Coated transparencies and transparent laminates incorporating a transparent polyurethane composition

• US 6,093,451 A
• Filed: 01/30/1998
• Issued: 07/25/2000
• Est. Priority Date: 01/30/1998
• Status: Expired due to Term

• Current Assignee: GKN Aerospace Transparency Systems, Inc. (Melrose Industries Plc)
• Original Assignee: Pilkington Aerospace, Inc. (Melrose Industries Plc)
• Inventors: Sandlin, Stephen L., Moncur, Marlowe V., Hoo, Lin Hin
• Primary Examiner(s): NILAND, PATRICK DENNIS
• Application Number:
  US09/016,452
• Time in Patent Office: 907 Days
• Field of Search: 428/423.1, 428/423.7, 428/424.2, 428/424.4, 428/425.6
• US Class Current: 428/423.1
• CPC Class Codes: C08G 18/4854 Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
• CPC Class Codes: C08G 18/664 with compounds of group C08G18/3203
• CPC Class Codes: C08G 18/758 containing two or more cycloaliphatic rings
• CPC Class Codes: C08J 2475/00 Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
• CPC Class Codes: C08J 7/0423 with at least one layer of inorganic material and at least one layer of a composition containing a polymer binder
• CPC Class Codes: C08J 7/0427 with only one layer of a composition containing a polymer binder with more layers C08J7/042
• CPC Class Codes: C08J 7/043 Improving the adhesiveness of the coatings per se, e.g. forming primers adhesives in the form of films or foils characterised by the primer layers between the polymer carriers and the adhesives C09J7/50
• CPC Class Codes: C08J 7/044 Forming conductive coatings; Forming coatings having anti-static properties
• CPC Class Codes: C08J 7/046 Forming abrasion-resistant coatings; Forming surface-hardening coatings
• CPC Class Codes: C09D 175/06 from polyesters
• CPC Class Codes: Y10T 428/31507 Of polycarbonate
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• CPC Class Codes: Y10T 428/31565 Next to polyester [polyethylene terephthalate, etc.]
• CPC Class Codes: Y10T 428/31573 Next to addition polymer of ethylenically unsaturated monomer
• CPC Class Codes: Y10T 428/31576 Ester monomer type [polyvinylacetate, etc.]
• CPC Class Codes: Y10T 428/31583 Nitrile monomer type [polyacrylonitrile, etc.]
• CPC Class Codes: Y10T 428/31601 Quartz or glass

Abstract

The present invention is embodied in a polyurethane composition suitable for coating, casting or laminating, which incorporates a prescribed additive selected to increase the composition'"'"'s electrical conductivity without adversely affecting the composition'"'"'s transparency and percent haze and without adversely affecting its adhesion to an underlying substrate or its environmental durability, especially with regard to humidity resistance. The prescribed additive is an ionizable metal salt of a perfluoroalkylsulfonimide, in a weight percent of 0.5 to 5.0, with the metal being an alkali metal and the preferred perfluoroalkylsulfonimide being trifluoromethanesulfonimide. The most preferred salt is lithium trifluoromethanesulfonimide. The preferred polyurethanes include both aliphatic polyetherurethanes and aliphatic polyesterurethanes. Use of the additive enhances the composition'"'"'s electrical conductivity by at least about two orders of magnitude, thereby minimizing the risk of a static charge building to a point where a shock hazard is created or the polyurethane coating or laminate is damaged by a rapid discharge of electrical current. The composition is particularly useful in an aircraft window or transparency, where it can be used as a coating or laminated film overlaying a transparent conductive coating.

Claims

1. A coated transparency comprising:

a transparent substrate having an outer surface;

a thin, transparent conductive coating overlaying the substrate'"'"'s outer surface; and

a transparent polyurethane coating overlaying the transparent conductive coating, the polyurethane coating formed from a composition incorporating 0.5 to 5.0 weight percent of an ionizable salt of a perfluoroalkylsulfonimide.

2. A coated transparency as defined in claim 1, wherein the transparent polyurethane coating is an aliphatic polyesterurethane.

3. A coated transparency as defined in claim 1, wherein the transparent polyurethane coating is an aliphatic polyetherurethane.

4. A coated transparency as defined in claim 1, wherein the metal in the transparent polyurethane coating is an alkali metal and the perfluoroalkylsulfonimide in the transparent polyurethane coating is trifluoromethanesulfonimide.

