Methods for making multi-layer golf balls using rigid uncrosslinked shells

• US 6,093,357 A
• Filed: 03/26/1998
• Issued: 07/25/2000
• Est. Priority Date: 03/26/1998
• Status: Expired due to Term

• Current Assignee: Acushnet Company (FILA Holdings Corp.)
• Original Assignee: Acushnet Company (FILA Holdings Corp.)
• Inventors: Bissonette, Laurent C., Pasqua, Samuel A. Jr., Desimas, Antonio U.
• Primary Examiner(s): Silbaugh, Jan H.
• Assistant Examiner(s): Lee, Edmund H.
• Application Number:
  US09/048,348
• Time in Patent Office: 852 Days
• Field of Search: 264/250, 264/320, 264/328.1, 264/331.13, 264/331.15, 264/248, 264/279.1, 473/374, 473/376, 473/370, 473/373
• US Class Current: 264/248
• CPC Class Codes: A63B 2225/30 Maintenance
• CPC Class Codes: A63B 37/0003 Golf balls
• CPC Class Codes: A63B 37/0051 Materials other than polybutadienes; Constructional details
• CPC Class Codes: A63B 37/0052 Liquid cores
• CPC Class Codes: A63B 37/0069 Flexural modulus; Bending stiffness
• CPC Class Codes: A63B 37/0076 Multi-piece balls, i.e. having two or more intermediate layers
• CPC Class Codes: A63B 37/0086 Flexural modulus; Bending stiffness
• CPC Class Codes: B29C 43/18 incorporating preformed parts or layers, e.g. compression moulding around inserts or for coating articles B29C43/206 takes precedence
• CPC Class Codes: B29D 99/0042 Producing plain balls hollow balls B29D22/04
• CPC Class Codes: B29L 2031/54 Balls
• CPC Class Codes: B29L 2031/546 Golf balls
• CPC Class Codes: C08F 285/00 Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 51/04 grafted on to rubbers
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 53/02 of vinyl-aromatic monomers and conjugated dienes

Abstract

A multi-layer golf ball and methods for preparing a portion thereof including a core having at least one core layer, a mantle having at least one layer including an amount of reinforcing polymer component and a resilient polymer component disposed concentrically adjacent the core, and at least one cover layer disposed concentrically adjacent the mantle, wherein the layer of the mantle is sufficiently rigid to inhibit the resilient polymer component from substantially altering shape prior to crosslinking. The invention also includes an elastomeric composition including a polybutadiene having a high molecular weight average and a predominantly 1,4-cis content, a free-radical initiator, and a reinforcing polymer component having a sufficiently low viscosity at a mixing temperature to permit substantially uniform dispersion of the polymer component with the polybutadiene and having a crystalline melting point sufficiently low to permit mixing while avoiding substantial crosslinking.

Claims

1. A method of forming at least a portion of a golf ball core which comprises:

mixing a resilient polymer component, a free-radical initiator, a crosslinking agent, and a sufficient amount of a reinforcing polymer component to provide an uncrosslinked first mixture having a rigidity as determined by a flexural modulus greater than about 3.5 MPa;

forming the first mixture into at least two shells in a desired shape, wherein the reinforcing polymer component imparts the rigidity to the shells to maintain the desired shape until the first mixture is crosslinked;

providing a center having a first geometric center;

assembling the at least two shells concentrically about the center to form a first mantle layer having a second desired shape, wherein the first mantle layer and center together form an uncured golf ball core; and

applying sufficient heat and pressure to the uncured golf ball core for a time sufficient to crosslink the first mixture in the shells, thereby curing and forming the at least a portion of the golf ball core so as to adjust a loss tangent of the crosslinked first mixture to less than about 0.15 at -60°

C. and less than about 0.05 at 30°

C., and adjust the tensile storage modulus of the crosslinked first mixture to greater than about 100 MPa at -60°

C. and greater than about 50 MPa at 30°

C., each when measured at 1 Hz and one percent strain.

2. The method of claim 1, wherein the second desired shape is an ellipsoidal shape.

3. The method of claim 1, which further comprises selecting the resilient polymer component to have a molecular weight average of between about 50,000 to 1,000,000.

