Photocatalyst-binder compositions

• US 6,093,676 A
• Filed: 11/12/1998
• Issued: 07/25/2000
• Est. Priority Date: 10/26/1993
• Status: Expired due to Term

• Current Assignee: Ephraim Heller
• Original Assignee: E. Heller & Company
• Inventors: Heller, Ephraim, Heller, Adam, Pishko, Michael V.
• Primary Examiner(s): Simmons, David A.
• Assistant Examiner(s): HOEY, BETSEY MORRISON
• Application Number:
  US09/191,214
• Time in Patent Office: 621 Days
• Field of Search: 502/242, 502/248, 502/250, 502/253, 106/286.3, 106/286.4, 106/286.6, 106/287.1, 106/287.12, 106/287.13, 106/287.14, 106/287.19
• US Class Current: 502/242
• CPC Class Codes: B01J 35/30 characterised by their physical properties
• CPC Class Codes: B01J 35/39 Photocatalytic properties
• CPC Class Codes: B01J 37/0215 Coating
• CPC Class Codes: B01J 37/0219 the coating containing organic compounds
• CPC Class Codes: C02F 1/32 with ultraviolet light
• CPC Class Codes: C02F 1/725 by catalytic oxidation
• CPC Class Codes: C02F 2305/10 Photocatalysts
• CPC Class Codes: C03C 17/007 containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
• CPC Class Codes: C03C 2217/45 Inorganic continuous phases
• CPC Class Codes: C03C 2217/475 Inorganic materials
• CPC Class Codes: C03C 2217/477 Titanium oxide
• CPC Class Codes: C03C 2217/71 Photocatalytic coatings
• CPC Class Codes: C08G 77/045 containing less than 25 silicon atoms
• CPC Class Codes: C08K 2003/2241 Titanium dioxide
• CPC Class Codes: C09D 183/04 Polysiloxanes
• CPC Class Codes: Y10S 210/908 Organic
• CPC Class Codes: Y10S 210/909 Aromatic compound, e.g. pcb, phenol

Abstract

A photocatalyst composition containing a substantially non-oxidizable binder which allows large amounts of photocatalytic particles to be adhered to a surface. Upon application to a surface, the composition dries or cures to form an adherent, abrasion-resistant, thermostable, and photocatalytic coating.

Claims

1. A composition comprising:

photocatalytic particles responsive to incident light and having an average diameter of about 100 nm or less; and

a binder within which the photocatalytic particles are dispersed, the binder comprising no more than 15% oxidizable carbon and transmitting, at a thickness of 1 μ

m, a substantial portion of incident light of at least one wavelength capable of activating the photocatalyst;

wherein the composition forms an adherent film when applied to a surface.

2. The composition of claim 1, wherein the binder transmits, at a thickness of 1 μ

m, at least 50% of photons of at least one wavelength capable of activating the photocatalyst.

3. The composition of claim 1, wherein the binder, in the absence of the photocatalytic particles, is transparent to visible light.

4. The composition of claim 1, wherein the photocatalytic particles comprise TiO₂, ZnO, CaTiO₃, SnO₂, MoO₃, Fe₂ O₃, WO₃, NbO₅, SiC, and combinations thereof.

5. The composition of claim 1, wherein the photocatalytic particles have a diameter of 50 nm or less.

6. The composition of claim 1, wherein the photocatalytic particles have a surface area of at least about 30 m² /g.

7. The composition of claim 1, wherein the photocatalytic particles are 10 to 20 percent of the composition in the absence of a solvent.

8. The composition of claim 1, wherein the composition forms a abrasion-resistant, thermostable film when applied to a surface.

9. A composition comprising:

photocatalytic particles responsive to incident light and having an average diameter of about 100 nm or less; and

a binder within which the photocatalytic particles are dispersed, the binder comprising hydrated silica, hydrated alumina, or mixtures thereof,

wherein the composition forms an adherent film when applied to a surface.

10. The composition of claim 9, wherein the binder consists essentially of hydrated silica, hydrated alumina, or mixtures thereof.

11. A composition comprising:

photocatalytic particles responsive to incident light and having an average diameter of about 100 nm or less; and

a transparent, substantially non-oxidizable binder within which the photocatalytic particles are dispersed;

wherein the composition forms an adherent film when applied to a surface.

12. The composition of claim 11, wherein the binder comprises no more than 15% oxidizable carbon.

13. The composition of claim 11, wherein the binder comprises no more than 10% oxidizable carbon after curing for six months.

14. The composition of claim 11, wherein the binder has a backbone and less than one in six atoms of the backbone is oxidizable carbon.

15. The composition of claim 11, wherein the photocatalytic particles comprise TiO₂, ZnO, CaTiO₃, SnO₂, MoO₃, Fe₂ O₃, WO₃, NbO₅, SiC, and combinations thereof.

16. The composition of claim 11, wherein the photocatalytic particles have a surface area of at least about 30 m² /g.

17. The composition of claim 11, wherein the composition forms an abrasion-resistant, thermostable film when applied to a surface.

18. A composition comprising:

photocatalytic particles responsive to incident light and having an average surface area of at least about about 30 m² /g; and

a binder within which the photocatalytic particles are dispersed, the binder comprising no more than 15% oxidizable carbon and transmitting, at a thickness of 1 μ

m, a substantial portion of incident light of at least one wavelength capable of activating the photocatalyst;

wherein the composition forms an adherent film when applied to a surface.

19. The composition of claim 18, wherein the binder comprises hydrated silica, hydrated alumina, or mixtures thereof.

20. A composition comprising:

photocatalytic particles responsive to incident light and having an average surface area of at least about about 30 m² /g; and

a transparent, substantially non-oxidizable binder within which the photocatalytic particles are dispersed;

wherein the composition forms an adherent film when applied to a surface.

21. The composition of claim 20, wherein the binder transmits, at a thickness of 1 μ

m, at least 50% of photons of at least one wavelength capable of activating the photocatalyst.