5. A coated transparency as defined in claim 4, wherein the ionizable salt in the transparent polyurethane coating is lithium trifluoromethanesulfonimide.

6. A coated transparency as defined in claim 5, wherein the weight percent of lithium trifluoromethanesulfonimide in the transparent polyurethane coating is in the range of 1.0 to 3.0.

7. A coated transparency as defined in claim 1, wherein the ionizable salt in the transparent polyurethane coating is incorporated at a concentration effective to reduce the coating'"'"'s volume resistivity, after curing, by more than about two orders of magnitude over what it would be in the absence of the ionizable salt.

8. A coated transparency as defined in claim 1, wherein the transparent polyurethane coating comprises:

a transparent underlayer incorporating a thermoset adhesive; and

a transparent overlayer.

9. A coated transparency as defined in claim 8, wherein:

the underlayer of the transparent polyurethane coating is formed from a solution of a moisture-curable, aromatic polyetherurethane, thermoset adhesive, based on methylene diphenyl diisocyanate and polytetramethylene oxide polyols, in cyclohexanone, incorporating the ionizable salt of a perfluoroalkylsulfonimide; and

the overlayer of the transparent polyurethane coating is an aliphatic polyesterurethane incorporating the ionizable salt of a perfluoroalkylsulfonimide.

10. A coated transparency as defined in claim 1, wherein:

the transparent substrate is selected from the group consisting of polycarbonate, glass, and acrylic; and

the tin, transparent conductive coating is selected from the group consisting of gold, indium tin oxide, metal oxide, and multi-layer stacks thereof.

11. A coated transparency comprising:

a transparent substrate having an outer surface;

a thin, transparent conductive coating overlaying the substrate'"'"'s outer surface; and

a transparent aliphatic polyetherurethane coating overlaying the transparent conductive coating, wherein the polyetherurethane coating is formed from a composition incorporating 1.0 to 3.0 weight percent of lithium trifluoromethanesulfonimide, and wherein the polyetherurethane coating, after curing, has a volume resistivity of less than about 1×

10¹¹ ohm-cm.

12. A transparent laminate comprising:

a transparent substrate having an outer surface;

a thin, transparent conductive coating overlaying the substrate'"'"'s outer surface; and

a transparent polyurethane layer laminated to the transparent conductive coating, the polyurethane layer formed from a composition incorporating 0.5 to 5.0 weight percent of an ionizable salt of a perfluoroalkylsulfonimide.

13. A transparent laminate as defined in claim 12, wherein the transparent polyurethane layer incorporates an aliphatic polyesterurethane.

14. A transparent laminate as defined in claim 12, wherein the transparent polyurethane layer incorporates an aliphatic polyetherurethane.

15. A transparent laminate as defined in claim 12, wherein the metal in the transparent polyurethane layer is an alkali metal and the perfluoroalkylsulfonimide in the transparent polyurethane layer is trifluoromethanesulfonimide.

16. A transparent laminate as defined in claim 15, wherein the ionizable salt in the transparent polyurethane layer is lithium trifluoromethanesulfonimide.

17. A transparent laminate as defined in claim 16, wherein the weight percent of lithium trifluoromethanesulfonimide in the transparent polyurethane layer is in the range of 1.0 to 3.0.

18. A transparent laminate as defined in claim 12, wherein the ionizable salt in the transparent polyurethane layer has a weight percentage effective to reduce the layer'"'"'s volume resistivity, after curing, by more than about two orders of magnitude over what it would be in the absence of the ionizable salt.

19. A transparent laminate as defined in claim 12, wherein:

the transparent polyurethane layer comprises

a transparent underlayer functioning as an adhesive layer, and

a transparent overlayer; and

both the underlayer and the overlayer of the transparent polyurethane layer incorporate the ionizable salt of a perfluoroalkylsulfonimide.

20. A transparent laminate as defined in claim 19, wherein:

the underlayer of the transparent polyurethane layer is a polyetherurethane sheet having surfaces carrying the ionizable salt of a perfluoroalkylsulfonimide; and

the overlayer of the transparent polyurethane layer is an aliphatic polyesterurethane incorporating the ionizable salt of a perfluoroalkylsulfonimide.

21. A transparent laminate as defined in claim 12, wherein:

the transparent substrate is selected from the group consisting of polycarbonate, glass, and acrylic; and

the thin, transparent conductive coating is selected from the group consisting of gold, indium tin oxide, metal oxide, and multi-layer stacks thereof.