Methods of recycling and compositions used therein

• US 6,090,860 A
• Filed: 11/17/1998
• Issued: 07/18/2000
• Est. Priority Date: 09/18/1996
• Status: Expired due to Fees

• Current Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Original Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Inventors: Peters, Donald S., Brent, Randall J.
• Primary Examiner(s): Seidleck, James J.
• Assistant Examiner(s): Asinovsky, Olga
• Application Number:
  US09/193,545
• Time in Patent Office: 609 Days
• Field of Search: 521/48, 521/48.5, 521/40, 521/40.5, 521/41, 528/488, 528/491, 528/499, 528/502
• US Class Current: 521/48
• CPC Class Codes: C08J 11/06 without chemical reactions
• CPC Class Codes: C08J 2367/04 Polyesters derived from hydroxy carboxylic acids, e.g. lactones C08J2367/06 takes precedence
• CPC Class Codes: C09D 9/04 with surface-active agents
• CPC Class Codes: Y02W 30/62 Plastics recycling; Rubber recycling

Abstract

In one embodiment, the present invention relates to a method of separating a coating from a base plastic in a multilayered structure, comprising the steps of (A) providing the multilayered structure comprising at least a coating and a base plastic; (B) contacting the multilayered structure with a mixture comprising (i) a major amount of water, (ii) at least one basic compound or acid compound, (iii) at least one lifting agent, and (iv) at least one accelerator; and (C) separating the coating from the base plastic. In another embodiment, the present invention relates to a separating composition containing a major amount of water, at least one basic compound or acid compound, at least one lifting agent, and at least one accelerator. The inventive methods and compositions overcome numerous problems in the art by enabling the efficient recycling of coated polymer articles whereby clear and/or colorless recycled polymers may be obtained.

Claims

1. A method of physically separating a gas barrier polymer coating from a base thermoplastic polymer in a multilayered structure, comprising the steps of:

(A) providing the multilayered structure comprising at least one gas barrier polymer coating and at least one base thermoplastic polymer;

(B) contacting the multilayered structure with a mixture comprising (i) a major amount of water, (ii) at least one basic compound, (iii) at least one lifting agent, and (iv) at least one accelerator selected from the group consisting of glycol ethers, glycol ether acetates, alkylene carbonates, glycerine, lactones, hydrocarbyl substituted lactones, pvrrolidones, hydrocarbyl substituted pyrrolidones, furan compounds and mixtures thereof, wherein the pH of the mixture of step (B) is greater than about 7.5; and

(C) physically separating the gas barrier polymer coating from the base thermoplastic polymer.

2. The method of claim 1 wherein the multilayered structure is a beverage container or a food container.

3. The method of claim 1 wherein the multilayered structure is a polyethylene terephthalate container having a gas barrier polymer coating.

4. The method of claim 1 wherein the contacting of step (B) is accomplished by spraying, flooding or immersing the multilayered structure with the mixture.

5. The method of claim 1 wherein the basic compound is an alkali metal, alkaline earth metal or ammonium hydroxide, silicate, phosphate, borate, carbonate or mixtures thereof.

6. The method of claim 1 wherein the basic compound is selected from the group consisting of ammonium hydroxide, sodium hydroxide and potassium hydroxide.

7. The method of claim 1 wherein the multilayered structure is a flake.

8. The method of claim 1 wherein the lifting agent selected from the group consisting of fluorocarbon surfactants, sulfosuccinate surfactants, alkoxylated alcohols, alkoxylated phenols, polyoxyalkylene glycols, phosphate esters, aromatic sulfonates, diphenylsulfonates, alkoxylated alkyl aromatic surfactants and mixtures thereof.

9. The method of claim 1 wherein the accelerator is selected from the group consisting of an ethylene glycol ether, diethylene glycol ether, propylene glycol ether, or dipropylene glycol ether.

