Thermal management system and method for a solid-state energy storing device

• US 6,087,036 A
• Filed: 07/25/1997
• Issued: 07/11/2000
• Est. Priority Date: 07/25/1997
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company), Avestor (Bolloré SE), Bathium Canada Inc. (Bolloré SE)
• Original Assignee: 3M Innovative Properties Company (3M Company), HYDRO-Quebec Corporation
• Inventors: Noel, Joseph-Robert-Gaetan, Gauthier, Michel, Domroese, Michael K., Ranger, Michel, Sudano, Anthony, Hoffman, Joseph A., Trice, Jennifer L., Rouillard, Roger, Radewald, Vern E., Lindeman, David D., St-Germain, Philippe, Turgeon, Thomas A., Rouillard, Jean, Shiota, Toshimi
• Primary Examiner(s): KALAFUT, STEPHEN J
• Application Number:
  US08/900,566
• Time in Patent Office: 1,082 Days
• Field of Search: 429/62, 429/66, 429/120
• US Class Current: 429/66
• CPC Class Codes: H01M 10/0413 Large-sized flat cells or batteries for motive or stationary systems with plate-like electrodes
• CPC Class Codes: H01M 10/0468 Compression means for stacks of electrodes and separators
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/058 Construction or manufacture
• CPC Class Codes: H01M 10/613 Cooling or keeping cold
• CPC Class Codes: H01M 10/647 Prismatic or flat cells, e.g. pouch cells
• CPC Class Codes: H01M 10/6555 arranged between the cells
• CPC Class Codes: H01M 10/6556 Solid parts with flow channel passages or pipes for heat exchange closed pipes H01M10/6552
• CPC Class Codes: H01M 10/6567 Liquids
• CPC Class Codes: H01M 2200/103 Fuse
• CPC Class Codes: H01M 50/51 Connection only in series
• CPC Class Codes: H01M 50/512 Connection only in parallel
• CPC Class Codes: H01M 50/516 by welding, soldering or brazing
• CPC Class Codes: H01M 50/519 comprising printed circuit boards [PCB]
• CPC Class Codes: H01M 6/181 with polymeric electrolytes
• CPC Class Codes: H01M 6/5016 Multimode utilisation
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

An improved electrochemical energy storing device includes a number of thin-film electrochemical cells which are maintained in a state of compression through use of an internal or an external pressure apparatus. A thermal conductor, which is connected to at least one of the positive or negative contacts of each electrochemical cell, conducts current into and out of the electrochemical cells and also conducts thermal energy between the electrochemical cells and thermally conductive material disposed on a wall structure adjacent the conductors. The wall structure includes electrically resistive material, such as an anodized coating or a thin film of plastic. The thermal conductors are fabricated to include a spring mechanism which expands and contacts to maintain mechanical contact between the electrochemical cells and the thermally conductive material in the presence of relative movement between the electrochemical cells and the wall structure. An active cooling apparatus may be employed external to a hermetically sealed housing containing the electrochemical cells to enhance the transfer of thermal energy into and out of the electrochemical cells. An integrated interconnect board may be disposed within the housing onto which a number of electrical and electro-mechanical components are mounted. Heat generated by the components is conducted from the interconnect board to the housing using the thermal conductors.

Claims

1. An electrochemical energy storing device, comprising:

a plurality of thin-film electrochemical cells maintained in a state of compression;

a plurality of thermal conductors, each of the plurality of thermal conductors defining a positive or negative contact for one of the plurality of electrochemical cells, the thermal conductors conducting current into and out of the cells and conducting thermal energy between the cells and a first electrically resistive surface of a thermally conductive structure disposed adjacent the thermal conductors; and

a cooling apparatus in thermal contact with a second surface of the thermally conductive structure, a heat transfer medium provided within the cooling apparatus to enhance thermal energy conduction between the cells and the thermally conductive structure.

2. The electrochemical energy storing device of claim 1, wherein a pressure apparatus external to the electrochemical cells maintains the electrochemical cells in the state of compression.

3. The electrochemical energy storing device of claim 1, wherein a pressure apparatus internal to at least some of the plurality of electrochemical cells maintains the plurality of electrochemical cells in the state of compression.