4. The method of claim 1, which further comprises selecting the reinforcing polymer component to have a crystalline melting temperature between 35°

C. to 120°

C.

5. The method of claim 1, wherein the first mixture is formed into the at least two shells by injection molding.

6. The method of claim 1, wherein the forming comprises compression molding.

7. The method of claim 1, wherein a plurality of the at least a portion of the golf ball core each have a second geometric center which is disposed within an average of about 0.015 inches from the first geometric center of each of the at least a portion of the golf ball core.

8. The method of claim 1, which further comprises adjusting the flexural modulus of the uncrosslinked first mixture to at least about 7 MPa.

9. The method of claim 1, wherein the melting temperature of the reinforcing polymer component and the crosslinking temperature of the first mixture are selected to differ by about 60°

C. to 160°

C.

10. The method of claim 1, wherein the core comprises a center selected from the group consisting of a center including surrounding elastic windings, a solid center, or a liquid center.

11. The method of claim 1, which further comprises forming at least one additional layer about the center prior to assembling the shells concentrically about the center, after assembling the shells concentrically about the center, or after heating the at least a portion of the golf ball core.

12. The method of claim 11, wherein the additional layer is formed around the at least a portion of the golf ball core after heating the at least a portion of the golf ball core to provide a cover disposed concentrically about the at least a portion of the golf ball golf ball core.

13. The method of claim 1, wherein the free-radical initiator selected is an organic peroxide.

14. The method of claim 1, wherein the reinforcing polymer component comprises a polymer selected from the group consisting of a block copolymer ether/ester, an acrylic polyol, a transpolyisoprene, a transpolybutadiene, a 1,2-polybutadiene, an ethylene-vinyl acetate copolymer, a polyethylene or copolymer thereof, a cyclooctene, and a combination thereof.

15. The method of claim 1, wherein the crosslinking agent comprises a metallic salt selected from the group consisting of an unsaturated fatty acid, a monocarboxylic acid, and mixtures thereof.

16. The method of claim 1, wherein the reinforcing polymer component is provided in an amount from about 1 to 40 weight percent of the total polymer components.

17. The method of claim 1, wherein the reinforcing polymer component is provided in an amount from about 5 to 25 weight percent of the first mixture.

18. The method of claim 1, wherein the resilient polymer component comprises a polymer selected from the group consisting of polybutadiene, polyisoprene, styrene-butadiene polymer, styrene-propylene-diene rubber, and a combination thereof.

19. The method of claim 1, wherein the rigidity is greater than about 7 MPa.

20. The method of claim 1, wherein the resilient polymer component is provided in an amount from about 60 to 99 weight percent of the total weight of the polymer components.

21. The method of claim 1, which further comprises combining a filler with at least one of the resilient polymer component, free-radical initiator, crosslinking agent, and the reinforcing polymer component.

22. The method of claim 1, wherein the filler is selected to comprise zinc oxide, tin oxide, barium sulfate, zinc sulfate, calcium carbonate, barium carbonate, clay, tungsten, tungsten carbide, a silica, or cured ground rubber, with the filler being present in an amount from about 0.5 to 50 weight percent of the first mixture.

23. A method for forming a golf ball core which comprises:

mixing a resilient polymer component, a free-radical initiator, a crosslinking agent, and a sufficient amount of a reinforcing polymer component to provide an uncrosslinked first mixture having a rigidity as determined by a flexural modulus greater than about 3.5 MPa;

forming the first mixture into at least two shells in a desired shape, wherein the reinforcing polymer component imparts rigidity to the shells to maintain the desired shape until the first mixture is crosslinked;

providing a center having a first geometric center;

assembling the at least two shells concentrically about the center to form a mantle layer having a second desired shape, wherein the mantle layer and center together form an uncured golf ball core; and

applying sufficient heat and pressure to the uncured golf ball core for about 5 to 40 minutes to at least partially crosslink the first mixture in the mantle, thereby curing and forming that at least a portion of the golf ball core so as to adjust a loss tangent of the crosslinked first mixture to less than about 0.15 at -60°

C. and less than about 0.05 at 30°

C., and adjust the tensile storage modulus of the crosslinked first mixture to greater than about 100 MPa at -60°

C. and greater than about 50 MPa at 30°

C., each when measured at 1Hz and one percent strain.