Pyrotechnic gas generant composition including high oxygen balance fuel

• US 6,093,269 A
• Filed: 12/18/1997
• Issued: 07/25/2000
• Est. Priority Date: 12/18/1997
• Status: Expired due to Term

• Current Assignee: Arc Automotive Incorporated (The Jordan Co. LP)
• Original Assignee: Atlantic Research Corporation (L3Harris Technologies, Inc.)
• Inventors: Lundstrom, Norman H., Greso, Aaron J., Scheffee, Robert S.
• Primary Examiner(s): Miller, Edward A.
• Application Number:
  US08/993,882
• Time in Patent Office: 950 Days
• Field of Search: 149/36, 149/76, 149/61, 149/19.1
• US Class Current: 149/36
• CPC Class Codes: C06B 25/34 the compound being a nitrated acyclic, alicyclic or heterocyclic amine
• CPC Class Codes: C06D 5/06 by reaction of two or more solids
• CPC Class Codes: C07C 281/16 Compounds containing any of the groups , e.g. aminoguanidine

Abstract

A pyrotechnic gas generant composition including a high oxygen balance compound or fuel which is the resulting reaction product of aminoguanidine nitrate and nitric acid. Specifically, the resulting reaction product is a yellow precipitate that can be used alone, with or without oxidizers or other additives, for very rapid self-deflagration or in combination with oxidizers and additives. In each instance, the gas generant composition provides both high gas output and low production of solid combustion products. Further, the precipitant is relatively non-hygroscopic and has a high burn rate. Specifically, the gas generating composition is useful as a gas generator for an air bag of an occupant restraint system for an automobile, gun propellants, inflation and expulsion devices, flotation devices, pyrotechnics, fire suppression devices and smokeless, reduced smoke and smokey rocket propellants.

Claims

1. A pyrotechnic as generant composition comprising:

a high oxygen balance fuel in an amount of 67-84 wt. % which is a resulting solid yellow reaction product of aminoguanidine nitrate and nitric acid; and

an oxidizer system which includes 6-14 wt. % of sodium nitrate and 9-20 wt. % of ammonium perchlorate.

2. A pyrotechnic gas generant composition of claim 1, wherein said resulting yellow reaction product of aminoguanidine nitrate and nitric acid is prepared by a process comprising:

(a) providing aminoguanidine nitrate;

(b) combining said aminoguanidine nitrate with nitric acid to form a dispersion, wherein said dispersion proceeds through a color transition from water white to straw to bright yellow color, said color being comparable to a potassium dichromate solution.

3. A pyrotechnic gas generant composition of claim 2, wherein 70% reagent grade nitric acid is combined with said aminoguanidine nitrate.

4. A pyrotechnic gas generant composition of claim 1, wherein said resulting yellow reaction product of aminoguanidine nitrate and nitric acid is prepared by a process comprising:

(a) combining aminoguanidine nitrate and water to form a slurry;

(b) stirring 70% nitric acid into said slurry to form a dispersion;

(c) heating said dispersion during which time said dispersion dissolves and proceeds with effervescence through a color transition from water white to straw to a bright yellow color to form a solution, said bright yellow color being comparable to a potassium dichromate solution;

(d) cooling said solution to precipitate said solid yellow reaction product.

5. A pyrotechnic gas generant composition of claim 4, wherein said dispersion is heated to 55-65°

C. and said solution is cooled to below 12°

C.

6. A pyrotechnic gas generant composition of claim 1, wherein said oxidizer is substantially non-hygroscopic.

7. A pyrotechnic gas generant composition of claim 1, further including at least one additive selected from the group consisting of a scavenger, ignition aid, ignition initiator, gas conversion catalyst, ballistic modifier, slag formers, binders, energetic binders, plasticizers, energetic plasticizers, fuels, stabilizers, curing agents, cure catalysts, cross linkers, coolants, and compounding aids and mixtures thereof.

8. A pyrotechnic gas generant composition of claim 1, comprising 74.8 wt % of said high oxygen balance fuel, 10.6 wt % of said sodium nitrate and 14.6 wt % of said ammonium perchlorate, wherein said gas generant composition provides an exothern onset of 158°

C. and an exotherm peak of 182°

C.