4. The electrochemical energy storing device of claim 1, wherein each of the electrochemical cells comprise one of a foam element, a microstructured elastomeric element, or a metal spring element to maintain the electrochemical cells in the state of compression.

5. The electrochemical energy storing device of claim 1, wherein each of the thermal conductors comprises an integral spring.

6. The electrochemical energy storing device of claim 1, wherein each of the thermal conductors comprises a spring mechanism having one of a substantially C-shaped, double C-shaped, Z-shaped, V-shaped, L-shaped, finger-shaped or O-shaped cross-section.

7. The electrochemical energy storing device of claim 1, wherein the cooling apparatus comprises a plate heat exchanger defining a gap through which the heat transfer medium passes.

8. The electrochemical energy storing device of claim 7, wherein the heat exchanger is brazed to the second surface of the thermally conductive structure.

9. The electrochemical energy storing device of claim 1, further comprising a plurality of short-circuit protection devices, each of the plurality of short-circuit protection devices being coupled in series to one of the plurality of electrochemical cells, a particular short-circuit protection device of the plurality of short-circuit protection devices coupled to a particular cell of the plurality of electrochemical cells being activated by a current spike capacitively produced upon occurrence of a short in the particular cell, the particular cell being electrically isolated from other ones of the plurality of electrochemical cells upon activation of the particular short-circuit device.

10. The electrochemical energy storing device of claim 9, wherein the short-circuit protection devices, the electrochemical cells, and the thermal conductors are disposed in a hermetically sealed enclosure of the energy storing device.

11. The electrochemical energy storing device of claim 1, wherein:

the plurality of electrochemical cells are arranged such that a planar surface of a particular cell of the plurality of cells is in thermal contact with a planar surface of a cell disposed adjacent the particular cell; and

the planar surfaces of the particular cell and the adjacent cell each have a ratio of energy content-to-contact surface area such that thermal energy produced by a short-circuit condition arising in the particular cell is conducted to the adjacent cell so as to prevent a temperature of the particular cell from exceeding a breakdown temperature.

12. The electrochemical energy storing device of claim 1, wherein each of the thermal conductors is spot welded to a metalization layer provided along an edge of a respective electrochemical cell, the metalization layer defining the positive or negative contact of the respective cell and the current being conducted laterally along the metalization layer.

13. The electrochemical energy storing device of claim 1, wherein the electrochemical cells are arranged in a stacked configuration and selectively interconnected in a series or parallel relationship.

14. The electrochemical energy storing device of claim 1, further comprising an interconnect board including an electrically conductive surface comprising a connection pattern that provides selective connectivity with the electrochemical cells.

15. The electrochemical energy storing device of claim 14, wherein the interconnect board, the electrochemical cells, and the thermal conductors are disposed in a hermetically sealed enclosure of the energy storing device.

16. The electrochemical energy storing device of claim 1, wherein the first electrically resistive surface comprises an electrically insulating surface.

17. The electrochemical energy storing device of claim 1, wherein the electrically resistive surface comprises an anodized metallic material.

18. An electrochemical energy storing device, comprising:

an enclosure including a thermally conductive first wall and a second wall;

an electrically resistive material disposed on or adjacent to the first wall;

a plurality of thin-film electrochemical cells maintained in a state of compression and disposed between the first and second walls;

a plurality of thermal conductors, each of the plurality of thermal conductors attached to one of the plurality of electrochemical cells, the thermal conductors defining a current flux path for conducting current to and from the electrochemical cells, and defining a thermal flux path for conducting thermal energy between the electrochemical cells and the first wall of the enclosure;

a cover of the enclosure defining first and second holes through which positive and negative conduits respectively pass; and

a hermetic seal respectively disposed between the positive and negative conduits and respective perimeters of the first and second holes in the cover.

19. The electrochemical energy storing device of claim 18, wherein the thermal conductors maintain substantially continuous mechanical engagement with the first wall of the enclosure in response to relative movement between the electrochemical cells and the first wall.

20. The electrochemical energy storing device of claim 18, wherein the thermal conductors expand and contract to accommodate variations in a separation distance between the electrochemical cells and the first wall.

