Carpet backing precoats, laminate coats, and foam coats prepared from polyurethane formulations including fly ash

• US 6,096,401 A
• Filed: 08/28/1996
• Issued: 08/01/2000
• Est. Priority Date: 08/28/1996
• Status: Expired due to Term

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Jenkines, Randall C.
• Primary Examiner(s): Morris, Terrel
• Assistant Examiner(s): JUSKA, CHERYL ANN
• Application Number:
  US08/703,158
• Time in Patent Office: 1,434 Days
• Field of Search: 428/95, 428/97, 521/101, 521/106, 521/159
• US Class Current: 428/95
• CPC Class Codes: C08J 2375/04 Polyurethanes
• CPC Class Codes: C08J 9/0066 Use of inorganic compounding ingredients
• CPC Class Codes: D06N 2203/068 Polyurethanes
• CPC Class Codes: D06N 2205/10 Particulate form, e.g. powder, granule
• CPC Class Codes: D06N 2205/20 Cured materials, e.g. vulcanised, cross-linked
• CPC Class Codes: D06N 7/0086 characterised by the cushion backing, e.g. foamed polyurethane
• CPC Class Codes: Y10T 428/23979 Particular backing structure or composition
• CPC Class Codes: Y10T 428/23986 With coating, impregnation, or bond
• CPC Class Codes: Y10T 428/23993 Composition of pile or adhesive

Abstract

The present invention is a polyurethane carpet backing prepared from a polyurethane-forming composition wherein fly ash is included as a filler material. High loadings of fly ash can be obtained without detriment to the process for preparing a polyurethane carpet backing, or adverse effect to the physical properties of the carpet backing.

Claims

1. A polyurethane-forming composition useful for preparing a polyurethane precoat, polyurethane laminate coat, or polyurethane foam coat comprising:

(a) a polyol;

(b) a chain extender;

(c) a polyisocyanate;

(d) a catalyst;

(e) a filler wetting agent, wherein thee filler wetting agent is an ethoxylated phosphate ester in an organic carrier; and

(f) a filler, wherein the filler includes fly ash.

2. The polyurethane-forming composition of claim 1 wherein the composition additionally includes:

(1) a surfactant; and

(2) a blowing agent.

3. The polyurethane-forming composition of claim 1 wherein the polyol has an average functionality of from about 1.4 to about 3.0.

4. The polyurethane-forming composition of claim 1 wherein the polyol has an average functionality of from about 1.6 to about 2.8.

5. The polyurethane-forming composition of claim 1 wherein a polyol mixture is included.

6. The polyurethane-forming composition of claim 5 wherein the polyol mixture has an average functionality of from about 1.97 to about 2.5.

7. The polyurethane-forming composition of claim 5 wherein the polyol mixture has an average functionality of from about 1.98 to about 2.4.

8. The polyurethane-forming composition of claim 5 wherein the polyol mixture has an average functionality of from about 1.99 to about 2.3.

9. The polyurethane-forming composition of claim 1 wherein the filler includes at least 50 percent fly ash, by weight of total filler.

10. The polyurethane-forming composition of claim 1 wherein the filler includes at least 75 percent fly ash, by weight of total filler.

11. The polyurethane-forming composition of claim 1 wherein the filler includes at least 90 percent fly ash, by weight of total filler.

12. The polyurethane-forming composition of claim 1 wherein substantially all of the filler is fly ash.

13. A backed carpet having a polyurethane backing that includes at least one coat of polyurethane that is prepared from a polyurethane-forming composition comprising:

(a) a polyol;

(b) a chain extender;

(c) a polyisocyanate;

(d) a catalyst;

(e) a filler wetting agent, wherein the filler wetting agent is an ethoxylated phosphate ester in an organic carrier;

(f) a filler, wherein the filler includes fly ash.

14. The backed carpet of claim 13 wherein the polyurethane-forming composition additionally includes:

(1) a surfactant; and

(2) a blowing agent.

15. The backed carpet of claim 13 wherein the carpet backing includes:

(a) a polyurethane precoat; and

(b) a polyurethane laminate coat.

16. The backed carpet of claim 15 wherein the precoat and laminate coat each includes fly ash.

17. The backed carpet of claim 15 wherein the carpet backing additionally includes a polyurethane foam coat.

18. The backed carpet of claim 17 wherein the precoat, laminate coat and foam coat each includes fly ash.

19. The backed carpet of claim 13 wherein the carpet backing includes a polyurethane precoat and a polyurethane foam coat.

20. The backed carpet of claim 19 wherein the foam coat includes fly ash.

21. The backed carpet of claim 19 wherein the precoat and the foam coat each includes fly ash.