9. A pyrotechnic gas generant composition comprising:

a high oxygen balance fuel in an amount of 73.35 wt. % which is a resulting solid yellow reaction product of aminoguanidine nitrate and nitric acid;

potassium nitrate in an amount of 12.35 wt. %; and

ammonium perchlorate in an amount of 14.3 wt. %, wherein

said gas generant composition provides an exotherm onset of 157°

C. and an exotherm peak of 183°

C.

10. A pyrotechnic gas generant composition comprising:

a high oxygen balance fuel in an amount of 72.9 wt. % which is a resulting solid yellow reaction product of aminoguanidine nitrate and nitric acid;

strontium nitrate in an amount of 12.9 wt. %; and

ammonium perchlorate in an amount of 14.2 wt. %, wherein

said gas generant composition provides an exotherm onset of 160°

C. and an exotherm peak of 184.5°

C.

11. A pyrotechnic gas generant composition comprising:

a high oxygen balance fuel in an amount of 65-83 wt. % which is a resulting solid yellow reaction product of aminoguanidine nitrate and nitric acid;

potassium nitrate in an amount of 8-17 wt. %; and

ammonium perchlorate in an amount of 9-19 wt. %.

12. A pyrotechnic gas generant composition comprising:

a high oxygen balance fuel in an amount of 64-83 wt. % which is a resulting solid yellow reaction product of aminoguanidine nitrate and nitric acid;

strontium nitrate in an amount of 8-17 wt. %, and

ammonium perchlorate in an amount of 9-19 wt. %.

13. A pyrotechnic gas generant composition comprising:

a high oxygen balance fuel in an amount of 70.3 wt. % which is a resulting solid yellow reaction product of aminoguanidine nitrate and nitric acid;

lithium carbonate in an amount of 7.7 wt. %; and

ammonium perchlorate in an amount of 22.0 wt. %, wherein

said gas generant composition provides an exotherm onset of 146°

C. and an exotherm peak of 179°

C.

14. A pyrotechnic as generant composition comprising:

a high oxygen balance fuel in an amount of 67-84 wt. % which is azodiformamidine dinitrate; and

an oxidizer system which includes 6-14 wt. % of sodium nitrate and 9-20 wt. % of ammonium perchlorate.

15. A pyrotechnic gas generant composition of claim 14, wherein said oxidizer is substantially non-hygroscopic.

16. A pyrotechnic gas generant composition of claim 14, further including at least one additive selected from the group consisting of a scavenger, ignition aid, ignition initiator, gas conversion catalyst, ballistic modifier, slag formers, binders, energetic binders, plasticizers, energetic plasticizers, fuels, stabilizers, curing agents, cure catalysts, cross linkers, coolants, and compounding aids and mixtures thereof.

17. A pyrotechnic gas generant composition comprising:

a high oxygen balance fuel in an amount of 65-83 wt. % which is azodiformamidine dinitrate;

potassium nitrate in an amount of 8-17 wt. %, and

ammonium perchlorate in an amount of 9-19 wt. %.

18. A pyrotechnic gas generant composition comprising:

a high oxygen balance fuel in an amount of 64-83 wt. % which is azodiformamidine dinitrate;

strontium nitrate in an amount of 8-17 wt. %; and

ammonium perchlorate in an amount of 9-19 wt. %.

19. A pyrotechnic gas generant composition comprising:

azodiformamidine dinitrate (AZODN); and

between 5 to 50 wt. % of an oxidizer system which comprises ammonium perchlorate and at least one additional oxidizer selected from the group consisting of sodium nitrate, potassium nitrate, strontium nitrate and lithium carbonate.

20. The pyrotechnic gas generant composition of claim 19, comprising 73.35 wt. % AZODN, 12.35 wt. % of said potassium nitrate, and 14.3 wt. % of said ammonium perchlorate.

21. The pyrotechnic gas generant composition of claim 19, comprising 72.9 wt. % AZODN, 12.9 wt. % of said strontium nitrate, and 14.2 wt. % of said ammonium perchlorate.

22. The pyrotechnic gas generant composition of claim 19, comprising 65-83 wt. % AZODN, 8-17 wt. % of said potassium nitrate, and 9-19 wt. % of said ammonium perchlorate.

23. The pyrotechnic gas generant composition of claim 19, comprising 64-83 wt. % AZODN, 8-17 wt. % of said strontium nitrate, and 9-19 wt. % of said ammonium perchlorate.

24. The pyrotechnic gas generant composition of claim 19, comprising 70.3 wt. % AZODN, 7.7 wt. % of said lithium carbonate, and 22.0 wt. % of said ammonium perchlorate.