21. The electrochemical energy storing device of claim 18, wherein the thermal conductors each comprises a spring mechanism having one of a substantially C-shaped, double C-shaped, Z-shaped, V-shaped, L-shaped, finger-shaped or O-shaped cross-section.

22. The electrochemical energy storing device of claim 18, further comprising one of an internal pressure apparatus or an external pressure apparatus, with respect to the electrochemical cells, that maintains the electrochemical cells in the state of compression.

23. The electrochemical energy storing device of claim 18, wherein at least some of the plurality of electrochemical cells comprise one of a foam element or a metal spring element to maintain the plurality of electrochemical cells in the state of compression.

24. The electrochemical energy storing device of claim 18, further comprising a resilient band encompassing the electrochemical cells, the resilient band including one of a wave spring or elastic material for maintaining the electrochemical cells in the state of compression.

25. The electrochemical energy storing device of claim 18, further comprising a plurality of short-circuit protection devices, each of the plurality of short-circuit protection devices being coupled in series to one of the plurality of electrochemical cells, a particular short-circuit protection device of the plurality of short-circuit protection devices coupled to a particular cell of the plurality of electrochemical cells being activated by a current spike capacitively produced upon development of a short in the particular cell, the particular cell being electrically isolated from other ones of the plurality of electrochemical cells upon activation of the particular short-circuit device.

26. The electrochemical energy storing device of claim 25, wherein the short-circuit protection devices, the electrochemical cells, and the thermal conductors are disposed in the enclosure which forms a heretic seal with the cover.

27. The electrochemical energy storing device of claim 18, wherein:

the plurality of electrochemical cells are arranged such that a planar surface of a particular cell of the plurality of cells is in thermal contact with a planar surface of a cell disposed adjacent the particular cell; and

the planar surfaces of the particular cell and the adjacent cell each have a ratio of energy content-to-contact surface area such that thermal energy produced by a short-circuit condition arising in the particular cell is conducted to the adjacent cell so as to prevent a temperature of the particular cell from exceeding a breakdown temperature.

28. The electrochemical energy storing device of claim 18, further comprising a cooling apparatus in thermal contact with the first wall of the enclosure, a heat transfer medium provided within the cooling apparatus to enhance thermal energy conduction between the electrochemical cells and the first wall.

29. The electrochemical energy storing device of claim 28, wherein the cooling apparatus comprises a plate heat exchanger defining a gap through which the heat transfer medium passes.

30. The electrochemical energy storing device of claim 18, wherein each of the thermal conductors is spot welded to a metalization layer provided along an edge of a respective electrochemical cell, the current being conducted laterally along the metalization layer.

31. The electrochemical energy storing device of claim 18, wherein the electrochemical cells are arranged in a stacked configuration and selectively interconnected in a series or parallel relationship.

32. The electrochemical energy storing device of claim 18, further comprising an interconnect board disposed in the enclosure and coupled to first and second terminals passing through the first and second holes of the cover, the interconnect board including an electrically conductive surface comprising a connection pattern that provides selective connectivity with the electrochemical cells.

33. The electrochemical energy storing device of claim 18, wherein the electrically resistive material disposed on or adjacent to the first wall comprises an electrically insulating material.

34. A method of transferring thermal energy and electrical current into and out of thin-film electrochemical cells encased in a housing, comprising:

conducting current over a current flux path defined between the electrochemical cells and a contact external to the electrochemical cells;

conducting thermal energy, using a portion of the current flux path and a thermal flux path substantially separate from the current flux path, between the electrochemical cells and thermally conductive material disposed adjacent the thermal conductors;

maintaining mechanical contact between the thermal conductors and the thermally conductive material in the presence of relative movement between the electrochemical cells and the thermally conductive material; and

maintaining the electrochemical cells in a state of compression.

35. The method of claim 34, further comprising regulating the thermal energy conduction using a heat transfer apparatus external to the electrochemical cells and in thermal contact with the thermally conductive material.

36. The method of claim 34, wherein maintaining the electrochemical cell in the state of compression comprises generating a compressive force external to the electrochemical cells.

37. The method of claim 34, wherein maintaining the electrochemical cells in the state of compression comprises generating a compressive force internal to selected ones of the plurality of electrochemical cells.