10. The method of claim 9 wherein the accelerator is selected from the group consisting of ethylene glycol methyl ether, ethylene glycol ethyl ether, ethylene glycol butyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol dibutyl ether, propylene glycol methyl ether, propylene glycol ethyl ether, propylene glycol butyl ether, propylene glycol dimethyl ether, propylene glycol diethyl ether, propylene glycol dibutyl ether, di(propylene glycol) methyl ether and mixtures thereof.

11. A composition having a pH greater than about 7.5 and comprising (i) a major amount of water, (ii) at least one basic compound selected from the group consisting of an alkaline earth metal hydroxide, alkaline earth metal silicate, alkaline earth metal phosphate, alkaline earth metal borate, alkaline earth metal carbonate, ammonium hydroxide, ammonium silicate, ammonium phosphate, ammonium borate, ammonium carbonate, alkali metal silicate, alkali metal phosphate, alkali metal borate, alkali metal carbonate and mixtures thereof, (iii) at least one lifting agent, and (iv) at least one accelerator selected from the group consisting of alkylene carbonates, glycerine, lactones and substituted lactones, pyrrolidones and substituted pyrrolidones, furan compounds and mixtures thereof.

12. The composition of claim 11 wherein the lifting agent is selected from the group consisting of fluorocarbon surfactants, sulfosuccinate surfactants, alkoxylated alcohols, alkoxylated phenols, polyoxyalkylene glycols, phosphate esters, aromatic sulfonates, diphenylsulfonates, alkoxylated alkyl aromatic surfactants and mixtures thereof.

13. The composition of claim 11 wherein water (i) is present in an amount greater than about 60% by weight, the basic compound (ii) is present in an amount from about 1% up to about 25% by weight, the lifting agent (iii) is present in an amount from about 0.001% up to about 5% by weight, and the accelerator (iv) is present in an amount from about 1% up to about 20% by weight.

14. A method of recycling coated polymer containers comprising the steps of

(A) providing a polymer container having a polymer coating;

(B) preparing flakes from the coated polymer container;

(C) contacting the flakes with a mixture comprising (i) a major amount of water, (ii) at least one basic compound, (iii) at least one lifting agent and (iv) at least one accelerator selected from the group consisting of glycol ethers, glycol ether acetates, alkylene carbonates, glycerine, lactones and substituted lactones, pyrrolidones and substituted pyrrolidones, furan compounds and mixtures thereof; and

(D) separating the mixture and the polymer coating from the flakes.

15. The method of claim 14 wherein the polymer container is a polyethylene terephthalate food or beverage container.

16. The method of claim 14 wherein the basic compound (ii) is an alkali metal, alkaline earth metal or ammonium hydroxide, silicate, phosphate, borate, carbonate or mixtures thereof.

17. The method of claim 14 further comprising the step of (F) extruding the flakes into a food or beverage container.

18. A method of physically separating a gas barrier polymer coating from a base thermoplastic polymer in a multilayered structure, comprising the steps of:

(A) providing the multilayered structure comprising at least one gas barrier polymer coating and at least one base thermoplastic polymer, the gas barrier polymer coating comprising a gas barrier polymer selected from the group consisting of polymers formed from vinylhalides, acrylates, methacrylates, ethylenically unsaturated monomers, unsaturated nitriles, unsaturated organic acids, ethylene-vinyl alcohol, alkyl and/or aryl esters of unsaturated carboxylic acids and a polymeric reaction product of a polyamine and polyepoxide;

(B) contacting the multilayered structure with a mixture comprising (i) a major amount of water, (ii) at least one basic compound, (iii) at least one lifting agent, and (iv) at least one accelerator selected from the group consisting of glycol ethers, glycol ether acetates, alkylene carbonates, glycerine, lactones, hydrocarbyl substituted lactones, pyrrolidones, hydrocarbyl substituted pyrrolidones, furan compounds and mixtures thereof, wherein the pH of the mixture of step (B) is greater than about 7.5; and

(C) physically separating the gas barrier polymer coating from the base thermoplastic polymer.