands having on at least a portion of surfaces thereof (a) a primary layer of a coating composition including a hydrophobic fluorine-containing polymer, the primary coated strands being useful for reinforcing thermoplastic composites, and (b) a secondary layer including a hydrophilic material applied over at least a portion of the primary layer, the secondarily coated strands being useful for inhibiting water wicking in a telecommunications cable assembly.

Claims

1. A strand comprising a plurality of fibers having on at least a portion of surfaces thereof:

(a) a primary layer of a coating composition comprising a hydrophobic fluorine-containing polymer; and

(b) a secondary layer comprising a hydrophilic material applied over at least a portion of the primary layer.

2. The strand according to claim 1, wherein the fibers are formed from fibrous materials selected from the group consisting of inorganic materials, thermoplastic materials, natural materials and combinations thereof.

3. The strand according to claim 2, wherein the fibers are formed from an inorganic material which is glass.

4. The fiber strand according to claim 1, wherein the fluorine-containing polymer is present as a solid.

5. The fiber strand according to claim 1, wherein the fluorine-containing polymer is a polymerization reaction product of a fluoroalkyl acrylate monomer component, vinylidene chloride and an alkyl acrylate monomer component.

6. The fiber strand according to claim 5, wherein the fluoroalkyl acrylate monomer component is a perfluoroalkylethylacrylate monomer.

7. The fiber strand according to claim 5, wherein the fluoroalkyl acrylate monomer component is a mixture of perfluoroalkylethylacrylate monomers.

8. The fiber strand according to claim 5, wherein the alkyl acrylate monomer component is a mixture of alkyl acrylate monomers.

9. The fiber strand according to claim 1, wherein the hydrophilic material is selected from the group consisting of cellulosics, starch-graft copolymers, synthetic superabsorbent materials and mixtures thereof.

10. The fiber strand according to claim 9, wherein the hydrophilic material is a synthetic superabsorbent material which comprises a copolymer of sodium polyacrylate and polyalcohol.

11. A glass fiber strand having on at least a portion of surfaces thereof:

(a) a primary layer of a coating composition comprising a hydrophobic fluorine-containing polymer; and

(b) a secondary layer comprising a hydrophilic material applied over at least a portion of the primary layer.

12. A strand comprising a plurality of fibers having on at least a portion of surfaces thereof:

(a) a primary layer of a coating composition comprising a hydrophobic polymerization reaction product of a fluoroalkyl acrylate monomer component, vinylidene chloride and an alkyl acrylate monomer component; and

(b) a secondary layer comprising a hydrophilic material applied over at least a portion of the primary layer.

13. The strand according to claim 12, wherein the fibers are formed from fibrous materials selected from the group consisting of inorganic materials, thermoplastic materials, natural materials and combinations thereof.

14. The strand according to claim 13, wherein the fibers are formed from an inorganic material which is glass.

15. The fiber strand according to claim 12, wherein the fluorine-containing polymer is present as a solid.

16. The fiber strand according to claim 12, wherein the fluoroalkyl acrylate monomer component is a perfluoroalkylethylacrylate monomer.

17. The fiber strand according to claim 12, wherein the fluoroalkyl acrylate monomer component is a mixture of perfluoroalkylethylacrylate monomers.

18. The fiber strand according to claim 12, wherein the alkyl acrylate monomer component is a mixture of alkyl acrylate monomers.

19. The fiber strand according to claim 12, wherein the hydrophilic material is selected from the group consisting of cellulosics, starch-graft copolymers, synthetic superabsorbent materials and mixtures thereof.

20. The fiber strand according to claim 19, wherein the hydrophilic material is a synthetic superabsorbent material which comprises a copolymer of sodium polyacrylate and polyalcohol.

21. A glass fiber strand having on at least a portion of surfaces thereof:

(a) a primary layer of a coating composition comprising a hydrophobic polymerization reaction product of a fluoroalkyl acrylate monomer component, vinylidene chloride and an alkyl acrylate monomer component; and

(b) a secondary layer comprising a hydrophilic material applied over at least a portion of the primary layer.